The gasification industries make use of biomass residue as feedstock to produce synthesis gas,but the gasification of this waste biomass generates tons of ash everyday.Performance properties and agglomeration behavior...The gasification industries make use of biomass residue as feedstock to produce synthesis gas,but the gasification of this waste biomass generates tons of ash everyday.Performance properties and agglomeration behavior of corncob ash(CCA) collected from the gasification of corncobs in a pilot-scale gasification station were investigated by using some experimental methods.Based on the chemical composition results,the agglomeration tendency of CCA from combustion and gasification process was also analyzed.Chemical analysis shows that the fly ash is mainly composed of inorganic matters formed by K,Mg,Ca,Na,Fe,Al,S,etc.The agglomeration characteristics indicate that the slagging degree increases with the increase of ashing temperature,and the slagging tendency of these CCA samples from gasification or combustion is different with various slagging indices.All CCA samples from combustion or gasification can cause slagging/fouling problems in thermal conversion systems.The applications of CCA are closely related to its performances,and CCA has the potential to be used in various fields,for example,as a material for ceramic products and activated carbon,as an adsorbent,as a crude fertilizer,and as a structural material.展开更多
A1203/5%SIC nanocomposites were fabricated by pressureless sintering using MgO as a sintering aid and then post hot-isostatic pressed (HIP), which can subsequently break through the disadvantage of hot-pressing proc...A1203/5%SIC nanocomposites were fabricated by pressureless sintering using MgO as a sintering aid and then post hot-isostatic pressed (HIP), which can subsequently break through the disadvantage of hot-pressing process. The MgO additive was able to promote the densification of the composites, but could not induce the grain growth of A1203 matrix due to the grain growth inhibition by nano-sized SiC particles. After HIP treatment, A12OJSiC nanocomposites achieved full densification and homogeneous distribution of nano-sized SiC particles. Moreover, the fracture morphology of HIP treated specimens was identical with that of the hot-pressed A1203/SiC nanocomposites showing complete transgranular fracture. Consequently, high fracture strength of 1 GPa was achieved for the A1203/5%SIC nanocomposites by pressureless sintering and post HIP process.展开更多
The phase composition, phase transition and phase structure transformation of the wire-cut section of functionally graded WC-Co cemented carbide with dual phase structure were investigated by XRD phase analysis. It is...The phase composition, phase transition and phase structure transformation of the wire-cut section of functionally graded WC-Co cemented carbide with dual phase structure were investigated by XRD phase analysis. It is shown that the composition of η phase in the core zone is Co_3W_3C (M_6 C type). The structure of cobalt based solid solution binder phase is fcc type. At the cooling stage of the sintering process, the phase transition of η phase, i.e. M_6C→M_12C and the martensitic phase transition of the cobalt based solid solution binder phase, i.e. fcc→hcp are suppressed, which facilitates the strengthening of the alloy. Because the instantaneous temperature of the discharge channel is as high as 10 000 ℃ during the wire cutting process, the processed surface is oxidized. Nevertheless, the oxide layer thickness is in micro grade. In the oxide film, η phase is decomposed into W_2C and CoO, and cobalt based solid solution binder is selectively oxidized, while WC remains stable due to the existence of carbon containing liquid organic cutting medium.展开更多
A novel Ti-based Ti-Mn composite anode used for electrolytic manganese dioxide(EMD) fabrication was developed by a two-step heating manganizing technique.The effects of sintering temperature on the manganized microstr...A novel Ti-based Ti-Mn composite anode used for electrolytic manganese dioxide(EMD) fabrication was developed by a two-step heating manganizing technique.The effects of sintering temperature on the manganized microstructure and the performance of the composite anode were studied by scanning electron microscopy(SEM),mechanical properties tests at room temperature and electrochemical methods.The results show that the thickness of the diffusion layer increases with the increase of sintering temperature up to 1 100 °C;whereas,the surface Mn content increases and reaches the maximum at 1 000 °C and then decreases thereafter.Lower surface Mn content is beneficial for the enhanced corrosion resistance and lowered open cell voltage in electrolytic process.The new anode prepared under the optimized conditions has been applied in industry and exhibits superior economic benefits to conventional Ti anodic materials.展开更多
基金Project(2013020137)supported by the Natural Science Foundation of Liaoning Province,ChinaProject(2015-36)supported by Rural Energy Comprehensive Construction Foundation of the Ministry of Agriculture,China
文摘The gasification industries make use of biomass residue as feedstock to produce synthesis gas,but the gasification of this waste biomass generates tons of ash everyday.Performance properties and agglomeration behavior of corncob ash(CCA) collected from the gasification of corncobs in a pilot-scale gasification station were investigated by using some experimental methods.Based on the chemical composition results,the agglomeration tendency of CCA from combustion and gasification process was also analyzed.Chemical analysis shows that the fly ash is mainly composed of inorganic matters formed by K,Mg,Ca,Na,Fe,Al,S,etc.The agglomeration characteristics indicate that the slagging degree increases with the increase of ashing temperature,and the slagging tendency of these CCA samples from gasification or combustion is different with various slagging indices.All CCA samples from combustion or gasification can cause slagging/fouling problems in thermal conversion systems.The applications of CCA are closely related to its performances,and CCA has the potential to be used in various fields,for example,as a material for ceramic products and activated carbon,as an adsorbent,as a crude fertilizer,and as a structural material.
基金Project supported by Pusan National University Research GrantProject(2010-0008-276) supported by National Core Research Center Program through the National Research Foundation of Korea funded by the Ministry of Education, Science and Technology
文摘A1203/5%SIC nanocomposites were fabricated by pressureless sintering using MgO as a sintering aid and then post hot-isostatic pressed (HIP), which can subsequently break through the disadvantage of hot-pressing process. The MgO additive was able to promote the densification of the composites, but could not induce the grain growth of A1203 matrix due to the grain growth inhibition by nano-sized SiC particles. After HIP treatment, A12OJSiC nanocomposites achieved full densification and homogeneous distribution of nano-sized SiC particles. Moreover, the fracture morphology of HIP treated specimens was identical with that of the hot-pressed A1203/SiC nanocomposites showing complete transgranular fracture. Consequently, high fracture strength of 1 GPa was achieved for the A1203/5%SIC nanocomposites by pressureless sintering and post HIP process.
基金Projects(50323008, 50574104) supported by the National Natural Science Foundation of ChinaProject (04JJ3084) supported by the Natural Science Foundation of Hunan Province, China
文摘The phase composition, phase transition and phase structure transformation of the wire-cut section of functionally graded WC-Co cemented carbide with dual phase structure were investigated by XRD phase analysis. It is shown that the composition of η phase in the core zone is Co_3W_3C (M_6 C type). The structure of cobalt based solid solution binder phase is fcc type. At the cooling stage of the sintering process, the phase transition of η phase, i.e. M_6C→M_12C and the martensitic phase transition of the cobalt based solid solution binder phase, i.e. fcc→hcp are suppressed, which facilitates the strengthening of the alloy. Because the instantaneous temperature of the discharge channel is as high as 10 000 ℃ during the wire cutting process, the processed surface is oxidized. Nevertheless, the oxide layer thickness is in micro grade. In the oxide film, η phase is decomposed into W_2C and CoO, and cobalt based solid solution binder is selectively oxidized, while WC remains stable due to the existence of carbon containing liquid organic cutting medium.
基金Projects(20476106,50721003 and 20636020) supported by the National Natural Science Foundation of ChinaProject(50825102) supported by the National Natural Science Funds for Distinguished Young Scholar of China+1 种基金Project(2006AA03Z511) supported by the National High Technology Research and Development Program of ChinaProject supported by the 111 Program of Chinese Ministry of Education
文摘A novel Ti-based Ti-Mn composite anode used for electrolytic manganese dioxide(EMD) fabrication was developed by a two-step heating manganizing technique.The effects of sintering temperature on the manganized microstructure and the performance of the composite anode were studied by scanning electron microscopy(SEM),mechanical properties tests at room temperature and electrochemical methods.The results show that the thickness of the diffusion layer increases with the increase of sintering temperature up to 1 100 °C;whereas,the surface Mn content increases and reaches the maximum at 1 000 °C and then decreases thereafter.Lower surface Mn content is beneficial for the enhanced corrosion resistance and lowered open cell voltage in electrolytic process.The new anode prepared under the optimized conditions has been applied in industry and exhibits superior economic benefits to conventional Ti anodic materials.