Diffusion bonding between tungsten and 0Cr13Al stainless steel using a Cu/90W-10Ni powder mixtures/Ni multi-interlayer was carried out in vacuum at 1150 °C with a pressure of 5 MPa for 60 min. The microstructures...Diffusion bonding between tungsten and 0Cr13Al stainless steel using a Cu/90W-10Ni powder mixtures/Ni multi-interlayer was carried out in vacuum at 1150 °C with a pressure of 5 MPa for 60 min. The microstructures, composition distribution and fracture characteristics of the joint were studied by SEM and EDS. Joint properties were evaluated by shear experiments and thermal shock tests. The results showed that the joints comprised tungsten/Cu-Ni sub-layer/W-Ni composites sub-layer/Ni sub-layer/0Cr13Al stainless steel. The W-Ni composites sub-layer with a homogeneous and dense microstructure was formed by solid phase sintering of 90W-10Ni powder mixtures. Sound bonding between tungsten base material and W-Ni composites sub-layer was realized based on transient liquid phase (TLP) diffusion bonding mechanism. Joints fractured at bonding zone of W-Ni composites sub-layer and Ni sub-layer during shear testing, and the average strength was 256 MPa. Thermal shock tests showed that joints could withstood 60 thermal cycles quenching from 700 °C to room temperature.展开更多
Multiple direction compression(MDC)was conducted on sintered pure tungsten(99.9%,mass fraction)with different reductions at 1423 K.The microstructure,microhardness and thermal stability of the MDC-processed samples we...Multiple direction compression(MDC)was conducted on sintered pure tungsten(99.9%,mass fraction)with different reductions at 1423 K.The microstructure,microhardness and thermal stability of the MDC-processed samples were studied by X-ray diffraction(XRD),electron backscattered diffraction(EBSD)and differential scanning calorimetry(DSC)compared with those of the initial sintered tungsten.The results show that the dislocation density increases significantly with the reduction of MDC,ranging from 3.08×1014 m-2 for the initial sintered tungsten to 8.08×1014 m-2 for the tungsten after MDC with the reduction of 50%.The average grain size decreases from 83.8 to 14.7μm and the microhardness value increases from HV0.2 417 to HV0.2 521.The recrystallization temperature for the tungsten samples processed by MDC is approximately constant at around 1600 K.The MDC of sintered tungsten results in a decrease of grain size concurrent with an increase of uniformly distributed nucleation sites,which leads to the improvement of the thermal stability.展开更多
The microstructure and properties of the 93W-4Ni-2Co-1Fe(mass fraction,%) tungsten heavy alloys prepared by mechanical alloying and electric current activated sintering from mixed elemental powders were investigated.A...The microstructure and properties of the 93W-4Ni-2Co-1Fe(mass fraction,%) tungsten heavy alloys prepared by mechanical alloying and electric current activated sintering from mixed elemental powders were investigated.After 15 h milling,the average W grain size in the powders is decreased to 120 nm.For the powders milled for 15 h,the density,hardness and transverse rupture strength of the alloys sintered only by an intensive pulse electric current are the maximum.When the total sintering time keeps constant,the properties of the sintered alloys can be obviously improved by optimizing the sintering time of pulse-and constant-currents.A bulk ultrafine alloy with an average W grain size of about 340 nm can be obtained by sintering 15 h-milled powders in a total sintering time of 6 min.The corresponding sintered density,hardness and transverse rupture strength reach 16.78 g /cm3,HRA84.3 and 968 MPa,respectively.展开更多
基金Project(51075205)supported by the National Natural Science Foundation of China
文摘Diffusion bonding between tungsten and 0Cr13Al stainless steel using a Cu/90W-10Ni powder mixtures/Ni multi-interlayer was carried out in vacuum at 1150 °C with a pressure of 5 MPa for 60 min. The microstructures, composition distribution and fracture characteristics of the joint were studied by SEM and EDS. Joint properties were evaluated by shear experiments and thermal shock tests. The results showed that the joints comprised tungsten/Cu-Ni sub-layer/W-Ni composites sub-layer/Ni sub-layer/0Cr13Al stainless steel. The W-Ni composites sub-layer with a homogeneous and dense microstructure was formed by solid phase sintering of 90W-10Ni powder mixtures. Sound bonding between tungsten base material and W-Ni composites sub-layer was realized based on transient liquid phase (TLP) diffusion bonding mechanism. Joints fractured at bonding zone of W-Ni composites sub-layer and Ni sub-layer during shear testing, and the average strength was 256 MPa. Thermal shock tests showed that joints could withstood 60 thermal cycles quenching from 700 °C to room temperature.
基金Project(51675154)supported by the National Natural Science Foundation of ChinaProject(2014GB121000)supported by the National Magnetic Confinement Fusion Program,China
文摘Multiple direction compression(MDC)was conducted on sintered pure tungsten(99.9%,mass fraction)with different reductions at 1423 K.The microstructure,microhardness and thermal stability of the MDC-processed samples were studied by X-ray diffraction(XRD),electron backscattered diffraction(EBSD)and differential scanning calorimetry(DSC)compared with those of the initial sintered tungsten.The results show that the dislocation density increases significantly with the reduction of MDC,ranging from 3.08×1014 m-2 for the initial sintered tungsten to 8.08×1014 m-2 for the tungsten after MDC with the reduction of 50%.The average grain size decreases from 83.8 to 14.7μm and the microhardness value increases from HV0.2 417 to HV0.2 521.The recrystallization temperature for the tungsten samples processed by MDC is approximately constant at around 1600 K.The MDC of sintered tungsten results in a decrease of grain size concurrent with an increase of uniformly distributed nucleation sites,which leads to the improvement of the thermal stability.
基金Project(2007CB616905) supported by the National Basic Research Program of ChinaProject(2007AA03Z112) supported by the National High-tech Research and Development Program of China+1 种基金Project(x2jqB6080210) supported by the Natural Science Foundation of Guangdong Province,ChinaProject(9140A18040709JW1601) supported by the Advanced Research Fund of Department of Defense,China
文摘The microstructure and properties of the 93W-4Ni-2Co-1Fe(mass fraction,%) tungsten heavy alloys prepared by mechanical alloying and electric current activated sintering from mixed elemental powders were investigated.After 15 h milling,the average W grain size in the powders is decreased to 120 nm.For the powders milled for 15 h,the density,hardness and transverse rupture strength of the alloys sintered only by an intensive pulse electric current are the maximum.When the total sintering time keeps constant,the properties of the sintered alloys can be obviously improved by optimizing the sintering time of pulse-and constant-currents.A bulk ultrafine alloy with an average W grain size of about 340 nm can be obtained by sintering 15 h-milled powders in a total sintering time of 6 min.The corresponding sintered density,hardness and transverse rupture strength reach 16.78 g /cm3,HRA84.3 and 968 MPa,respectively.
