天然气添加氢气燃烧特性研究

本文介绍了当前国内外关于天然气掺入氢气燃烧特性的研究，阐述了天然气添加氢气后的理论空气量、燃料和空气当量比的计算方法，并综合分析了氢气对混合燃气燃烧稳定性，火焰结构，火焰传播速度，NOx和CO2生成的影响。

Recent Advances in Flame Tomography

To reduce greenhouse gas emissions from fossil fuel fired power plants,a range of new combustion technologies are being developed or refined,including oxy-fuel combustion,co-firing biomass with coal and fluidized bed combustion.Flame characteristics under such combustion conditions are expected to be different from those in normal air fired combustion processes.Quantified flame characteristics such as temperature distribution,oscillation frequency,and ignition volume play an important part in the optimized design and operation of the environmentally friendly power generation systems.However,it is challenging to obtain such flame characteristics particularly through a three-dimensional and non-intrusive means.Various tomography methods have been proposed to visualize and characterize flames,including passive optical tomography,laser based tomography,and electrical tomography.This paper identifies the challenges in flame tomography and reviews existing techniques for the quantitative characterization of flames.Future trends in flame tomography for industrial applications are discussed.

Evaluation on Combustion Characteristics of Finishing Materials for Exterior Walls

Existing fire test methods reply on measurement of the energy released rate to identify the combustion properties of a material. However, they are inadequate when assessing combustion characteristics of a composite material characterized by vertical flame spread and different inside/outside combustion behaviors. In addition, major factors that affect the flame spread outside the building include the combustion characteristics of materials used as well as air flow around a skyscraper. However, since it is highly difficult to analyze and forecast the air flow from a fire engineering viewpoint, an investigation of the flame spread characteristics of exterior walls of a building depends primarily on the combustion characteristics of materials. Hence, this study examined, using ISO 13785-2 testing method, the temperature changes and vertical flame spread behaviors of one of the finishing materials for exterior walls--（generic ＆ fire-resistant） aluminium panels by a real-scale combustion experiment. According to the results of real-scale experiment, the maximum heat temperature of 987.7 ℃ was recorded seven minutes after the fire test was initiated while the fire-resistant aluminium panels showed the maximum heat temperature of 850.2℃ after exposed for approximately 12 min. The vertical flame spread properties put more emphasis on the time required to reach the maximum temperature rather than its magnitude and there was a five minutes difference between the materials.

Emission Characteristics and Axial Flame Temperature Distribution of a Circumferential Reverse Flow Combustor

In partially premixed combustion of gas turbine, the combustion temperature should be lowed in order to reduce NOx. One solution is lean premixed combustion. However, the problem is that large excess air ratio may make the combustion unstable. A novel combustor with circumferential reverse flow of fuel gas is proposed for settling this problem. A 10 kw furnace is established to test performance of this combustor. Three factors such as primary air ratio, position of secondary air, total excess air ratio are studied. The emission characteristics and axial flame temperature distribution are studied. Basing on experimental results, the axial flame temperature and NOr emission increase with primary air ratio and axial length of second stream, and decrease with total excess air ratio. When the total excess air ratio is larger than 1.05, the combustor presents a lower temperature field and much lower NOx emission （less than 10 ppm）.

Investigation of non-premixed flame combustion characters in GO_2/GH_2 shear coaxial injectors using non-intrusive optical diagnostics

Single-element combustor experiments are conducted for three shear coaxial geometry configuration injectors by using gaseous oxygen and gaseous hydrogen(GO2/GH2) as propellants. During the combustion process, several spatially and time- resolved non-intrusive optical techniques, such as OH planar laser induced fluorescence(PLIF), high speed imaging, and infrared imaging, are simultaneously employed to observe the OH radical concentration distribution, flame fluctuations, and temperature fields. The results demonstrate that the turbulent flow phenomenon of non-premixed flame exhibits a remarkable periodicity, and the mixing ratio becomes a crucial factor to influence the combustion flame length. The high speed and infrared images have a consistent temperature field trend. As for the OH-PLIF images, an intuitionistic local flame structure is revealed by single-shot instantaneous images. Furthermore, the means and standard deviations of OH radical intensity are acquired to provide statistical information regarding the flame, which may be helpful for validation of numerical simulations in future. Parameters of structure configurations, such as impinging angle and oxygen post thickness, play an important role in the reaction zone distribution. Based on a successful flame contour extraction method assembled with non-linear anisotropic diffusive filtering and variational level-set, it is possible to implement a fractal analysis to describe the fractal characteristics of the non-premixed flame contour. As a result, the flame front cannot be regarded as a fractal object. However, this turbulent process presents a self-similarity characteristic.

Free Radical Imaging Techniques Applied to Hydrocarbon Flames Diagnosis

This paper evaluates the utilization of the radical chemiluminesecnce imaging and tomographic reconstruction techniques to assess advanced information on reacting flows. Two different laboratory flow configurations were analyzed, including unconfined non-premixed jet flame measurements to evaluate name fuel/air mixing patterns at the burner-port of a typical glass-furnace burner. The second case characterized the reaction zone of premixed flames within gas turbine combustion chambers, based on a laboratory scale model of a lean prevaporized premixed (LPP) combustion chamber. The analysis shows that advanced imaging diagnosis can provide new information on the characterization of flame mixing and reacting phenomena. The utilization of local C2 and CH chemiluminescence can assess useful information on the quality of the combustion process, which can be used to improve the design of practical combustors.

The constant-volume propagating spherical flame method for laminar flame speed measurement

Laminar flame speed is one of the most important intrinsic properties of a combustible mixture. Due to its importance, different methods have been developed to measure the laminar flame speed. This paper reviews the constant-volume propagating spherical flame method for laminar flame speed measurement. This method can be used to measure laminar flame speed at high pressures and temperatures which are close to engine-relevant conditions. First, the propagating spherical flame method is introduced and the constant-volume method （CVM） and constant- pressure method （CPM） are compared. Then, main groups using the constant-volume propagating spherical flame method are introduced and large discrepancies in laminar flame speeds measured by different groups for the same mixture are identified. The sources of discrepancies in laminar flame speed measured by CVM are discussed and special attention is devoted to the error encountered in data processing. Different correlations among burned mass fraction, pressure, temperature and flame speed, which are used by different researchers to obtain laminar flame speed, are summarized. The performance of these correlations are examined, based on which recommendations are given. Finally, recommendations for future studies on the con- stant-volume propagating spherical flame method for laminar flame speed measurement are presented.

Asymptotic Analysis of Transport Properties and Burning Velocities for Premixed Hydrocarbon Flames

Based on premixed flame, the theoretical model of transport properties with temperature variation was established inside a preheated zone. Lewis number of the deficient-to- stoichiometric hydrocarbon/air mixture has been theoretically predicted over a wide range of preheated temperature. These predictions are compared with the experimental data on disport properties that exist in the literature. The response of the burning velocity to flame stretch can be parameterized by the laminar flame speed and Markstein length. Therefore, if the laminar flame speed and Markstein number could be accurately simulated by using an analytic expression of characterized temperature, equivalence ratio, and Lewis number, the results are applicable to the prediction of methane, acetylene, ethylene, ethane, and propane flames. Expanding previous studies on the extinction of premixed flames under the influence of stretch and incomplete reaction, the results were further classified and rescaled. Finally, it could be inferred that parameter Pq, the rescaled extinction Karlovitz number could be used to explain the degree or flame quench.

Combustion Stabilization based on a Center Flame Strut in a Liquid Kerosene Fueled Supersonic Combustor

A newly designed strut is proposed in this paper for fuel injection and flame holding in a liquid-kerosene-fueled supersonic combustor. The thickness of the strut is 8ram and the front blockage is about 8%. The characteristic of this strut is that extra oxygen can be injected through a set of orifices at the back of the strut, which can change the local flow field structure and ER （Equivalence Ratio）. Based on the above mentioned strut, a stable local flame is generated at the back of the strut and the main combustion can be organized around this local fire. Nu- merical simulation is conducted to compare the local flow field distribution at the back of the strut with/without extra oxygen injection. Experiments are conducted to test the combustion characteristics based on this fuel injec- tion and flame holding strategy. The temperature distribution which can reflect the local flame characteristic has been measured in the experiments conducted under cold incoming supersonic air flow condition. In addition, the overall combustion performance in a full-scale supersonic combustor has been evaluated in the experiments con- ducted under hot incoming supersonic air flow condition. Results show that this strut strategy is very promising since it can organize stable supersonic combustion at the center of the combustor without any cavity or rearward facing step. Besides that, even with the 8ram thick strut, the combustion can be stable in a wide range of ER from 0.25-1 by using liquid room-temperature kerosene.