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LaMeAl_(11)O_(19)/YSZ热障涂层热力学性能和热循环寿命
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作者 蔚海浪 曹学强 +1 位作者 邓龙辉 蒋佳宁 《无机材料学报》 SCIE EI CAS CSCD 北大核心 2022年第12期1259-1266,共8页
LaMeAl_(11)O_(19)陶瓷具有独特的晶体结构,优异的热力学性能,低热导率,高温相稳定性等特点,是一类非常有应用前景的热障涂层(TBC)材料。本研究通过大气等离子喷涂(APS)制备了LaMeAl_(11)O_(19)/YSZ(Me=Mg,Cu,Zn)双陶瓷层热障涂层。通... LaMeAl_(11)O_(19)陶瓷具有独特的晶体结构,优异的热力学性能,低热导率,高温相稳定性等特点,是一类非常有应用前景的热障涂层(TBC)材料。本研究通过大气等离子喷涂(APS)制备了LaMeAl_(11)O_(19)/YSZ(Me=Mg,Cu,Zn)双陶瓷层热障涂层。通过对涂层进行火焰热循环测试并结合扫描电子显微镜、X射线衍射仪等分析技术对涂层进行失效分析。结果表明,LaMgAl_(11)O_(19)(LMA)、LaZnAl_(11)O_(19)(LZA)和LaCuAl_(11)O_(19)(LCA)粉末在等离子喷涂过程中发生了分解,导致三种涂层中磁铅石相含量的差异,从而影响三种涂层的热循环寿命。由于LaMeAl_(11)O_(19)层与YSZ层的热膨胀系数不匹配以及非晶相重结晶产生的体积收缩,LaMeAl_(11)O_(19)层从YSZ层上剥落。YSZ层暴露在高温下,加速了烧结和TGO的生长,又促进了YSZ层剥落。低温下,LaMeAl_(11)O_(19)的热导率随着Me原子序数增加而降低;高温下,与LMA和LZA相比,LCA涂层红外发射率最高(0.88,600℃),削弱了光子传导对热导率的贡献,导致热导率降低,LCA在高温红外辐射涂层中具有潜在的应用价值。 展开更多
关键词 热障涂层 磁铅石型稀土六铝酸盐 火焰热循环 热力学性能
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Effects of wall thickness and material on flame stability in a planar micro-combustor 被引量:1
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作者 LIU Lei ZHAO Liang FAN Ai-wu 《Journal of Central South University》 SCIE EI CAS CSCD 2019年第8期2224-2233,共10页
Flame is prone to lose its stability in micro-combustors due to the large amount of heat loss from the external walls. On the other hand, heat recirculation through the upstream combustor walls can enhance flame stabi... Flame is prone to lose its stability in micro-combustors due to the large amount of heat loss from the external walls. On the other hand, heat recirculation through the upstream combustor walls can enhance flame stability. These two aspects depend on the structural heat transfer, which is associated with the thickness and thermal conductivity of the combustor walls. In the present study, the effects of wall thickness and material on flame stability were numerically investigated by selecting two thicknesses (δ=0.2 and 0.4 mm) and two materials (quartz and SiC). The results show that when δ=0.2 mm, flame inclination occurs at a certain inlet velocity in both combustors, but it happens later in SiC combustor. For δ=0.4 mm, flame inclination still occurs in quartz combustor from a larger inlet velocity compared to the case of δ=0.2 mm. However, flame inclination in SiC combustor with δ=0.4 mm does not happen and it has a much larger blowout limit. Analysis reveals that a thicker wall can enhance heat recirculation and reduce heat loss simultaneously. Moreover, SiC combustor has larger heat recirculation ratio and smaller heat loss ratio. In summary, the micro-combustor with thicker and more conductive walls can harvest large flame stability limit. 展开更多
关键词 MICRO-COMBUSTOR flame stability flame inclination blowout limit heat recirculation heat loss
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