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荧光炭点比率探针的构建及可视化快速检测Fe^(3+)
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作者 赵雪 徐欣仪 +2 位作者 贡永青 吴聪影 吴琪琳 《材料科学与工程学报》 CAS CSCD 北大核心 2024年第3期419-426,共8页
以柠檬酸和邻苯二胺为原料,采用水热法制备了15种炭点,发现通过调控反应的温度和酸的种类,可以改变炭点的荧光颜色和荧光强度。以HNO_(3)调节pH值为2,反应温度为180℃时,获得了绿色炭点,该炭点量子产率高达41.56%;该绿色炭点对Fe^(3+)... 以柠檬酸和邻苯二胺为原料,采用水热法制备了15种炭点,发现通过调控反应的温度和酸的种类,可以改变炭点的荧光颜色和荧光强度。以HNO_(3)调节pH值为2,反应温度为180℃时,获得了绿色炭点,该炭点量子产率高达41.56%;该绿色炭点对Fe^(3+)具有特异荧光响应,且在0.1~1 mM的检测范围中,炭点与Fe^(3+)的浓度具有良好线性关系,其相关系数R^(2)可达0.99795,最低检出限为0.47μM。进一步将该绿色炭点与罗丹明B结合,构建了比率荧光探针,并成功制备了其对应的比色卡纸,实现了可视化快速检测Fe^(3+)浓度。 展开更多
关键词 炭点 离子检测 比率荧光探针 可视化
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炭-/石墨烯量子点在超级电容器中的应用 被引量:14
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作者 朱家瑶 董玥 +1 位作者 张苏 范壮军 《物理化学学报》 SCIE CAS CSCD 北大核心 2020年第2期30-45,共16页
炭-/石墨烯量子点作为新兴的炭纳米材料,因具有独特的小尺寸效应和丰富的边缘活性位点而在高性能超级电容器电极材料的研发方面展现出巨大潜力。针对目前炭-/石墨烯量子点在超级电容器电极材料方面的应用优势和存在的关键问题,本文以炭-... 炭-/石墨烯量子点作为新兴的炭纳米材料,因具有独特的小尺寸效应和丰富的边缘活性位点而在高性能超级电容器电极材料的研发方面展现出巨大潜力。针对目前炭-/石墨烯量子点在超级电容器电极材料方面的应用优势和存在的关键问题,本文以炭-/石墨烯量子点、量子点/导电炭复合材料、量子点/金属氧化物复合材料、量子点/导电聚合物复合材料以及量子点衍生炭这些电极材料为脉络,梳理了近年来该领域的发展状况,尝试阐释炭-/石墨烯量子点在电极材料、复合材料和衍生炭电极材料中所起到的关键作用,最后对炭-/石墨烯量子点电极材料的发展进行了展望。本综述以期为炭-/石墨烯量子点基电极材料的研究提供一定参考和依据。 展开更多
关键词 量子 石墨烯量子 超级电容器 复合材料 材料
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粉末活性炭强化处理京杭运河常州段微污染原水 被引量:4
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作者 张文中 李正兆 《中国给水排水》 CAS CSCD 北大核心 2009年第3期77-79,84,共4页
以京杭运河常州段微污染原水为研究对象,对其进行常规处理的同时增投粉末活性炭(PAC),通过静态吸附试验考察了最佳的投炭点和投加量。结果表明,投炭点在净水工艺流程中越靠前,则PAC对污染物的吸附效果越好;增投粉末活性炭可大幅度提高... 以京杭运河常州段微污染原水为研究对象,对其进行常规处理的同时增投粉末活性炭(PAC),通过静态吸附试验考察了最佳的投炭点和投加量。结果表明,投炭点在净水工艺流程中越靠前,则PAC对污染物的吸附效果越好;增投粉末活性炭可大幅度提高对有机污染物的去除效果;粉末活性炭的最佳投加点为吸水井,最佳投量为30mg/L。 展开更多
关键词 粉末活性 微污染原水 炭点
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高效去除有机物沉淀工艺中试研究 被引量:1
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作者 张东波 徐海燕 +3 位作者 许龙 郑国兴 许嘉炯 丁伯香 《给水排水》 CSCD 北大核心 2012年第7期13-16,共4页
针对地表水有机物污染较重,深度处理单元负荷过高或地表水有机物污染较轻,建设深度处理单元投资过大的问题,提出一种高效去除有机物的沉淀工艺。其以高密度沉淀池为载体,粉末活性炭吸附去除有机物为手段,利用污泥回流对粉末活性炭的富... 针对地表水有机物污染较重,深度处理单元负荷过高或地表水有机物污染较轻,建设深度处理单元投资过大的问题,提出一种高效去除有机物的沉淀工艺。其以高密度沉淀池为载体,粉末活性炭吸附去除有机物为手段,利用污泥回流对粉末活性炭的富集和回收作用,延长粉末活性炭在沉淀池中的停留时间,充分发挥活性炭的吸附能力,强化对有机物的去除效果。研究结果表明,该工艺相比不投加粉末活性炭的高密度沉淀池,CODMn去除率提高了17个百分点。相比于沉淀池普通活性炭投加方式,在相同去除率的情况下,粉末活性炭投加量减少了68%,节约了运行成本。 展开更多
关键词 高密度沉淀池 粉末活性 投加方式 炭点 投加量
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蛋黄馏油纳米类成分治疗湿疹的药效评价及机制研究 被引量:4
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作者 钟琪 赵金莉 +5 位作者 李伟洋 寇秘榔 刘楚妤 赵琰 屈会化 孔慧 《世界中医药》 CAS 2021年第20期3007-3011,3017,共6页
目的:探索蛋黄馏油中纳米类成分治疗湿疹的作用及其机制。方法:蛋黄馏油经过水萃取,得到富含纳米类成分的蛋黄馏油水溶液(EYO-CDs)。利用2,4-二硝基氯苯乙醇溶液建立小鼠慢性湿疹模型,以复方醋酸地塞米松乳膏为阳性对照,评价EYO-CDs治... 目的:探索蛋黄馏油中纳米类成分治疗湿疹的作用及其机制。方法:蛋黄馏油经过水萃取,得到富含纳米类成分的蛋黄馏油水溶液(EYO-CDs)。利用2,4-二硝基氯苯乙醇溶液建立小鼠慢性湿疹模型,以复方醋酸地塞米松乳膏为阳性对照,评价EYO-CDs治疗湿疹的作用及机制。结果:EYO-CDs能减轻慢性湿疹小鼠耳肿胀度,降低血清及组织中白细胞介素-4(IL-4),白细胞介素-17(IL-17)及升高γ干扰素(INF-γ)水平。HE染色结果显示,给药后耳组织表皮角化、水肿、淋巴细胞浸润、真皮血管扩张充血等病理现象均有不同程度缓解。治疗效果与给药浓度具有一定的量效关系。结论:蛋黄馏油中的EYO-CDs对小鼠慢性湿疹具有治疗作用,主要通过抑制炎症介质,调节免疫因子起效,为临床推广应用提供了实验依据。 展开更多
关键词 蛋黄馏油 炭点 蛋黄馏油水溶液 表征 湿疹 白细胞介素-4 白细胞介素-17 Γ干扰素
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2D-ball simulations on stiffness influences for coal bump 被引量:1
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作者 TAN Yun-liang SUN Chun-jiang ZHANG Zhen-yu 《Journal of Coal Science & Engineering(China)》 2009年第2期161-165,共5页
Coal bump is a dynamic process,thus it is necessary to reveal the process validly.2D-ball code is an efficient approach developed by the authors based on the basicDEM rationale proposed by Cundall.Numerical simulation... Coal bump is a dynamic process,thus it is necessary to reveal the process validly.2D-ball code is an efficient approach developed by the authors based on the basicDEM rationale proposed by Cundall.Numerical simulations show that the coal bump experiencesa process of energy accumulation,sudden release of energy and energy decrease.The stiffness of coal particles has a great influence on the coal bump morphosisand particle velocity.Generally,the larger the stiffness of particles,the longer the shootingoff period and the larger the bump velocity.This is in agreement with the results of laboratoryexperiment and in-situ studies.However,the stiffness of particles has an influence onthe quantity value energy and no influence on the releasing energy pattern of the coalbump. 展开更多
关键词 2D-ball code coal bump stiffness of particle simulation
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Biological liquefaction characteristics of Jurassic weak & non-stick coal in Hengshan,North Shaanxi Province
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作者 杜美利 陈宏贵 姜素荣 《Journal of Coal Science & Engineering(China)》 2008年第3期520-522,共3页
Jurassic weak & non-stick coal in Hengshan of North Shaanxi Province was pretreated by the nitric acid.Then,it was biodegraded by Phanerochaete chrysosporium. The biodegradation role of the white-rot fungus for co... Jurassic weak & non-stick coal in Hengshan of North Shaanxi Province was pretreated by the nitric acid.Then,it was biodegraded by Phanerochaete chrysosporium. The biodegradation role of the white-rot fungus for coal is extremely significant.Orthogo- nal test demonstrate that liquefied time,liquefaction temperature and the amount of fun- gus liquids etc.are the main factors affecting the coal biodegradation rate.The best tech- nical condition of the coal biological liquefaction was got.Comparing the coal sample be- fore biodegradation with that after biodegradation,it is found that the ash of the coal resi- due after biodegradation reduces significantly,H and O contents increase,C and N con- tents decrease.The biodegradation change the coal macromolecular structure. 展开更多
关键词 biological liquefaction JURASSIC weak non-stick coal orthogonal test biodegradation rate
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Suspended Solids from Drained Peatlands in the East Coastal Zone of New Brunswick: Point Estimates and Climate Effects on the Environment
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作者 Mathieu Quenum Marion Tetegan Papa Malick Sail 《Journal of Environmental Science and Engineering(A)》 2015年第1期1-13,共13页
Peatlands represent one of the most important economic resources and abandoned peatlands after mining can be considered as ecological resources by re-vegetation restoration or management. However, some environmental p... Peatlands represent one of the most important economic resources and abandoned peatlands after mining can be considered as ecological resources by re-vegetation restoration or management. However, some environmental problems like particles from peatlands and their effects in the water system have to be characterized. Since centuries, artificial drainage has been a current practice for the mining of peatlands. Mainly mined for horticultural purpose, New Brunswick's peatlands--predominantly located in the eastern of the province--cover about 140,000 ha. At the downstream end of the drainage system, the water from peatlands flow into sedimentation basins. Drainage waters are often laden with solid particles. Once they have flowed through the ponds to allow sediment settling, the water is released into the water system. This paper describes the spatio-temporal evolution of suspended solids from 12 New Brunswick drained peatlands. The studied sites were characterized by some heterogeneity in the concentration of suspended solids. This study also provides knowledge on the suspended solids amount that can be released by drained peatlands, and it proposes a function to estimate the concentration of suspended solids by using climate variables; and identifies some potential ecological risks. 展开更多
关键词 PEATLANDS drainage sedimentation ponds suspended matters water system.
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Crossing point temperature of coal 被引量:5
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作者 Qi xuyao Deming Wang +1 位作者 James A. Milke Xiaoxing Zhong 《Mining Science and Technology》 EI CAS 2011年第2期255-260,共6页
A further understanding of the self-heating of coal was obtained by investigating the crossing point temperature(CPT) of different ranks of coal.The tests were carried out using a self-designed experimental system f... A further understanding of the self-heating of coal was obtained by investigating the crossing point temperature(CPT) of different ranks of coal.The tests were carried out using a self-designed experimental system for coal self-heating.50 g(±0.01 g) of coal particles ranging from 0.18 mm to 0.38 mm in size were put into a pure copper reaction vessel attached to the center of a temperature programmed enclosure.The temperature program increased the temperature at a rate of 0.8℃/min.Dry air was permitted to flow into the coal reaction vessel at different rates.The surrounding temperature and the coal temperature were monitored by a temperature logger.The results indicate that CPT is affected by coal rank,moisture,sulfur, and the experimental conditions.Higher ranked coals show higher CPT values.A high moisture content causes a delay phenomenon during the self-heating of the coal.Drying at 40℃decreases the effects of moisture.The reactivity of sulfur components in the coal is low under dry and low-temperature conditions. These components form a film that covers the coal surface and slightly inhibits the self-heating of the coal. The flow rate of dry air,and the heating rate of the surroundings,also affect the self-heating of the coal.The most appropriate experimental conditions for coal samples of a given weight and particle size were determined through contrastive analysis.Based on this analysis we propose that CPTs be determined under the same,or nearly the same conditions,for evaluation of the spontaneous combustion of coal. 展开更多
关键词 COAL Spontaneous combustion Crossing point temperature MOISTURE SULFUR Coal rank
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