Rare earth element （REE） concentrations were measured by ICP-MS for groundwater collected from deep seated Taiyuan Fm limestone aquifer （from -400 to -530 m） in Renlou Coal Mine, northern Anhui Province, China. It...Rare earth element （REE） concentrations were measured by ICP-MS for groundwater collected from deep seated Taiyuan Fm limestone aquifer （from -400 to -530 m） in Renlou Coal Mine, northern Anhui Province, China. It can be concluded that the groundwater is warm （34.0-37.2 ℃） C1-Ca, Na type water with circum-neutral pH （7.35-8.28） and high total dissolved solids （TDS, 1 746-2 849 mg/L）. The groundwater exhibits heavy REEs enrichment relative to light REEs compared with Post Archean Average Shale （PAAS）, as well as their aquifer rocks （limestone）. The enrichment of REEs is considered to be controlled by terrigeneous materials （e.g. zircon） in aquifer rocks, whereas the fractionation of REEs is controlled by marine derived materials （e.g. calcite）, to a less extent, terrigeneous materials and inorganic complexation. The Ce anomalies normalized to PAAS and aquifer rocks are weak, which probably reflects the signature of the aquifer rock rather than redox conditions or pH. The similarities of REE patterns between groundwater and aquifer rocks imply that aquifer rocks play important roles in controlling the REE characteristics of groundwater, and then provide a probability for discrimination of groundwater sources by using REEs.展开更多
In a karst tunnel, fissures or cracks that are filled with weathered materials are a type of potential water outlet as they are easily triggered and converted into groundwater outlets under the influence of high groun...In a karst tunnel, fissures or cracks that are filled with weathered materials are a type of potential water outlet as they are easily triggered and converted into groundwater outlets under the influence of high groundwater pressure. A terrible water inrush caused by potential water outlets can seriously hinder the project construction. Potential water outlets and water sources that surrounding the tunnel must be detected before water inflow can be treated. This paper provides a successful case of the detection and treatment of water inflow in a karst tunnel and proposes a potential water outlet detection(PWOD) method in which heavy rainfall(>50 mm/d) is considered a trigger for a potential water outlet. The Daba tunnel located in Hunan province, China, has been constructed in a karst stratum where the rock mass has been weathered intensely by the influence of two faults. Heavy rain triggered some potential water outlets, causing a serious water inrush. The PWOD method was applied in this project for the treatment of water inflow, and six potential water outlets in total were identified through three heavy rains. Meanwhile, a geophysical prospecting technique was also used to detect water sources. The connections between water outlets and water sources were identified with a 3-D graphic that included all of them. According to the distribution of water outlets and water sources, the detection area was divided into three sections and separately treated by curtain grouting.展开更多
基金Project(40873015) supported by the National Natural Science Foundation of ChinaProject(08010302062) supported by the Eleventh Five-year Scientific and Technological Program of Anhui Province,China
文摘Rare earth element （REE） concentrations were measured by ICP-MS for groundwater collected from deep seated Taiyuan Fm limestone aquifer （from -400 to -530 m） in Renlou Coal Mine, northern Anhui Province, China. It can be concluded that the groundwater is warm （34.0-37.2 ℃） C1-Ca, Na type water with circum-neutral pH （7.35-8.28） and high total dissolved solids （TDS, 1 746-2 849 mg/L）. The groundwater exhibits heavy REEs enrichment relative to light REEs compared with Post Archean Average Shale （PAAS）, as well as their aquifer rocks （limestone）. The enrichment of REEs is considered to be controlled by terrigeneous materials （e.g. zircon） in aquifer rocks, whereas the fractionation of REEs is controlled by marine derived materials （e.g. calcite）, to a less extent, terrigeneous materials and inorganic complexation. The Ce anomalies normalized to PAAS and aquifer rocks are weak, which probably reflects the signature of the aquifer rock rather than redox conditions or pH. The similarities of REE patterns between groundwater and aquifer rocks imply that aquifer rocks play important roles in controlling the REE characteristics of groundwater, and then provide a probability for discrimination of groundwater sources by using REEs.
基金supported by the National Key Research and Development Project (Grant No.2016YFC0801604)Natural Science Foundation of Shandong Province (Grant No.ZR2017MEE070)
文摘In a karst tunnel, fissures or cracks that are filled with weathered materials are a type of potential water outlet as they are easily triggered and converted into groundwater outlets under the influence of high groundwater pressure. A terrible water inrush caused by potential water outlets can seriously hinder the project construction. Potential water outlets and water sources that surrounding the tunnel must be detected before water inflow can be treated. This paper provides a successful case of the detection and treatment of water inflow in a karst tunnel and proposes a potential water outlet detection(PWOD) method in which heavy rainfall(>50 mm/d) is considered a trigger for a potential water outlet. The Daba tunnel located in Hunan province, China, has been constructed in a karst stratum where the rock mass has been weathered intensely by the influence of two faults. Heavy rain triggered some potential water outlets, causing a serious water inrush. The PWOD method was applied in this project for the treatment of water inflow, and six potential water outlets in total were identified through three heavy rains. Meanwhile, a geophysical prospecting technique was also used to detect water sources. The connections between water outlets and water sources were identified with a 3-D graphic that included all of them. According to the distribution of water outlets and water sources, the detection area was divided into three sections and separately treated by curtain grouting.
