The effects of factors such as the molar ratio of H2O to CH4 (n(H2O)/n(CH4)), methane conversion temperature and time on methane conversion rate were investigated to build kinetic model for reforming of coke-oven gas ...The effects of factors such as the molar ratio of H2O to CH4 (n(H2O)/n(CH4)), methane conversion temperature and time on methane conversion rate were investigated to build kinetic model for reforming of coke-oven gas with steam. The results of experiments show that the optimal conditions for methane conversion are that the molar ratio of H2O to CH4 varies from 1.1 to 1.3 and the conversion temperature varies from 1 223 to 1 273 K. The methane conversion rate is more than 95% when the molar ratio of H2O to CH4 is 1.2, the conversion temperature is above 1 223 K and the conversion time is longer than 0.75 s. Kinetic model of methane conversion was proposed. All results demonstrate that the calculated values by the kinetic model accord with the experimental data well, and the error is less than 1.5%.展开更多
Technical process and pressure control system of coke furnace were introduced.The mathematical model based on experimental method of gas-collector pressure wasproposed.To a certain extent, it is more reliable and depe...Technical process and pressure control system of coke furnace were introduced.The mathematical model based on experimental method of gas-collector pressure wasproposed.To a certain extent, it is more reliable and dependable than mechanism method.Manufacturing process and experimental modeling can be finished at the same time, andfurthermore, the mathematical model can be established automatically.The realization algorithmof the total decoupling and on the line's modification for model value plays an importantrole in improving regulating quality.Finally, the DCS network structure to realizethe process was introduced.The control results show that the regulator can get reliableand robust performance.展开更多
基金Project(291054) supported by Postdoctoral Fund of China
文摘The effects of factors such as the molar ratio of H2O to CH4 (n(H2O)/n(CH4)), methane conversion temperature and time on methane conversion rate were investigated to build kinetic model for reforming of coke-oven gas with steam. The results of experiments show that the optimal conditions for methane conversion are that the molar ratio of H2O to CH4 varies from 1.1 to 1.3 and the conversion temperature varies from 1 223 to 1 273 K. The methane conversion rate is more than 95% when the molar ratio of H2O to CH4 is 1.2, the conversion temperature is above 1 223 K and the conversion time is longer than 0.75 s. Kinetic model of methane conversion was proposed. All results demonstrate that the calculated values by the kinetic model accord with the experimental data well, and the error is less than 1.5%.
文摘Technical process and pressure control system of coke furnace were introduced.The mathematical model based on experimental method of gas-collector pressure wasproposed.To a certain extent, it is more reliable and dependable than mechanism method.Manufacturing process and experimental modeling can be finished at the same time, andfurthermore, the mathematical model can be established automatically.The realization algorithmof the total decoupling and on the line's modification for model value plays an importantrole in improving regulating quality.Finally, the DCS network structure to realizethe process was introduced.The control results show that the regulator can get reliableand robust performance.
