The time-frequency domain electromagnetic(TFEM)sounding technique can directly detect oil and gas characteristics through anomalies in resistivity and polarizability.In recent years,it has made some breakthroughs in h...The time-frequency domain electromagnetic(TFEM)sounding technique can directly detect oil and gas characteristics through anomalies in resistivity and polarizability.In recent years,it has made some breakthroughs in hydrocarbon detection.TFEM was applied to predict the petroliferous property of the Ili Basin.In accordance with the geological structure characteristics of the study area,a two-dimensional layered medium model was constructed and forward modeling was performed.We used the forward-modeling results to guide fi eld construction and ensure the quality of the fi eld data collection.We used the model inversion results to identify and distinguish the resolution of the geoelectric information and provide a reliable basis for data processing.On the basis of our results,key technologies such as 2D resistivity tomography imaging inversion and polarimetric constrained inversion were developed,and we obtained abundant geological and geophysical information.The characteristics of the TFEM anomalies of the hydrocarbon reservoirs in the Ili Basin were summarized through an analysis of the electrical logging data in the study area.Moreover,the oil-gas properties of the Permian and Triassic layers were predicted,and the next favorable exploration targets were optimized.展开更多
Plant biomarkers, such as hydrocarbon waxes, are frequently found in various sediments and could be adopted as paleovegetation and paleoclimate indicators. Nevertheless, scarce researches have focused on leaf waxes in...Plant biomarkers, such as hydrocarbon waxes, are frequently found in various sediments and could be adopted as paleovegetation and paleoclimate indicators. Nevertheless, scarce researches have focused on leaf waxes in higher plants of alpine region.Herein, hydrocarbon leaf wax components of Salix oritrepha, which flourish in Nianbaoyeze Mountains in eastern Tibetan Plateau were fully discussed. The n-alkane distribution in leaves ranges from n-C_(21) to nC_(29) with maxima at n-C_(25), which were entirely different with Salix taxa displayed in previous surveys in non-alpine regions. The unusual even carbon nalkenes from n-C_(22:1) to n-C_(30:1), which were thought to appear only in aquatic organisms, were firstly reported in an alpine plant. Additionally, iso-(2-methyl) alkanes, ranging from i-C_(23) to i-C_(29) with maxima at i-C_(25), which have been commonly reported in microorganisms, were also identified in an alpine plant for the first time. Unusual hydrocarbon distribution detected in Salix oritrepha leaf from Nianbaoyeze Mountains is most likely due to the extreme environment in such alpine region.展开更多
Objective:The aim of this study was to investigate the effect of polycyclic aromatic hydrocarbons (PAHs) on the occurrence of human pancreatic cancer.Methods:PAHs in human pancreatic cancer,adjacent pancreatic cancer ...Objective:The aim of this study was to investigate the effect of polycyclic aromatic hydrocarbons (PAHs) on the occurrence of human pancreatic cancer.Methods:PAHs in human pancreatic cancer,adjacent pancreatic cancer tissues and tissues without pancreatic cancer were extracted by ultrasonic extraction (UE).And then the extracts were cleaned up by solid phase extraction and analyzed by high performance liquid chromatography (HPLC) with fluorescence spectroscopy.Results:Four kinds of PAHs were detected,which were chrysene,2-methylanthracene,pyrene and benzo (a) pyrene.The contents of the four PAHs were not statistically significant between pancreatic cancer and adjacent tissues (P > 0.05).The contents of 2-methylanthracene,pyrene and benzo (a) pyrene in pancreatic cancer and adjacent tissues were higher than tissues without pancreatic cancer,the differences were statistically significant (P < 0.05).The contents of chrysene in the three kinds of pancreatic tissues were not statistically significant (P > 0.05).Conclusion:PAHs were found in human pancreatic tissues.Human pancreatic tissues have extremely strong ability of bio-concentrating PAHs.PAHs might play an important role in the occurrence of human pancreatic cancer.展开更多
The procedures of ultrasonic extraction and clean-up were optimized for the determination of polycyclic aromatic hydrocarbons (PAHs) in marine sediments. Samples were ultrasonically extracted, and the extracts were pu...The procedures of ultrasonic extraction and clean-up were optimized for the determination of polycyclic aromatic hydrocarbons (PAHs) in marine sediments. Samples were ultrasonically extracted, and the extracts were purified with a miniaturized silica gel chromatographic column and analyzed with high performance liquid chromatography (HPLC) with a fluorescence detector. Ultrasonication with methanol-dichloromethane (2:1, v/v) mixture gave higher extraction efficiency than that with dichloromethane. Among the three elution solvents used in clean-up step, dichloromethane-hexane (2:3, v/v) mixture was the most satisfactory. Under the optimized conditions, the recoveries in the range of 54.82% to 94.70% with RSDs of 3.02% to 23.22% for a spiked blank, and in the range of 61.20% to 127.08% with RSDs of 7.61% to 26.93% for a spiked matrix, were obtained for the 15 PAHs studied, while the recoveries for a NIST standard reference SRM 1941b were in the range of 50.79% to 83.78% with RSDs of 5.24% to 21.38%. The detection limits were between 0.75 ng L-1 and 10.99 ng L-1for different PAHs. A sample from the Jiaozhou Bay area was examined to test the established methods.展开更多
The broad class of explosives includes nitro aromatics as well as challenging aliphatic nitro-organics whose detection is important from counter-terrorism and national security perspectives.Here we report a turn-on fl...The broad class of explosives includes nitro aromatics as well as challenging aliphatic nitro-organics whose detection is important from counter-terrorism and national security perspectives.Here we report a turn-on fluorescent sensor array based on aggregation-induced emission(AIE)fluorophores as receptors.To achieve a good sensing system with fast response,good sensitivity and low detection limit,three receptors with abundant chemical diversities for target analytes were synthesized.The turn-on response of the individual receptor showed highly variable and cross-reactive analyte-dependent changes in fluorescence.The excellent ability to identify a variety of explosives,especially the challenging aliphatic nitro-organics(2,3-dimethyl-2,3-dinitrobutane(DMNB),1,3,5-trinitro-1,3,5-triazinane(RDX),cyclotetramethylene tetranitramine(HMX)and entaerythritol tetranitrate(PETN)),was demonstrated in qualitative and quantitative analyses with 100%accuracy.The fluorescence signal amplification in the presence of explosives allows for application of these receptors in a sensor microarray suitable for high-throughput screening.These results suggested that the cross-reactive sensor array based on AIE fluorophores could find a wide range of applications for sensing various analytes or complex mixtures.展开更多
基金This work was supported by the Geology and Mineral Resources Investigation and Evaluation Program(No.12120115006601 and No.DD20160181)the National key Research and Development projects(No.2016YFC060110204 and No.2016YFC060110305).
文摘The time-frequency domain electromagnetic(TFEM)sounding technique can directly detect oil and gas characteristics through anomalies in resistivity and polarizability.In recent years,it has made some breakthroughs in hydrocarbon detection.TFEM was applied to predict the petroliferous property of the Ili Basin.In accordance with the geological structure characteristics of the study area,a two-dimensional layered medium model was constructed and forward modeling was performed.We used the forward-modeling results to guide fi eld construction and ensure the quality of the fi eld data collection.We used the model inversion results to identify and distinguish the resolution of the geoelectric information and provide a reliable basis for data processing.On the basis of our results,key technologies such as 2D resistivity tomography imaging inversion and polarimetric constrained inversion were developed,and we obtained abundant geological and geophysical information.The characteristics of the TFEM anomalies of the hydrocarbon reservoirs in the Ili Basin were summarized through an analysis of the electrical logging data in the study area.Moreover,the oil-gas properties of the Permian and Triassic layers were predicted,and the next favorable exploration targets were optimized.
基金supported by the National Natural Science Foundation of China (Grant Nos. 41301224, 41601195)Jiangsu Overseas Research & Training Program for University Prominent Young & Middle-aged Teachers and Presidents
文摘Plant biomarkers, such as hydrocarbon waxes, are frequently found in various sediments and could be adopted as paleovegetation and paleoclimate indicators. Nevertheless, scarce researches have focused on leaf waxes in higher plants of alpine region.Herein, hydrocarbon leaf wax components of Salix oritrepha, which flourish in Nianbaoyeze Mountains in eastern Tibetan Plateau were fully discussed. The n-alkane distribution in leaves ranges from n-C_(21) to nC_(29) with maxima at n-C_(25), which were entirely different with Salix taxa displayed in previous surveys in non-alpine regions. The unusual even carbon nalkenes from n-C_(22:1) to n-C_(30:1), which were thought to appear only in aquatic organisms, were firstly reported in an alpine plant. Additionally, iso-(2-methyl) alkanes, ranging from i-C_(23) to i-C_(29) with maxima at i-C_(25), which have been commonly reported in microorganisms, were also identified in an alpine plant for the first time. Unusual hydrocarbon distribution detected in Salix oritrepha leaf from Nianbaoyeze Mountains is most likely due to the extreme environment in such alpine region.
基金Supported by agrant from Key Laboratory of Marine SpillOil Identification and Damage Assessment Technology (No. 200902)
文摘Objective:The aim of this study was to investigate the effect of polycyclic aromatic hydrocarbons (PAHs) on the occurrence of human pancreatic cancer.Methods:PAHs in human pancreatic cancer,adjacent pancreatic cancer tissues and tissues without pancreatic cancer were extracted by ultrasonic extraction (UE).And then the extracts were cleaned up by solid phase extraction and analyzed by high performance liquid chromatography (HPLC) with fluorescence spectroscopy.Results:Four kinds of PAHs were detected,which were chrysene,2-methylanthracene,pyrene and benzo (a) pyrene.The contents of the four PAHs were not statistically significant between pancreatic cancer and adjacent tissues (P > 0.05).The contents of 2-methylanthracene,pyrene and benzo (a) pyrene in pancreatic cancer and adjacent tissues were higher than tissues without pancreatic cancer,the differences were statistically significant (P < 0.05).The contents of chrysene in the three kinds of pancreatic tissues were not statistically significant (P > 0.05).Conclusion:PAHs were found in human pancreatic tissues.Human pancreatic tissues have extremely strong ability of bio-concentrating PAHs.PAHs might play an important role in the occurrence of human pancreatic cancer.
基金supported by the National Natural Science Foundation of China (Grant No.20775074)
文摘The procedures of ultrasonic extraction and clean-up were optimized for the determination of polycyclic aromatic hydrocarbons (PAHs) in marine sediments. Samples were ultrasonically extracted, and the extracts were purified with a miniaturized silica gel chromatographic column and analyzed with high performance liquid chromatography (HPLC) with a fluorescence detector. Ultrasonication with methanol-dichloromethane (2:1, v/v) mixture gave higher extraction efficiency than that with dichloromethane. Among the three elution solvents used in clean-up step, dichloromethane-hexane (2:3, v/v) mixture was the most satisfactory. Under the optimized conditions, the recoveries in the range of 54.82% to 94.70% with RSDs of 3.02% to 23.22% for a spiked blank, and in the range of 61.20% to 127.08% with RSDs of 7.61% to 26.93% for a spiked matrix, were obtained for the 15 PAHs studied, while the recoveries for a NIST standard reference SRM 1941b were in the range of 50.79% to 83.78% with RSDs of 5.24% to 21.38%. The detection limits were between 0.75 ng L-1 and 10.99 ng L-1for different PAHs. A sample from the Jiaozhou Bay area was examined to test the established methods.
基金the National Natural Science Foundation of China(50873051,205333050)National High Technology Research and Development Program of China(2007AA03Z307)Transregional Project(TRR61)
文摘The broad class of explosives includes nitro aromatics as well as challenging aliphatic nitro-organics whose detection is important from counter-terrorism and national security perspectives.Here we report a turn-on fluorescent sensor array based on aggregation-induced emission(AIE)fluorophores as receptors.To achieve a good sensing system with fast response,good sensitivity and low detection limit,three receptors with abundant chemical diversities for target analytes were synthesized.The turn-on response of the individual receptor showed highly variable and cross-reactive analyte-dependent changes in fluorescence.The excellent ability to identify a variety of explosives,especially the challenging aliphatic nitro-organics(2,3-dimethyl-2,3-dinitrobutane(DMNB),1,3,5-trinitro-1,3,5-triazinane(RDX),cyclotetramethylene tetranitramine(HMX)and entaerythritol tetranitrate(PETN)),was demonstrated in qualitative and quantitative analyses with 100%accuracy.The fluorescence signal amplification in the presence of explosives allows for application of these receptors in a sensor microarray suitable for high-throughput screening.These results suggested that the cross-reactive sensor array based on AIE fluorophores could find a wide range of applications for sensing various analytes or complex mixtures.
