催化汽油选择性加氢脱硫装置采用热分流程的探讨

介绍了催化汽油选择性加氢技术冷分和热分工艺流程,并探讨了两种流程采用PSA氢气和重整氢气作补充新氢时在设备热负荷、循环氢纯度、装置能耗及设备投资等方面的对比。结果表明,热分流程较之冷分流程,PSA氢气作补充新氢时,能耗降低约32.2 MJ/t,循环氢纯度降低1.76百分点,设备投资减少33万元;重整氢气作补充新氢时,能耗降低约21.3 MJ/t,循环氢纯度降低4.44百分点,循环氢纯度低于85%,不利于加氢脱硫催化剂的选择性脱硫性能,且总体上看没有正的效益;相比采用重整氢气和冷分流程,采用PSA氢气和热分流程能耗降低42.7 MJ/t,节能效果显著。

A Novel Strategy for Simulating the Main Fractionator of Delayed Cokers by Separating the De-superheating Process

Delayed coking is an important process in refinery to convert heavy residue oils from crude distillation units （CDUs） and fluid catalytic cracking units （FCCUs） into dry gas, liquefied petroleum gas （LPG）, gasoline, die- sel, gas oils and cokes. The main fractionator, separating superheating reaction vapors from the coke drums into lighter oil products, involves a de-superheating section and a rectifying section, and couldn＇t be simulated as a whole column directly because of non-eouilibrium in the de-suoerheatine section. It is verv imoortant to correctlv simulate the main fractionator for operational parameter and energy-use optimization of delayed cokers. This paper discusses the principle of de-superheating processes, and then proposes a new simulation strategy. Some key issues such as composition prediction of the reaction vapors, selection of thermodynamic methods, estimation of tray efficiency, etc. are discussed. The proposed simulation approach is applied to two industrial delayed cokers with typical technological processes in a Chinese refinery by using PRO/II. The simulation results obtained are well consistent with the actual operation data, which indicates that the presented approach is suitable to simulate the main fraction- ators of delayed cokers or other distillation columns consisting of de-superheating sections and rectifying sections.

Numerical Modeling of the Performance of R22 and R290 in Adiabatic Capillary Tubes Considering Metastable Two-Phase Region——Flow Characteristics and Parametric Analysis of R22 and R290

Characteristics of R22 and its new alternative refrigerant R200 flowing through adiabatic capillary tubes are investigated based on the homogeneous model. Extensive flow variables along tube length such as pressure, temperature, viscosity, velocity. Reynolds number, friction factor and vapor quality etc are compared between the two fluids under the same operating condition. Two cases are considered, namely, either the same tube length or the same mass flow rate as inlet condition. The results show that the mass flow rate in the capillary tube of R290 is 40% lower than that of R22 due to the differences of physical properties between the two fluids. Further. a parametric analysis is performed and it appears that effects of geometric and thermodynamic parameters on mass flow rate of R290 are weaker than that of R22. When the condensing temperature is increased from 40℃ to 50℃ C. the mass flow rate for R22 is increased by 16%. while the increasing rate for R290 is 13%.

Resolving double-sided inverse heat conduction problem using calibration integral equation method

In this paper, a novel calibration integral equation is derived for resolving double-sided, two-probe inverse heat conduction problem of surface heat flux estimation. In contrast to the conventional inverse heat conduction techniques, this calibration approach does not require explicit input of the probe locations, thermophysical properties of the host material and temperature sensor parameters related to thermal contact resistance, sensor capacitance and conductive lead losses. All those parameters and properties are inherently contained in the calibration framework in terms of Volterra integral equation of the first kind. The Laplace transform technique is applied and the frequency domain manipulations of the heat equation are performed for deriving the calibration integral equation. Due to the ill-posed nature, regularization is required for the inverse heat conduction problem, a future-time method or singular value decomposition (SVD) can be used for stabilizing the ill-posed Volterra integral equation of the first kind.

Transient analysis of Casson fluid thermo-convection from a vertical cylinder embedded in a porous medium: Entropy generation and thermal energy transfer visualization

Thermal transport in porous media has stimulated substantial interest in engineering sciences due to increasing applications in filtration systems,porous bearings,porous layer insulation,biomechanics,geomechanics etc.Motivated by such applications,in this article,a numerical study of entropy generation impacts on the heat and momentum transfer in time-dependent laminar incompressible boundary layer flow of a Casson viscoplastic fluid over a uniformly heated vertical cylinder embedded in a porous medium is presented.Darcy’s law is used to simulate bulk drag effects at low Reynolds number for an isotropic,homogenous porous medium.Heat line visualization is also included.The mathematical model is derived and normalized using appropriate transformation variables.The resulting non-linear time-dependent coupled governing equations with associated boundary conditions are solved via an implicit finite difference method which is efficient and unconditionally stable.The outcomes show that entropy generation and Bejan number are both elevated with increasing values of Darcy number,Casson fluid parameter,group parameter and Grashof number.To analyze the heat transfer process in a two-dimensional domain,plotting heat lines provides an excellent approach in addition to streamlines and isotherms.It is remarked that as the Darcy number increases,the deviations of heat lines from the hot wall are reduced.

The Effect of Micro Air Movement on the Heat and Moisture Characteristics of Building Constructions

The research focuses on the effect of air movement through building constructions. Although the typical air movement inside building constructions is quite small （velocity is of order -10-5 m/s）, this research shows the impact on the heat and moisture characteristics. The paper presents a case study on the modeling and simulation of 2D heat and moisture transport with and without air movement for a building construction using a state-of-art multiphysics FEM software tool. Most other heat and moisture related models don＇t include airflow or use a steady airflow through the construction during the simulation period. However, in this model, the wind induced pressure is dynamic and thus also the airflow through the construction is dynamic. For this particular case study, the results indicate that at the intemal surface, the vapor pressure is almost not influenced by both the 2D effect and the wind speed. The temperatures at the inner surface are mostly influenced by the 2D effect. Only at wind pressure differences above 30 Pa, the airflow has a significant effect. At the extemal surface, the temperatttres are not influenced by both the 2D effect and the wind speed. However, the vapor pressure seems to be quite dependent on the wind induced pressure. Overall it is concluded that air movement through building materials seems to have a significant impact on the heat and moisture characteristics. In order to verify this statement and validate the models, new in-depth experiments including air flow through materials are recommended.

Process Study and Exergy Analysis of a Novel Air Separation Process Cooled by LNG Cold Energy

In order to resolve the problems of the current air separation process such as the complex process, cumbersome operation and high operating costs, a novel air separation process cooled by LNG cold energy is proposed in this paper, which is based on high-efficiency heat exchanger network and chemical packing separation technology. The operating temperature range of LNG cold energy is widened from 133K-203K to l13K-283K by high- efficiency heat exchanger network and air separation pressure is declined from 0.5MPa to about 0.35MPa due to packing separation technology, thereby greatly improve the energy efficiency. Both the traditional and novel air separation processes are simulated with air handling capacity of 20t＇h-1. Comparing with the traditional process, the LNG consumption is reduced by 44.2%, power consumption decrease is 211.5 kWh per hour, which means the annual benefit will be up to 1.218 million CNY. And the exergy efficiency is also improved by 42.5%.

Impact of Clocking on the Aero-Thermodynamics of a Second Stator tested in a One and a Half Stage HP Turbine

This paper focuses on the experimental investigation of the time-averaged and time-accurate aero- thermodynamics of a second stator tested in a 1.5 stage high-pressure turbine. The effect of clocking on aerodynamic and heat transfer are investigated. Tests are performed under engine representative conditions in the VKI compression tube CT3. The test program includes four different clocking positions, i.e. relative pitch-wise positions between the fh-st and the second stator. Probes located upstream and downstream of the second stator provide the thermodynamic conditions of the flow field. On the second stator airfoil, measurements are taken around the blade profile at 15, 50 and 85% span with pressure sensors and thin-film gauges. Both time-averaged and time-resolved aspects of the flow field are addressed. Regarding the time-averaged results, clocking effects are mainly observed within the leading edge region of the second stator, the largest effects being observed at 15% span. The surface static pressure distribution is changed locally, hence affecting the overall airfoil performance. For one clocking position, the thermal load of the airfoil is noticeably reduced. Pressure fluctuations are attributed to the passage of the up- stream transonic rotor and its associated pressure gradients. The pattern of these fluctuations changes noticeably as a function of docking. The time-resolved variations of heat flux and static pressure are analyzed together showing that the major effect is due to a potential interaction. The time-resolved pressure distribution integrated along the second stator surface yields the unsteady forces on the vane. The magnitude of the unsteady force is very dependent on the clocking position.

LARGE－TIME BEHMIOR OF SOLUTIONS FOR THE SYSTEM OF COMPRESSIBLE ADIABATIC FLOW THROUGHPOROUS MEDIA

Consider the systemwhich can be used to model the adiabatic gas flow through porous media. Here v is specific volume, u denotes velocity, s stands for entropy, p denotes pressure with pv <0 for v >0. It is proved that the solutions of (1) tend to those of the following nonlinear parabolic equation time-asymptotically:

Heat transfer analysis of viscoelastic fluid flow due to metachronal wave of cilia

This study describes ciliary motion on the transport of fluids in human body with heat transfer. The mathematical model of the flow of a Jeffrey fluid in a tube of finite length is considered due to metachronal wave of cilia motion. Flow equations have been modeled and simplified using similarity variables. Exact solutions of the formulated problem have been obtained for velocity, temperature and pressure gradient and graphs for velocity, pressure rise pressure gradient and temperature profile have been plotted and studied for different values of specific physical parameters. Trapping phenomena and isotherms are presented at the end of the paper.

Oscillatory blood flow through a capillary in presence of thermal radiation

This paper deals with the theoretical investigation of a fundamental problem of magne- tohydrodynamic （MHD） flow of blood in a capillary in the presence of thermal radiation and chemical reaction. The unsteadiness in the flow and temperature fields is caused by the time-dependence of the stretching velocity and the surface temperature. The fluid is considered to be non-Newtonian, whose flow is governed by the equation of a third-order fluid. The problem is first reduced to solving a system of coupled nonlinear differential equations involving several parameters. Considering blood as an electrically conducting fluid and using the present analysis, an attempt is made to compute some parameters of the blood flow by developing a suitable numerical method and by devising an appropri- ate finite difference scheme. The computational results are presented in graphical form, and thereby some theoretical predictions are made with respect to the hemodynamical flow of the blood in a hyperthermal state under the action of a magnetic field. Com- putational results for the variation in velocity, temperature, concentration, skin-friction coefi^icient, Nusselt number and Sherwood number are presented in graphical/tabular form. Since the study takes care of thermal radiation in blood flow, the results reported here are likely to have an important bearing on the therapeutic procedure of hyperthermia, particularly in understanding blood flow and heat transfer in capillaries.