Oxidation behaviors of Ni(Cr)-TiB2 coating deposited by HVOF technique were studied at 800,900 and 1 000℃in air. The microstructures of as-sprayed and oxidized coatings were characterized by X-ray diffractometry(XRD)...Oxidation behaviors of Ni(Cr)-TiB2 coating deposited by HVOF technique were studied at 800,900 and 1 000℃in air. The microstructures of as-sprayed and oxidized coatings were characterized by X-ray diffractometry(XRD)and scanning electron microscopy(SEM).After oxidation at 800℃,a thin and adherent oxide layer was formed on the surface of the coating.With increasing exposure temperature,the thickness of the oxide layer increased;and at 1 000℃the oxide layer separated from the coating.Investigation of the kinetics of oxidation by using the thermogravimetric analysis(TGA)technique shows a parabolic oxidation rate.展开更多
As the influence of the ratio of the characteristic value of structural resistance to that of frequent combination effect, K, on the thickness of concrete cover of prestressed concrete (PC) beams and slabs for fire ...As the influence of the ratio of the characteristic value of structural resistance to that of frequent combination effect, K, on the thickness of concrete cover of prestressed concrete (PC) beams and slabs for fire resistance is not considered sufficiently in design criteria for concrete structures in China and other countries at present, numerical analyses were carried out by ANSYS software on unbonded prestressed concrete (UPC) oneway simply-supported and continuous slabs and beams, and bonded PC simply-supported and continuous beams subjected to fire in 186 cases. In the analysis, K, section dimensions and the thickness of concrete cover are regarded as independent variables and some calculation parameters determined by trial and error based on test resuits. Calculation formula for fire endurance of UPC simply-supported and continuous slabs was proposed, and the recommended thicknesses of cover of PC beams and slabs was presented in consideration of the influence of K and section dimensions as well as fire endurance requirements. Comparison analysis of relevant design criterions in China and other countries was performed to verify the rationale of the proposed values.展开更多
文摘Oxidation behaviors of Ni(Cr)-TiB2 coating deposited by HVOF technique were studied at 800,900 and 1 000℃in air. The microstructures of as-sprayed and oxidized coatings were characterized by X-ray diffractometry(XRD)and scanning electron microscopy(SEM).After oxidation at 800℃,a thin and adherent oxide layer was formed on the surface of the coating.With increasing exposure temperature,the thickness of the oxide layer increased;and at 1 000℃the oxide layer separated from the coating.Investigation of the kinetics of oxidation by using the thermogravimetric analysis(TGA)technique shows a parabolic oxidation rate.
基金Sponsored by the National Natural Science Foundation of China(Grant No.50678050)the Outstanding Youth Science Foundation of Heilongjiang Province(Grant No.2001-8)
文摘As the influence of the ratio of the characteristic value of structural resistance to that of frequent combination effect, K, on the thickness of concrete cover of prestressed concrete (PC) beams and slabs for fire resistance is not considered sufficiently in design criteria for concrete structures in China and other countries at present, numerical analyses were carried out by ANSYS software on unbonded prestressed concrete (UPC) oneway simply-supported and continuous slabs and beams, and bonded PC simply-supported and continuous beams subjected to fire in 186 cases. In the analysis, K, section dimensions and the thickness of concrete cover are regarded as independent variables and some calculation parameters determined by trial and error based on test resuits. Calculation formula for fire endurance of UPC simply-supported and continuous slabs was proposed, and the recommended thicknesses of cover of PC beams and slabs was presented in consideration of the influence of K and section dimensions as well as fire endurance requirements. Comparison analysis of relevant design criterions in China and other countries was performed to verify the rationale of the proposed values.