Nowadays, lighting design is the modern attractive field of professional activity. Although its theoretical and methodological bases are in the initial stage of formulation. Though there are standards for regulating i...Nowadays, lighting design is the modern attractive field of professional activity. Although its theoretical and methodological bases are in the initial stage of formulation. Though there are standards for regulating illumination quantitatively, the science has never created a bridge to transfer illumination quantity into illumination quality. How to keep a day image of architectural object without imitating natural lighting？ How unrecognizably to change the image, to make it extraordinary and catchy？ This paper offers a solution in the form of external illumination designing principles. This paper proposes two conceptual ways of creating artificial lighting of buildings and constructions that pursue different goals： the principle of ＂tectonic＂ illumination and the principle of ＂decorative＂ illumination. These principles were developed based on the analysis of the state of the art experience of lighting architectural objects and author＇s empirical study. The latter contained measuring luminosity with luminance meter, processing the data, statistical survey （180 respondents） and lighting modeling in the laboratory of Moscow Architectural Institute.展开更多
In this paper, thermal characteristics of the high-power LED spot lamp are reported. The emphasis is placed upon optimizing design of the heat sink of LED spot lamp using the optimization module and the orthogonal-exp...In this paper, thermal characteristics of the high-power LED spot lamp are reported. The emphasis is placed upon optimizing design of the heat sink of LED spot lamp using the optimization module and the orthogonal-experiment method. Results demonstrate that the weight of the heat sink is decreased to 46.1% of that for the initial structure, and the influence of each factor on junction temperature and weight of the heat sink is acquired by range analysis. Finally, the influence of ambient temperature and natural convection coefficient on the LED maximum temperature is analyzed. The results and the optimizing methodology are of great importance to the thermal design of LED lamps.展开更多
Modification of classic fluorophore to possess the emission transitions between aggregation-induced emission （ALE） and intrinsic emission offers reliable approach to the design of ratiometric fluorescent sensors. In...Modification of classic fluorophore to possess the emission transitions between aggregation-induced emission （ALE） and intrinsic emission offers reliable approach to the design of ratiometric fluorescent sensors. In this study, a proton acceptor benzimidazole was integrated with BODIPY to form three compounds, BBI-1/2/3, which demonstrated the AIE （-595 nm, Iagg） in neutral aqueous medium and intrinsic BODIPY emission （-510 nm,Iint） in acidic medium. All the three showed the ratiometric pH sensing behavior in a dual excitation/dual emission mode, yet BBI-3 displayed still the dual emission ratiometric pH sensing ability. The pH-dependent emission ratio/int/Iagg of the three were fully reversible, and no interference was observed from normal abundant chemical species in live cells. Their different pKa （BBI-1, pKa 4.4; BBI-2, pKa 2.7; BBI-3, pKa 3.6） suggested that the substituents on benzimidazole moiety were essential to govern their functioning pH range. The ratiometric imaging of BBI-1 in A549 cells provided an effective intracellular pH （pHi） calibration formula corresponding to emission ratio oflJ Iint/Iagg. Ratiometric pH imaging in A549 cells upon small particle exposure confirmed the particle-induced cellular acidification with this formula. Both particle size and the chemical nature of the particle contribute to the observed acidification effect. The synchronization of lysosome disruption to cellular acidification in A549 cells upon crystalline silica exposure was directly observed for the first time with BBI-1, showing the potential application of BBI-1 in the study of silicosis and other related diseases. This study de- monstrated that endowing fluorophore with AIE/intrinsic emission transition could be a promising strategy for ratiometric sensor design.展开更多
文摘Nowadays, lighting design is the modern attractive field of professional activity. Although its theoretical and methodological bases are in the initial stage of formulation. Though there are standards for regulating illumination quantitatively, the science has never created a bridge to transfer illumination quantity into illumination quality. How to keep a day image of architectural object without imitating natural lighting？ How unrecognizably to change the image, to make it extraordinary and catchy？ This paper offers a solution in the form of external illumination designing principles. This paper proposes two conceptual ways of creating artificial lighting of buildings and constructions that pursue different goals： the principle of ＂tectonic＂ illumination and the principle of ＂decorative＂ illumination. These principles were developed based on the analysis of the state of the art experience of lighting architectural objects and author＇s empirical study. The latter contained measuring luminosity with luminance meter, processing the data, statistical survey （180 respondents） and lighting modeling in the laboratory of Moscow Architectural Institute.
基金supported by the Natural Science Foundation of Zhejiang Province (No.Y104436)the Science and Technology Fund Projects of Zhejiang Province (No.2008C21158)the Innovative Basement Project of Graduate Education of Zhejiang Province
文摘In this paper, thermal characteristics of the high-power LED spot lamp are reported. The emphasis is placed upon optimizing design of the heat sink of LED spot lamp using the optimization module and the orthogonal-experiment method. Results demonstrate that the weight of the heat sink is decreased to 46.1% of that for the initial structure, and the influence of each factor on junction temperature and weight of the heat sink is acquired by range analysis. Finally, the influence of ambient temperature and natural convection coefficient on the LED maximum temperature is analyzed. The results and the optimizing methodology are of great importance to the thermal design of LED lamps.
基金supported by the National Basic Research Program of China (2015CB856300)the National Natural Science Foundation of China (21571099, 21731004)the Natural Science Foundation of Jiangsu Province (BK20150054)
文摘Modification of classic fluorophore to possess the emission transitions between aggregation-induced emission （ALE） and intrinsic emission offers reliable approach to the design of ratiometric fluorescent sensors. In this study, a proton acceptor benzimidazole was integrated with BODIPY to form three compounds, BBI-1/2/3, which demonstrated the AIE （-595 nm, Iagg） in neutral aqueous medium and intrinsic BODIPY emission （-510 nm,Iint） in acidic medium. All the three showed the ratiometric pH sensing behavior in a dual excitation/dual emission mode, yet BBI-3 displayed still the dual emission ratiometric pH sensing ability. The pH-dependent emission ratio/int/Iagg of the three were fully reversible, and no interference was observed from normal abundant chemical species in live cells. Their different pKa （BBI-1, pKa 4.4; BBI-2, pKa 2.7; BBI-3, pKa 3.6） suggested that the substituents on benzimidazole moiety were essential to govern their functioning pH range. The ratiometric imaging of BBI-1 in A549 cells provided an effective intracellular pH （pHi） calibration formula corresponding to emission ratio oflJ Iint/Iagg. Ratiometric pH imaging in A549 cells upon small particle exposure confirmed the particle-induced cellular acidification with this formula. Both particle size and the chemical nature of the particle contribute to the observed acidification effect. The synchronization of lysosome disruption to cellular acidification in A549 cells upon crystalline silica exposure was directly observed for the first time with BBI-1, showing the potential application of BBI-1 in the study of silicosis and other related diseases. This study de- monstrated that endowing fluorophore with AIE/intrinsic emission transition could be a promising strategy for ratiometric sensor design.
