This pilot study intended to investigate the application of Mixing Zone Guidelines in northern Sweden. The EC （European Commission）-Mixing Zone Guidelines were applied to seven effluent discharges. The effluents wer...This pilot study intended to investigate the application of Mixing Zone Guidelines in northern Sweden. The EC （European Commission）-Mixing Zone Guidelines were applied to seven effluent discharges. The effluents were from industrial processes used in the Ronnskar smelter, in northern Sweden. Each outlet in the smelter area discharges water into the Bothnian bay of the Baltic Sea. Cadmium （Cd）, mercury （Hg）, nickel （Ni） and lead （Pb） were the primary substances present in the effluents. A ＂Tiered Approach＂ was followed for mixing zone assessments in each of the discharge points. Discharge Test was used at Tier 2 and CORMIX （Cornell Mixing Zone Expert System model）, version 7, at Tier 3. At each discharge point, the AA-EQS （annual average-environmental quality standard） for each metal was met within a distance of 500 m from the outfalls. This distance was exceeded to meet the MAC-EQS （maximum allowable concentration-environmental quality standard） criteria at points 1 and 3 for total Hg concentrations. However, for the proper application of Mixing Zone Guidelines, a version of the Discharge Test for coastal waters should be developed and used. The decision at which tier the dissolved metal concentration should be compared with EQS values could depend on the effluent characteristics. For Swedish coastal waters, some consideration should be given to the background concentration of metals.展开更多
TOR （Tema oil refinery） is the only petroleum refinery in Ghana. To assess the quality of the wastewater, wastewater samples taken from three points of discharge into the treatment plant and the treated effluent wer...TOR （Tema oil refinery） is the only petroleum refinery in Ghana. To assess the quality of the wastewater, wastewater samples taken from three points of discharge into the treatment plant and the treated effluent were analyzed for physico-chemical characteristics. The levels of the pH, temperature, conductivity, COD （Chemical Oxygen Demand）, TDS （Total Dissolved Solids）, TSS （Total Suspended Solids） and phenol were assessed from January to June, 2011. The results obtained indicate varied levels of contaminants in both the untreated and treated wastewater. The average values of the treated effluent parameters analyzed were 38 ℃, 6,258 μs.cm-1, 314 mg-L-1, 115 mg.L-1, 2,689 mg-L-1 and 1 mg.L-1 for the temperature, conductivity, COD, TDS, TSS and phenol, respectively. The results suggest that both the raw wastewater and the treated effluent did not meet the discharge limit set by Ghana Environmental Protection Agency. Therefore, the treated effluent required additional treatment before it can be discharged into the environment. This suggests that the wastewater treatment plant of TOR is ineffective for the type of wastewater produced.展开更多
The empirical Complex Model developed by the US Environmental Protection Agency （EPA） is used by refiners to predict the toxic emissions of reformulated gasoline with respect to gasoline properties. The difficulty i...The empirical Complex Model developed by the US Environmental Protection Agency （EPA） is used by refiners to predict the toxic emissions of reformulated gasoline with respect to gasoline properties. The difficulty in implementing this model in the blending process stems from the implicit definition of Complex Model through a series of disjunctions assembled by the EPA in the form of spreadsheets. A major breakthrough in the refinery-based Complex Model implementation occurred in 2008 and 2010 through the use of generalized disjunctive and mixed- integer nonlinear programming （MINLP）. Nevertheless, the execution time of these MINLP models remains prohibitively long to control emissions with our online gasoline blender. The first objective of this study is to present a new model that decreases the execution time of our online controller. The toxic thresholds as hard second objective is to consider constraints to be verified and search for blends that verify them. Our approach introduces a new way to write the Complex Model without any binary or integer variables. Sigmoid functions are used herein to approximate step functions until the measurement precision for each blend property is reached. By knowing this level of precision, we are able to propose an extremely good and differentiable approximation of the Complex Model. Next, a differentiable objective function is introduced to penalize emission values higher than the threshold emissions. Our optimization module has been implemented and tested with real data. The execution time never exceeded 1 s, which allows the online regulation of emissions the same way as other traditional properties of blended gasoline.展开更多
文摘This pilot study intended to investigate the application of Mixing Zone Guidelines in northern Sweden. The EC （European Commission）-Mixing Zone Guidelines were applied to seven effluent discharges. The effluents were from industrial processes used in the Ronnskar smelter, in northern Sweden. Each outlet in the smelter area discharges water into the Bothnian bay of the Baltic Sea. Cadmium （Cd）, mercury （Hg）, nickel （Ni） and lead （Pb） were the primary substances present in the effluents. A ＂Tiered Approach＂ was followed for mixing zone assessments in each of the discharge points. Discharge Test was used at Tier 2 and CORMIX （Cornell Mixing Zone Expert System model）, version 7, at Tier 3. At each discharge point, the AA-EQS （annual average-environmental quality standard） for each metal was met within a distance of 500 m from the outfalls. This distance was exceeded to meet the MAC-EQS （maximum allowable concentration-environmental quality standard） criteria at points 1 and 3 for total Hg concentrations. However, for the proper application of Mixing Zone Guidelines, a version of the Discharge Test for coastal waters should be developed and used. The decision at which tier the dissolved metal concentration should be compared with EQS values could depend on the effluent characteristics. For Swedish coastal waters, some consideration should be given to the background concentration of metals.
文摘TOR （Tema oil refinery） is the only petroleum refinery in Ghana. To assess the quality of the wastewater, wastewater samples taken from three points of discharge into the treatment plant and the treated effluent were analyzed for physico-chemical characteristics. The levels of the pH, temperature, conductivity, COD （Chemical Oxygen Demand）, TDS （Total Dissolved Solids）, TSS （Total Suspended Solids） and phenol were assessed from January to June, 2011. The results obtained indicate varied levels of contaminants in both the untreated and treated wastewater. The average values of the treated effluent parameters analyzed were 38 ℃, 6,258 μs.cm-1, 314 mg-L-1, 115 mg.L-1, 2,689 mg-L-1 and 1 mg.L-1 for the temperature, conductivity, COD, TDS, TSS and phenol, respectively. The results suggest that both the raw wastewater and the treated effluent did not meet the discharge limit set by Ghana Environmental Protection Agency. Therefore, the treated effluent required additional treatment before it can be discharged into the environment. This suggests that the wastewater treatment plant of TOR is ineffective for the type of wastewater produced.
基金financial support from TOTAL Refining and Chemicals
文摘The empirical Complex Model developed by the US Environmental Protection Agency （EPA） is used by refiners to predict the toxic emissions of reformulated gasoline with respect to gasoline properties. The difficulty in implementing this model in the blending process stems from the implicit definition of Complex Model through a series of disjunctions assembled by the EPA in the form of spreadsheets. A major breakthrough in the refinery-based Complex Model implementation occurred in 2008 and 2010 through the use of generalized disjunctive and mixed- integer nonlinear programming （MINLP）. Nevertheless, the execution time of these MINLP models remains prohibitively long to control emissions with our online gasoline blender. The first objective of this study is to present a new model that decreases the execution time of our online controller. The toxic thresholds as hard second objective is to consider constraints to be verified and search for blends that verify them. Our approach introduces a new way to write the Complex Model without any binary or integer variables. Sigmoid functions are used herein to approximate step functions until the measurement precision for each blend property is reached. By knowing this level of precision, we are able to propose an extremely good and differentiable approximation of the Complex Model. Next, a differentiable objective function is introduced to penalize emission values higher than the threshold emissions. Our optimization module has been implemented and tested with real data. The execution time never exceeded 1 s, which allows the online regulation of emissions the same way as other traditional properties of blended gasoline.
