It is generally known that the large formation amount of calcium ferrite is favorable for the iron ore sintering. The effects of sintering temperature and O2 content of inlet gas on the calcium ferrite formation chara...It is generally known that the large formation amount of calcium ferrite is favorable for the iron ore sintering. The effects of sintering temperature and O2 content of inlet gas on the calcium ferrite formation characteristic of typical iron ores, including hematite, limonite, specularite and magnetite, were investigated. And the effect of O2 content on the microstructure of the roasted briquettes was also studied in detail. The results show the amount of calcium ferrite initially increases then decreases with the increase of the sintering temperature. The temperature of maximum calcium ferrite generation amount is determined as follows： for hematite and limonite it is 1275 ~C, whereas for specularite and magnetite, 1250℃. The maximum contents of calcium ferrite for hematite, limonite, specularite and magnetite under the optimal sintering temperature are 73%, 82%, 67% and 63%, respectively. Increasing O2 content of the airflow is advantageous to the formation of calcium ferrite. Relatively, the effect of O2 content on the calcium ferrite formation of magnetite is the most pronounced, while O2 content of inlet gas has little effect on the calcium ferrite formation of limonite.展开更多
Different ambient conditions for the synthesis of Ag（Nb0.8Ta0.2）O3 ceramics were investi- gated. The Ag（Nb0.8Ta0.2）O3 powder was synthesized at 950 ℃ under different ambient conditions, and then pressed into disk...Different ambient conditions for the synthesis of Ag（Nb0.8Ta0.2）O3 ceramics were investi- gated. The Ag（Nb0.8Ta0.2）O3 powder was synthesized at 950 ℃ under different ambient conditions, and then pressed into disks and sintered between 1060 ℃ and 1100 ℃ respectively. Samples were investigated by X-ray diffraction, scanning electron microscopy and dielectric measurement. The results show that perovskite Ag（Nb0.8Ta0.2）O3 powder was easier to be synthesized in air than in vacuum at 950℃. Grain size of ceramic samples sintered in air was uniform （about 1 μm） and its dielectric loss was small for its high density. However, the samples decomposed greatly and ceramics could hardly be densified when sintered in vacuum, Thus,. higher atmospheric pressure and oxygen atmosphere would benifit the synthesis of Ag （Nb0.8Ta0.2）O3, and suppress its decomposition at high temperature.展开更多
As a special sedimentary grain type, the coated grain(with an ooid model) has been known for two centuries due to its fascinating special fabric and genesis developments. The leading factors in forming the coated grai...As a special sedimentary grain type, the coated grain(with an ooid model) has been known for two centuries due to its fascinating special fabric and genesis developments. The leading factors in forming the coated grain consist mainly of:(1) microorganism movement field;(2) chemical sedimentary effect;(3) hydrodynamic force environment and topography condition;(4) abundant core material supply;(5) embedding condition; and(6) humic acids condition in water medium. With the development of the coated grain genesis, the single factor theory cannot reasonably explain the exact formation of the surface sediment of coated grain. Here, we find a new way to study the coated grain on the basis of traditional research methods. The Wenquan area on the northeast edge of the Qiangtang Basin is one of the few areas where the coated grain is developing, and is a rare "natural laboratory" for the study of the coated grain and the thermal spring sediment. The oolitic sinter of the area has the triaxiality modality of pea polymer, and is obviously different from the karst travertine and the normal lacustrine ooid. We found that the hot spring water in the Wenquan area has higher partial pressure of CO2(PCO2) and saturation index of the calcite(SIc) than normal. Macrocosmically, the oolitic sinter is shaped like a pea, and its grains and gap fillings are light yellow. Microcosmically, the sinter grain forms six types of fundamental lamina, and those six types are developed to be four grain types with different combinations. The C-axis of the mineral grain of sinter cement(calcite) is normal to the lamina face, and grows on it with distinct generation formations. In short, the grain type of oolitic sinter is the oncoid, with the grain development caused by the factors such as the shallow water of strong hydrodynamic force, the special hydrochemistry condition, and the extensive algae activities(diatom).展开更多
基金Project(2013JSJJ028)supported by the Key Programs of Science and Technology from Hunan Province,China
文摘It is generally known that the large formation amount of calcium ferrite is favorable for the iron ore sintering. The effects of sintering temperature and O2 content of inlet gas on the calcium ferrite formation characteristic of typical iron ores, including hematite, limonite, specularite and magnetite, were investigated. And the effect of O2 content on the microstructure of the roasted briquettes was also studied in detail. The results show the amount of calcium ferrite initially increases then decreases with the increase of the sintering temperature. The temperature of maximum calcium ferrite generation amount is determined as follows： for hematite and limonite it is 1275 ~C, whereas for specularite and magnetite, 1250℃. The maximum contents of calcium ferrite for hematite, limonite, specularite and magnetite under the optimal sintering temperature are 73%, 82%, 67% and 63%, respectively. Increasing O2 content of the airflow is advantageous to the formation of calcium ferrite. Relatively, the effect of O2 content on the calcium ferrite formation of magnetite is the most pronounced, while O2 content of inlet gas has little effect on the calcium ferrite formation of limonite.
基金SUPPORTED BY NATIONAL NATURAL SCIENCE FOUNDATION OF CHINA( NO. 50402011 ).
文摘Different ambient conditions for the synthesis of Ag（Nb0.8Ta0.2）O3 ceramics were investi- gated. The Ag（Nb0.8Ta0.2）O3 powder was synthesized at 950 ℃ under different ambient conditions, and then pressed into disks and sintered between 1060 ℃ and 1100 ℃ respectively. Samples were investigated by X-ray diffraction, scanning electron microscopy and dielectric measurement. The results show that perovskite Ag（Nb0.8Ta0.2）O3 powder was easier to be synthesized in air than in vacuum at 950℃. Grain size of ceramic samples sintered in air was uniform （about 1 μm） and its dielectric loss was small for its high density. However, the samples decomposed greatly and ceramics could hardly be densified when sintered in vacuum, Thus,. higher atmospheric pressure and oxygen atmosphere would benifit the synthesis of Ag （Nb0.8Ta0.2）O3, and suppress its decomposition at high temperature.
基金supported by the National Natural Science Foundation of China (Grant Nos. 40972084 and 41102060)
文摘As a special sedimentary grain type, the coated grain(with an ooid model) has been known for two centuries due to its fascinating special fabric and genesis developments. The leading factors in forming the coated grain consist mainly of:(1) microorganism movement field;(2) chemical sedimentary effect;(3) hydrodynamic force environment and topography condition;(4) abundant core material supply;(5) embedding condition; and(6) humic acids condition in water medium. With the development of the coated grain genesis, the single factor theory cannot reasonably explain the exact formation of the surface sediment of coated grain. Here, we find a new way to study the coated grain on the basis of traditional research methods. The Wenquan area on the northeast edge of the Qiangtang Basin is one of the few areas where the coated grain is developing, and is a rare "natural laboratory" for the study of the coated grain and the thermal spring sediment. The oolitic sinter of the area has the triaxiality modality of pea polymer, and is obviously different from the karst travertine and the normal lacustrine ooid. We found that the hot spring water in the Wenquan area has higher partial pressure of CO2(PCO2) and saturation index of the calcite(SIc) than normal. Macrocosmically, the oolitic sinter is shaped like a pea, and its grains and gap fillings are light yellow. Microcosmically, the sinter grain forms six types of fundamental lamina, and those six types are developed to be four grain types with different combinations. The C-axis of the mineral grain of sinter cement(calcite) is normal to the lamina face, and grows on it with distinct generation formations. In short, the grain type of oolitic sinter is the oncoid, with the grain development caused by the factors such as the shallow water of strong hydrodynamic force, the special hydrochemistry condition, and the extensive algae activities(diatom).
