The steam-gasification reaction characteristics of coal and petroleum coke （PC） were studied in the drop tube furnace （DTF）. The effects of various factors such as types of carbonaceous material, gasification temp...The steam-gasification reaction characteristics of coal and petroleum coke （PC） were studied in the drop tube furnace （DTF）. The effects of various factors such as types of carbonaceous material, gasification temperature （1100- 1400 ℃） and mass ratio of steam to char （0.4：1, 0.6：1 and 1：1 separately） on gasification gas or solid products were investigated. The results showed that for all carbonaceous materials studied, H2 content exhibited the largest part of gasification gaseous products and CH4 had the smallest part. For the two petroleum cokes, CO2 content was higher than CO, which was similar to Zun-yi char. When the steam/char ratio was constant, the carbon con- version of both Shen-fu and PC chars increased with increasing temperature. When the gasification temperature was constant, the carbon conversions of all char samples increased with increasing steam/char ratio. For all the steam/char ratios, compared to water gas shift reaction, char-H2O and char-CO2 reaction were further from the thermodynamic equilibrium due to a much lower char gasification rate than that of water gas shift reaction rate. Therefore, kinetic effects may play a more important role in a char gasification step than thermodynamic effects when the gasification reaction of char was held in DTF, The calculating method for the equilibrium shift in this study will be a worth reference for analysis of the gaseous components in industrial gasifier. The reactivity of residual cokes decreased and the crystal layer （L002/d002） numbers of residual cokes increased with increasing gasification temperature. Therefore, L002/d002, the carbon crystallite structure parameter, can be used to evaluate the reactivity of residual cokes.展开更多
In coking process, the production quality, equipment life, energy consumption, and process safety are all influenced by the pressure in gas collector pipe of coke oven, which is frequently influenced by disturbances.T...In coking process, the production quality, equipment life, energy consumption, and process safety are all influenced by the pressure in gas collector pipe of coke oven, which is frequently influenced by disturbances.The main control objectives for the gas collector pressure system are keeping the pressures in collector pipes at appropriate operating point. In this paper, model predictive control(MPC) strategy is introduced to control the collector pressure system due to its ability to handle constraint and good control performance. Based on a method proposed to simplify the system model, an extended state space model predictive control is designed,which combines the feedforward strategy to eliminate the disturbance. The simulation results in a system with two coke ovens show the feasibility and effectiveness of the control scheme.展开更多
基金Supported by the National High Technology Research and Development of China(2012AA053101,2011AA050106)the National Key State Basic Research Development Program of China(2010CB227004)the National Natural Science Foundation of China(21376081)
文摘The steam-gasification reaction characteristics of coal and petroleum coke （PC） were studied in the drop tube furnace （DTF）. The effects of various factors such as types of carbonaceous material, gasification temperature （1100- 1400 ℃） and mass ratio of steam to char （0.4：1, 0.6：1 and 1：1 separately） on gasification gas or solid products were investigated. The results showed that for all carbonaceous materials studied, H2 content exhibited the largest part of gasification gaseous products and CH4 had the smallest part. For the two petroleum cokes, CO2 content was higher than CO, which was similar to Zun-yi char. When the steam/char ratio was constant, the carbon con- version of both Shen-fu and PC chars increased with increasing temperature. When the gasification temperature was constant, the carbon conversions of all char samples increased with increasing steam/char ratio. For all the steam/char ratios, compared to water gas shift reaction, char-H2O and char-CO2 reaction were further from the thermodynamic equilibrium due to a much lower char gasification rate than that of water gas shift reaction rate. Therefore, kinetic effects may play a more important role in a char gasification step than thermodynamic effects when the gasification reaction of char was held in DTF, The calculating method for the equilibrium shift in this study will be a worth reference for analysis of the gaseous components in industrial gasifier. The reactivity of residual cokes decreased and the crystal layer （L002/d002） numbers of residual cokes increased with increasing gasification temperature. Therefore, L002/d002, the carbon crystallite structure parameter, can be used to evaluate the reactivity of residual cokes.
基金Supported by the State Key Laboratory of Synthetical Automation for Process Industriesthe National Natural Science Foundation of China(61374110,61333009,61104078,61221003)the Minhang Technology Project of Shanghai(2012MH211)
文摘In coking process, the production quality, equipment life, energy consumption, and process safety are all influenced by the pressure in gas collector pipe of coke oven, which is frequently influenced by disturbances.The main control objectives for the gas collector pressure system are keeping the pressures in collector pipes at appropriate operating point. In this paper, model predictive control(MPC) strategy is introduced to control the collector pressure system due to its ability to handle constraint and good control performance. Based on a method proposed to simplify the system model, an extended state space model predictive control is designed,which combines the feedforward strategy to eliminate the disturbance. The simulation results in a system with two coke ovens show the feasibility and effectiveness of the control scheme.
