Ignition timing control is of great importance in homogeneous charge compression ignition engines. The effect of hydrogen addition on methane combustion was investigated using a CHEMKIN multi-zone model. Results show ...Ignition timing control is of great importance in homogeneous charge compression ignition engines. The effect of hydrogen addition on methane combustion was investigated using a CHEMKIN multi-zone model. Results show that hydrogen addition advances ignition tim- ing and enhances peak pressure and temperature. A brief analysis of chemical kinetics of methane blending hydrogen is also performed in order to investigate the scope of its appli- cation, and the analysis suggests that OH radical plays an important role in the oxidation. Hydrogen addition increases NOx while decreasing HC and CO emissions. Exhaust gas recir- culation （EGR） also advances ignition timing; however, its effects on emissions are generally the opposite. By adjusting the hydrogen addition and EGR rate, the ignition timing can be regulated with a low emission level. Investigation into zones suggests that NOx is mostly formed in core zones while HC and CO mostly originate in the crevice and the quench layer.展开更多
The flame propagation of methane-air mixture with various methane concen-trations was experimentally investigated at venting flame acceleration tube with quad-rate cross section under different obstacles presented. Th...The flame propagation of methane-air mixture with various methane concen-trations was experimentally investigated at venting flame acceleration tube with quad-rate cross section under different obstacles presented. The flame shape and propaga-tion speed was observed by high-speed color video camera. The explosion pressure was determined by piezoelectricity pressure transducers. The results are: The flame propagates in the shape of a hemisphere before the flame reaches the first baffle and flame propagation speed is not more than 15 m/s. When the flame propagates across the baffle, the flame begins to accelerate due to turbulence induced by obstacle. Blockage ratio has relatively greater effect on the flame propagation speed than re-peated baffle number does. The flame propagation speed and the pressure at different location along the tube are maximum when methane-air mixture is near the chemical stoichoimetric ratio. The pressure increases with the distance from ignition end at first and the maximum pressure was obtained at the middle of tube, but the pressure de-creases and again increases at venting end.展开更多
In this study, a series of flame-retardant polyisocyanurate-polyurethane (PIR-PUR) foams were prepared using various concentrations (0-25% by weight) of expandable graphite (EG) and dimethyl methyl phosphonate (DMMP) ...In this study, a series of flame-retardant polyisocyanurate-polyurethane (PIR-PUR) foams were prepared using various concentrations (0-25% by weight) of expandable graphite (EG) and dimethyl methyl phosphonate (DMMP) (0-7% by weight). The effect of these additives on the properties of the PIR-PUR foams, including physico-mechanical, morphological, flame retardancy, and thermal stability, was studied. Increasing amounts of EG in the PIR-PUR foam caused a significant drop in the compression strength. However, DMMP caused the mechanical properties of PIR-PUR foam to improve compared to foam filled with EG alone. The flame retardancy of PIR-PUR foams containing both EG and DMMP was enhanced significantly compared to EG filled foams. Thermogravimetric analysis (TGA) indicated that EG enhances the thermal stability of PIR-PUR foams but that DMMP decreased it. The morphology of the residual char provided conclusive evidence for the weak thermal stability of foams filled with DMMP.展开更多
To research the characteristics of vented explosion of methane-air mixture in the pipeline,coal mine tunnel or other closed space,the experiments and numerical simulations were carried out.In this work,explosion chara...To research the characteristics of vented explosion of methane-air mixture in the pipeline,coal mine tunnel or other closed space,the experiments and numerical simulations were carried out.In this work,explosion characteristics and flame propagation characteristics of methane in pipeline and coal mine tunnel are studied by using an explosion test system,combined with FLACS software,under different vented conditions.The numerical simulation results of methane explosion are basically consistent with the physical experiment results,which indicates that the numerical simulation for methane explosion is reliable to be applied to the practice.The results show that explosion parameters(pressure,temperature and product concentration)of methane at five volume fractions have the same change trend.Nevertheless,the explosion intension of 10.0%methane is the largest and that of 9.5%methane is relatively weak,followed by 11.0%methane,8.0%methane and 7.0%methane respectively.Under different vented conditions,the pressure and temperature of methane explosion are the highest in the pipeline without a vent,followed by the pipeline where ignition or vent position is in each end,and those are the lowest in the pipeline with ignition and vent at the same end.There is no significant effect on final product concentration of methane explosion under three vented conditions.For coal mine tunnel,it is indicated that the maximum explosion pressure at the airproof wall in return airway with the branch roadway at 50 m from goaf is significantly decreased while that in intake airway does not change overwhelmingly.In addition,when the branch roadway is longer or its section is larger,the peak pressure of airproof wall reduces slightly.展开更多
A numerical study on premixed methane/ethylene/air flames with various ethylene fractions and equivalence ratios was conducted at room temperature and atmospheric pressure. The effects of ethylene addition on laminar ...A numerical study on premixed methane/ethylene/air flames with various ethylene fractions and equivalence ratios was conducted at room temperature and atmospheric pressure. The effects of ethylene addition on laminar burning velocity, flame structure and flame stability under the condition of lean burning were investigated. The results show that the laminar burning velocity increases with ethylene fraction, especially at a large equivalence ratio. More ethylene addition gives rise to higher concentrations of H, O and OH radicals in the flame, which significantly promotes chemical reactions, and a linear correlation exists between the laminar burning velocity and the maximum H + OH concentration in the reaction zone. With the increase of ethylene fraction, the adiabatic flame temperature is raised, while the inner layer temperature becomes lower, contributing to the enhancement of combustion. Markstein length and Markstein number, representative of the flame stability, increase as more ethylene is added, indicating the tendency of flame stability to improve with ethylene addition.展开更多
A 500 N model engine filled with LO2/GCH4 was designed and manufactured.A series of ignition attempts were performed in it by both head spark plug and body spark plug.Results show that the engine can be ignited but th...A 500 N model engine filled with LO2/GCH4 was designed and manufactured.A series of ignition attempts were performed in it by both head spark plug and body spark plug.Results show that the engine can be ignited but the combustion cannot be sustained when head spark plug applied as the plug tip was set in the gaseous low-velocity zone with thin spray.This is mainly because flame from this zone cannot supply enough ignition energy for the whole chamber.However,reliable ignition and stable combustion can be achieved by body spark plug.As the O/F ratio increases from 2.61 to 3.49,chamber pressure increases from 0.474 to 0.925 MPa and combustion efficiency increases from 57.8%to 95.1%.This is determined by the injector configuration,which cannot produce the sufficiently breakup of the liquid oxygen on the low flow rate case.展开更多
To investigate the flame and overpressure characteristics of methane–air explosion with different obstacle configurations,an experimental study has been conducted,taking account of the number of obstacles,obstacle di...To investigate the flame and overpressure characteristics of methane–air explosion with different obstacle configurations,an experimental study has been conducted,taking account of the number of obstacles,obstacle distance from ignition source,and stream-wise and cross-wise obstacle positions.The results show that the flame speed and peak overpressure increase with the increasing number of obstacles,while the time to reach the peak is not fully determined by it.And the configuration having the farthest obstacle produces a higher overpressure and takes a longer time to reach the peak,but a slower flame propagation speed is obtained.Similar explosion characteristics are also observed in the configurations with two obstacles fixed at different stream-wise positions.Furthermore,the experimental results demonstrate that the peak overpressures and flame speeds in configurations with central or staggered obstacles are relatively higher,which should to be avoided in practical processes to minimize the risk associated with methane–air explosion.展开更多
Turbulent non-premixed combustion of gaseous fuels is of importance for many technical applications, especially for the steel and refractory industry. Accurate turbulent flow and temperature fields are of major import...Turbulent non-premixed combustion of gaseous fuels is of importance for many technical applications, especially for the steel and refractory industry. Accurate turbulent flow and temperature fields are of major importance in order to predict details on the concentration fields. The performances of the GRI-Mech 3.0 and the Jones and Lindstedt mechanisms are compared. Detailed chemistry is included with the GRI-Mech 3.0 and J-L kinetic mechanisms in combination with the laminar flamelet combustion model. The combustion system selected for this comparison is a confined non-premixed methane flame surrounded by co-flowing air The simulation results are compared with experimental data of Lewis and Smoot （2001）.展开更多
基金This work was supported by the Natural Science Foundation of Anhui Province （No.090412030）.
文摘Ignition timing control is of great importance in homogeneous charge compression ignition engines. The effect of hydrogen addition on methane combustion was investigated using a CHEMKIN multi-zone model. Results show that hydrogen addition advances ignition tim- ing and enhances peak pressure and temperature. A brief analysis of chemical kinetics of methane blending hydrogen is also performed in order to investigate the scope of its appli- cation, and the analysis suggests that OH radical plays an important role in the oxidation. Hydrogen addition increases NOx while decreasing HC and CO emissions. Exhaust gas recir- culation （EGR） also advances ignition timing; however, its effects on emissions are generally the opposite. By adjusting the hydrogen addition and EGR rate, the ignition timing can be regulated with a low emission level. Investigation into zones suggests that NOx is mostly formed in core zones while HC and CO mostly originate in the crevice and the quench layer.
文摘The flame propagation of methane-air mixture with various methane concen-trations was experimentally investigated at venting flame acceleration tube with quad-rate cross section under different obstacles presented. The flame shape and propaga-tion speed was observed by high-speed color video camera. The explosion pressure was determined by piezoelectricity pressure transducers. The results are: The flame propagates in the shape of a hemisphere before the flame reaches the first baffle and flame propagation speed is not more than 15 m/s. When the flame propagates across the baffle, the flame begins to accelerate due to turbulence induced by obstacle. Blockage ratio has relatively greater effect on the flame propagation speed than re-peated baffle number does. The flame propagation speed and the pressure at different location along the tube are maximum when methane-air mixture is near the chemical stoichoimetric ratio. The pressure increases with the distance from ignition end at first and the maximum pressure was obtained at the middle of tube, but the pressure de-creases and again increases at venting end.
基金supported by the State Key Program of Coal Joint Funds of National Natural Science Foundation of China (No.51134020)the Natural Science Foundation of Shandong Province(No. ZR2011EL036)the High School Science & Technology Fund Planning Project of Shandong Province (No. JIILD53)
文摘In this study, a series of flame-retardant polyisocyanurate-polyurethane (PIR-PUR) foams were prepared using various concentrations (0-25% by weight) of expandable graphite (EG) and dimethyl methyl phosphonate (DMMP) (0-7% by weight). The effect of these additives on the properties of the PIR-PUR foams, including physico-mechanical, morphological, flame retardancy, and thermal stability, was studied. Increasing amounts of EG in the PIR-PUR foam caused a significant drop in the compression strength. However, DMMP caused the mechanical properties of PIR-PUR foam to improve compared to foam filled with EG alone. The flame retardancy of PIR-PUR foams containing both EG and DMMP was enhanced significantly compared to EG filled foams. Thermogravimetric analysis (TGA) indicated that EG enhances the thermal stability of PIR-PUR foams but that DMMP decreased it. The morphology of the residual char provided conclusive evidence for the weak thermal stability of foams filled with DMMP.
基金Project(51674193)supported by the National Natural Science Foundation of ChinaProject(2019-JLM-9)supported by the Natural Science Foundation of Shaanxi Province,ChinaProject(2019-M-663780)supported by the Postdoctoral Science Foundation,China。
文摘To research the characteristics of vented explosion of methane-air mixture in the pipeline,coal mine tunnel or other closed space,the experiments and numerical simulations were carried out.In this work,explosion characteristics and flame propagation characteristics of methane in pipeline and coal mine tunnel are studied by using an explosion test system,combined with FLACS software,under different vented conditions.The numerical simulation results of methane explosion are basically consistent with the physical experiment results,which indicates that the numerical simulation for methane explosion is reliable to be applied to the practice.The results show that explosion parameters(pressure,temperature and product concentration)of methane at five volume fractions have the same change trend.Nevertheless,the explosion intension of 10.0%methane is the largest and that of 9.5%methane is relatively weak,followed by 11.0%methane,8.0%methane and 7.0%methane respectively.Under different vented conditions,the pressure and temperature of methane explosion are the highest in the pipeline without a vent,followed by the pipeline where ignition or vent position is in each end,and those are the lowest in the pipeline with ignition and vent at the same end.There is no significant effect on final product concentration of methane explosion under three vented conditions.For coal mine tunnel,it is indicated that the maximum explosion pressure at the airproof wall in return airway with the branch roadway at 50 m from goaf is significantly decreased while that in intake airway does not change overwhelmingly.In addition,when the branch roadway is longer or its section is larger,the peak pressure of airproof wall reduces slightly.
基金Supported by the National Natural Science Foundation of China (51176181)the National Basic Research Program of China (2012CB719704)
文摘A numerical study on premixed methane/ethylene/air flames with various ethylene fractions and equivalence ratios was conducted at room temperature and atmospheric pressure. The effects of ethylene addition on laminar burning velocity, flame structure and flame stability under the condition of lean burning were investigated. The results show that the laminar burning velocity increases with ethylene fraction, especially at a large equivalence ratio. More ethylene addition gives rise to higher concentrations of H, O and OH radicals in the flame, which significantly promotes chemical reactions, and a linear correlation exists between the laminar burning velocity and the maximum H + OH concentration in the reaction zone. With the increase of ethylene fraction, the adiabatic flame temperature is raised, while the inner layer temperature becomes lower, contributing to the enhancement of combustion. Markstein length and Markstein number, representative of the flame stability, increase as more ethylene is added, indicating the tendency of flame stability to improve with ethylene addition.
基金Project(613239)supported by the National Basic Research Program of China
文摘A 500 N model engine filled with LO2/GCH4 was designed and manufactured.A series of ignition attempts were performed in it by both head spark plug and body spark plug.Results show that the engine can be ignited but the combustion cannot be sustained when head spark plug applied as the plug tip was set in the gaseous low-velocity zone with thin spray.This is mainly because flame from this zone cannot supply enough ignition energy for the whole chamber.However,reliable ignition and stable combustion can be achieved by body spark plug.As the O/F ratio increases from 2.61 to 3.49,chamber pressure increases from 0.474 to 0.925 MPa and combustion efficiency increases from 57.8%to 95.1%.This is determined by the injector configuration,which cannot produce the sufficiently breakup of the liquid oxygen on the low flow rate case.
基金supported by the National Natural Science Foundation of China (Nos.51106044 and 51176021)the Research Foundation of Education Bureau of Henan Province of China (No.14A410007)
文摘To investigate the flame and overpressure characteristics of methane–air explosion with different obstacle configurations,an experimental study has been conducted,taking account of the number of obstacles,obstacle distance from ignition source,and stream-wise and cross-wise obstacle positions.The results show that the flame speed and peak overpressure increase with the increasing number of obstacles,while the time to reach the peak is not fully determined by it.And the configuration having the farthest obstacle produces a higher overpressure and takes a longer time to reach the peak,but a slower flame propagation speed is obtained.Similar explosion characteristics are also observed in the configurations with two obstacles fixed at different stream-wise positions.Furthermore,the experimental results demonstrate that the peak overpressures and flame speeds in configurations with central or staggered obstacles are relatively higher,which should to be avoided in practical processes to minimize the risk associated with methane–air explosion.
文摘Turbulent non-premixed combustion of gaseous fuels is of importance for many technical applications, especially for the steel and refractory industry. Accurate turbulent flow and temperature fields are of major importance in order to predict details on the concentration fields. The performances of the GRI-Mech 3.0 and the Jones and Lindstedt mechanisms are compared. Detailed chemistry is included with the GRI-Mech 3.0 and J-L kinetic mechanisms in combination with the laminar flamelet combustion model. The combustion system selected for this comparison is a confined non-premixed methane flame surrounded by co-flowing air The simulation results are compared with experimental data of Lewis and Smoot （2001）.
