The energy-conserving performance of dividing wall column(DWC) is discussed in this paper. The heat transfer through the dividing wall is considered and the results are compared with that of common heat insulation div...The energy-conserving performance of dividing wall column(DWC) is discussed in this paper. The heat transfer through the dividing wall is considered and the results are compared with that of common heat insulation dividing wall column(HIDWC). Based on the thermodynamic analysis of heat transfer dividing wall column(HTDWC) and HIDWC, both computer simulation and experiments are employed to analyze the energyconserving situation. Mixtures of n-hexane, n-heptane and n-octane are chosen as the example for separation.The results show that the energy consumption of HTDWC is 50.3% less than that of conventional distillation column, while it is 46.4% less than that of HIDWC. It indicates that DWC is efficient on separating threecomponent mixtures and HTDWC can save more energy than HIDWC. Thus it is necessary to consider the heat transfer while applying DWC to industry.展开更多
In the radiant section of cracking furnace,the thermal cracking process is highly coupled with turbulent flow,heat transfer and mass transfer.In this paper,a three-dimensional simulation of propane pyrolysis reactor t...In the radiant section of cracking furnace,the thermal cracking process is highly coupled with turbulent flow,heat transfer and mass transfer.In this paper,a three-dimensional simulation of propane pyrolysis reactor tube is performed based on a detailed kinetic radical cracking scheme,combined with a comprehensive rigorous computational fluid dynamics(CFD)model.The eddy-dissipation-concept(EDC)model is introduced to deal with turbulence-chemistry interaction of cracking gas,especially for the multi-step radical kinetics.Considering the high aspect ratio and severe gradient phenomenon,numerical strategies such as grid resolution and refinement,stepping method and relaxation technique at different levels are employed to accelerate convergence.Large scale of radial nonuniformity in the vicinity of the tube wall is investigated.Spatial distributions of each radical reaction rate are first studied,and made it possible to identify the dominant elementary reactions.Additionally,a series of operating conditions including the feedstock feed rate,wall temperature profile and heat flux profile towards the reactor tubes are investigated.The obtained results can be used as scientific guide for further technical retrofit and operation optimization aiming at high conversion and selectivity of pyrolysis process.展开更多
The flow stress behavior of aluminum alloy 6A10 was studied by the hot compression tests at temperatures from 350℃ to 550 ℃ and strain rates from 0.1 s^-1 to 10 s^-1 with Gleeble-1500 thermo-mechanical simulator. Th...The flow stress behavior of aluminum alloy 6A10 was studied by the hot compression tests at temperatures from 350℃ to 550 ℃ and strain rates from 0.1 s^-1 to 10 s^-1 with Gleeble-1500 thermo-mechanical simulator. The result demonstrates that the temperatures of specimen differ from initial ones affected by deformation conditions, and that the softening mechanism is dynamic recovery. A new approach was proposed to analyze the flow stress character directly from actual stress, strain, temperature and strain rate data, without performing any previous flow stress correction caused by temperature variation. Comparisons between the experimental and predicted results confirm that the established flow stress model can give reasonable estimation, indicating that the mentioned approach can be used in flow stress model analysis of the materials that undergo only dynamic recovery based on the data obtained under variable deformation temperature.展开更多
This paper presents a simulator model of a marine diesel engine based on physical, semi-physical, mathematical and thermodynamic equations, which allows fast predictive simulations The whole engine system is divided i...This paper presents a simulator model of a marine diesel engine based on physical, semi-physical, mathematical and thermodynamic equations, which allows fast predictive simulations The whole engine system is divided into several functional blocks: cooling, lubrication, air, injection, combustion and emissions. The sub-models and dynamic characteristics of individual blocks are established according to engine working principles equations and experimental data collected from a marine diesel engine test bench for SIMB Company under the reference 6M26SRP1. The overall engine system dynamics is expressed as a set of simultaneous algebraic and differential equations using sub-blocks and S-Functions of Matlab/Simulink. The simulation of this model, implemented on Matlab/Simulink has been validated and can be used to obtain engine performance, pressure, temperature, efficiency, heat release, crank angle, fuel rate, emissions at different sub-blocks. The simulator will be used, in future work, to study the engine performance in faulty conditions, and can be used to assist marine engineers in fault diagnosis and estimation (FDI) as well as designers to predict the behavior of the cooling system, lubrication system, injection system, combustion, emissions, in order to optimize the dimensions of different components. This program is a platform for fault simulator, to investigate the impact on sub-blocks engine's output of changing values for faults parameters such as: faulty fuel injector, leaky cylinder, worn fuel pump, broken piston rings, a dirty turbocharger, dirty air filter, dirty air cooler, air leakage, water leakage, oil leakage and contamination, fouling of heat exchanger, pumps wear, failure of injectors (and many others).展开更多
Based on the steady-state strain measured by single-pass hot compression tests,the method by a double-pass hot compression testing was developed to measure the metadynamic-recrystallization kinetics.The metadynamic re...Based on the steady-state strain measured by single-pass hot compression tests,the method by a double-pass hot compression testing was developed to measure the metadynamic-recrystallization kinetics.The metadynamic recrystallization behavior of low-alloy steel Q345B during hot compression deformation was investigated in the temperature range of 1 000-1 100℃,the strain rate range of 0.01-0.10 s -1 and the interpass time range of 0.5-50 s on a Gleeble-3500 thermo-simulation machine.The results show that metadynamic recrystallization during the interpass time can be observed.As the deformation temperature and strain rate increase,softening caused by metadynamic recrystallization is obvious.According to the data of thermo-simulation,the metadynamic recrystallization activation energy is obtained to be Qmd=100.674 kJ/mol and metadynamic recrystallization kinetics model is set up.Finally,the error analysis of metadynamic recrystallization kinetics model proves that the model has high accuracy(correlation coefficient R=0.988 6).展开更多
In this paper,we report the growth of Ga As Sb and its crystalline property under various Sb2/As2 flux ratios and growth temperatures.We simulated the incorporation difference between Sb2 and As2 by using a non-equili...In this paper,we report the growth of Ga As Sb and its crystalline property under various Sb2/As2 flux ratios and growth temperatures.We simulated the incorporation difference between Sb2 and As2 by using a non-equilibrium thermodynamic model.Our study of Ga As Sb growth has successfully yielded,high quality In Ga As/Ga As Sb Type II superlattice for which the optical properties were characterized by photoluminescence at different excitation power and temperature.A blue-shift in luminescence peak energy with excitation power was observed and was described by a non-equilibrium carrier density model.We measured and analyzed the dependences of peak energy and integrated intensity on temperature.Two thermal processes were observed from intensity dependent photoluminescence measurements.展开更多
基金Supported by the National Natural Science Foundation of China(21306036)Science&Technology Research Fund Project for Outstanding Youth in Colleges and Universities of Hebei province(Y2012040)the Joint Specialized Research Fund for the Doctoral Program of Higher Education of China(20131317120014)
文摘The energy-conserving performance of dividing wall column(DWC) is discussed in this paper. The heat transfer through the dividing wall is considered and the results are compared with that of common heat insulation dividing wall column(HIDWC). Based on the thermodynamic analysis of heat transfer dividing wall column(HTDWC) and HIDWC, both computer simulation and experiments are employed to analyze the energyconserving situation. Mixtures of n-hexane, n-heptane and n-octane are chosen as the example for separation.The results show that the energy consumption of HTDWC is 50.3% less than that of conventional distillation column, while it is 46.4% less than that of HIDWC. It indicates that DWC is efficient on separating threecomponent mixtures and HTDWC can save more energy than HIDWC. Thus it is necessary to consider the heat transfer while applying DWC to industry.
基金Supported by the National Science&Technology Supporting Plan(2012BAF05B00)the National Basic Research Program(2012CB720500)
文摘In the radiant section of cracking furnace,the thermal cracking process is highly coupled with turbulent flow,heat transfer and mass transfer.In this paper,a three-dimensional simulation of propane pyrolysis reactor tube is performed based on a detailed kinetic radical cracking scheme,combined with a comprehensive rigorous computational fluid dynamics(CFD)model.The eddy-dissipation-concept(EDC)model is introduced to deal with turbulence-chemistry interaction of cracking gas,especially for the multi-step radical kinetics.Considering the high aspect ratio and severe gradient phenomenon,numerical strategies such as grid resolution and refinement,stepping method and relaxation technique at different levels are employed to accelerate convergence.Large scale of radial nonuniformity in the vicinity of the tube wall is investigated.Spatial distributions of each radical reaction rate are first studied,and made it possible to identify the dominant elementary reactions.Additionally,a series of operating conditions including the feedstock feed rate,wall temperature profile and heat flux profile towards the reactor tubes are investigated.The obtained results can be used as scientific guide for further technical retrofit and operation optimization aiming at high conversion and selectivity of pyrolysis process.
基金Project(50675133) supported by the National Natural Science Foundation of ChinaProject(2006CB705401) supported by the National Basic Research Program of China
文摘The flow stress behavior of aluminum alloy 6A10 was studied by the hot compression tests at temperatures from 350℃ to 550 ℃ and strain rates from 0.1 s^-1 to 10 s^-1 with Gleeble-1500 thermo-mechanical simulator. The result demonstrates that the temperatures of specimen differ from initial ones affected by deformation conditions, and that the softening mechanism is dynamic recovery. A new approach was proposed to analyze the flow stress character directly from actual stress, strain, temperature and strain rate data, without performing any previous flow stress correction caused by temperature variation. Comparisons between the experimental and predicted results confirm that the established flow stress model can give reasonable estimation, indicating that the mentioned approach can be used in flow stress model analysis of the materials that undergo only dynamic recovery based on the data obtained under variable deformation temperature.
文摘This paper presents a simulator model of a marine diesel engine based on physical, semi-physical, mathematical and thermodynamic equations, which allows fast predictive simulations The whole engine system is divided into several functional blocks: cooling, lubrication, air, injection, combustion and emissions. The sub-models and dynamic characteristics of individual blocks are established according to engine working principles equations and experimental data collected from a marine diesel engine test bench for SIMB Company under the reference 6M26SRP1. The overall engine system dynamics is expressed as a set of simultaneous algebraic and differential equations using sub-blocks and S-Functions of Matlab/Simulink. The simulation of this model, implemented on Matlab/Simulink has been validated and can be used to obtain engine performance, pressure, temperature, efficiency, heat release, crank angle, fuel rate, emissions at different sub-blocks. The simulator will be used, in future work, to study the engine performance in faulty conditions, and can be used to assist marine engineers in fault diagnosis and estimation (FDI) as well as designers to predict the behavior of the cooling system, lubrication system, injection system, combustion, emissions, in order to optimize the dimensions of different components. This program is a platform for fault simulator, to investigate the impact on sub-blocks engine's output of changing values for faults parameters such as: faulty fuel injector, leaky cylinder, worn fuel pump, broken piston rings, a dirty turbocharger, dirty air filter, dirty air cooler, air leakage, water leakage, oil leakage and contamination, fouling of heat exchanger, pumps wear, failure of injectors (and many others).
基金Project(101048) supported by Fok Ying Tung Education FoundationProject(E2008000835) supported by the Natural Science Foundation of Hebei Province,China
文摘Based on the steady-state strain measured by single-pass hot compression tests,the method by a double-pass hot compression testing was developed to measure the metadynamic-recrystallization kinetics.The metadynamic recrystallization behavior of low-alloy steel Q345B during hot compression deformation was investigated in the temperature range of 1 000-1 100℃,the strain rate range of 0.01-0.10 s -1 and the interpass time range of 0.5-50 s on a Gleeble-3500 thermo-simulation machine.The results show that metadynamic recrystallization during the interpass time can be observed.As the deformation temperature and strain rate increase,softening caused by metadynamic recrystallization is obvious.According to the data of thermo-simulation,the metadynamic recrystallization activation energy is obtained to be Qmd=100.674 kJ/mol and metadynamic recrystallization kinetics model is set up.Finally,the error analysis of metadynamic recrystallization kinetics model proves that the model has high accuracy(correlation coefficient R=0.988 6).
基金supported by the National Natural Science Foundation of China(Grant No.61176082)the National Basic Research Program of China(Grant No.2012CB619203)
文摘In this paper,we report the growth of Ga As Sb and its crystalline property under various Sb2/As2 flux ratios and growth temperatures.We simulated the incorporation difference between Sb2 and As2 by using a non-equilibrium thermodynamic model.Our study of Ga As Sb growth has successfully yielded,high quality In Ga As/Ga As Sb Type II superlattice for which the optical properties were characterized by photoluminescence at different excitation power and temperature.A blue-shift in luminescence peak energy with excitation power was observed and was described by a non-equilibrium carrier density model.We measured and analyzed the dependences of peak energy and integrated intensity on temperature.Two thermal processes were observed from intensity dependent photoluminescence measurements.