热力学重要关系式的图记法

本文通过八个热力学量布于方形图的一定位置上所构成的特定图形,能够得到简单均匀系的热力学基本公式及各个偏导数之间关系的简单记忆方法。

关于电极溶液界面电位差公式的热力学推导

在不引入电化学位概念的前提下 ,导出电极溶液界面电位差的热力学表示式 。

HCl干式净化过程平衡浓度计算及其应用

利用固体产物生成的能耗分析 ,在传统的热力学平衡公式中加入修正项 ,计算 HCl气体在利用石灰类吸收剂对其进行干式净化过程中的平衡浓度 ,首次提出气固反应过程中反应气体的平衡浓度随着固体反应率的增大而上升的概念。计算结果表明 :吸收剂在达到一定的反应率以后 ,HCl的平衡浓度随温度的上升而下降。利用平衡浓度随反应率和温度的变化特征可以解释传统的热力学平衡式所不能解释的一些实验现象 ,并可以利用平衡浓度来预测利用钙基吸收剂干式净化焚烧炉排烟中 HCl的净化效率和吸收剂用量。预测结果可以判断干式净化的使用范围。

Recent Advances in Studies on Formation Mechanism of Subtropical Mode Water and Its Climate Features in North Pacific

Mode Water’, as a product of air-sea interaction, influences the thermal structure and circulation pattern in upper layer ocean and consequently affects the variations of climate. In this paper the recent research results about the subtropi-cal Mode Water in the North Pacific are overiewed. A detailed description of the three kinds of Mode Water in the subtropical North Pacific and some comparisons of their similarities and differences are introduced. Some science problems that need further exploration have been raised.

Preparation of basic magnesium carbonate and its thermal decomposition kinetics in air

The thermal decomposition process of basic magnesium carbonate was investigated. Firstly, Basic magnesium carbonate was prepared from magnesite, and the characteristics of the product were detected by X-ray diffraction （XRD） and scanning electron microscopy （SEM）. Subsequently, the thermal decomposition process of basic magnesium carbonate in air was studied by thermogravimetry-differential thermogravimetry （TG-DTG）. The results of XRD confirm that the chemical composition of basic magnesium carbonate is 4MgCO3·Mg（OH）2·4H2O. And the SEM images show that the sample is in sheet structure, with a diameter of 0.1-1 μm. The TG-DTG results demonstrate that there are two steps in the thermal decomposition process of basic magnesium carbonate. The apparent activation energies （E） were calculated by Flyrm-Wall-Ozawa method. It is obtained from Coats-Redfem＇s equation and Malek method that the mechanism functions of the two decomposition stages are D3 and A1.5, respectively. And then, the kinetic equations of the two steps were deduced as well.

Calculation of Thermodynamic Parameters for Freundlichand Temkin Isotherm Models

Derivation of the Freundlich and Temkin isotherm models from the kinetic adsorption/desorpt ion equations was carried out to calculate their thermodynamic equilibrium constants. The calculation formulae ofthree thermodynamic parameters, the standard molar Gibbs free energy change, the standard molar enthalpy change and the standard molar entropy change, of isothermal adsorption processes for Freundlich andTemkin isotherm models were deduced according to the relationship between the thermodynamic equilibriumconstats and the temperature.

Modeling and Optimization of the Steam Turbine Network of an Ethylene Plant

In this paper,we developed a hybrid model for the steam turbines of a utility system,which combines an improved neural network model with the thermodynamic model.Then,a nonlinear programming(NLP) model of the steam turbine network is formulated by utilizing the developed steam turbine models to minimize the total steam cost for the whole steam turbine network.Finally,this model is applied to optimize the steam turbine network of an ethylene plant.The obtained results demonstrate that this hybrid model can accurately estimate and evaluate the performance of steam turbines,and the significant cost savings can be made by optimizing the steam turbine network operation at no capital cost.

Ignition models and simulation of solid propellant of thermodynamic undersea vehicle

The starting characteristics of thermodynamic undersea vehicle systems are determined by the geometry, size and combustion area of solid propellants, which directly effect liquid propellant pipeline design. It is necessary to establish accurate burning models for solid propellants. Based on combustion models using powder rings and two different solid ignition grains, namely star-shaped ignition grains and stuffed ignition grains, a mathematic model of the ignition process of the propulsion system was built. With the help of Matlab, a series of calculations were made to determine the effects of different grains on ignition characteristics. The results show that stuffed ignition grain is best suited to be the ignition grain of a thermodynamic undersea vehicle system.

Theoretical and experimental research on heat transfer performance of the semi-open heat pipe

This paper focuses on the heat transfer performance of semi-open heat pipe which is a new type of heat pipe. After analyzing its condensation heat transfer mechanisms theoretically, several semi-open heat pipes in different length ratios and upper hole diameters are studied experimentally and compared with the same dimensions closed heat pipes. Experimental results show that the heat transfer performance of semi-open heat pipe becomes better by increasing heat transfer rate. At the first transitional point, the heat transfer performance of semi-open heat pipe approaches the level of the closed heat pipe. It is suitable to choose upper small hole about 1 mm in diameter and length ratio larger than 0.6 for the semi-open heat pipe.

Mechanism and Kinetics of Thermal Dissociation of Inclusion Complex of β-Cyclodextrin and 1-Methylcyclopropene

The inclusion-complex of CD-MCP （β-cyclodextrin （β-CD） including 1-methylcyclopropene （1-MCP）） was prepared and characterized. Basing on programmed-heating procedure and weight-temperature analysis, as well as the application of Satava-Sestak＇s, Ozawa＇s and Kissinger＇s methods, the mechanism and kinetics of thermal dissociation of this inclusion complex were studied. An additional mass loss is found at 170-180℃. The mechanism of thermal dissociation of CD-MCP is dominated by a one-dimensional random nucleation and subsequent growth process （A2/3）. The activation energy Es and the pre-exponential factor AS for the process are 102.14 kJ/mol and 3.63×10^10s^-1, respectively. This ES value shows that there is no strong chemical intere, ctions between β-CD and 1-MC;P,

A New Alpha-function for the Peng-Robinson Equation of State： Application to Natural Gas

Cubic equations of state(EOSs) are simple and easy at calculation. One way of improving the accuracy of a cubic EOS is through the modification of temperature-dependent energy parameter by using alpha-function.The industrial applications of natural gas are very wide and as a result, prediction of thermodynamic properties and phase behavior of natural gas is an important part of design for such processes. In this work we develop a newα-function for the Peng-Robinson(PR) EOS with the parameters optimized especially for natural gas components.The parameters are generalized as a linear function of acentric factor. The results are compared to the predictions from original PR EOS and other α-functions in literature. It is shown that the new α-function presents a good accuracy with the average deviation of 1.42% for natural gas components.

Perturbation to Symmetries and Adiabatic Invariants of Nonholonomic Dynamical System of Relative Motion

Based on the theory of symmetries and conserved quantities, the exact invariants and adiabatic invariants of nonholonomic dynamical system of relative motion are studied. The perturbation to symmetries for the nonholonomic dynamical system of relative motion under small excitation is discussed. The concept of high-order adiabatic invariant is presented, and the form of exact invariants and adiabatic invariants as well as the conditions for their existence are given. Then the corresponding inverse problem is studied.

Fermionic Zero Modes in Self-dual Vortex Background on a Torus

We study fermionic zero modes in the self-dual vortex background on an extra two-dimensional Riemann surface in （5＋1） dimensions. Using the generalized Abelian-Higgs model, we obtain the inner topological structure of the self-dual vortex and establish the exact self-duality equation with topological term. Then we analyze the Dirac operator on an extra torus and the effective Lagrangian of four-dimensional fermions with the self-dual vortex background. Solving the Dirac equation, the fermionic zero modes on a torus with the self-dual vortex background in two simple cases are obtained.

Study of Thermodynamics of Liquid Noble-Metals Alloys Through a Pseudopotential Theory

The Gibbs-Bogoliubov （GB） inequality is applied to investigate the thermodynamic properties of some equiatomic noble metal alloys in liquid phase such as Au-Cu, Ag-Cu, and Ag-Au using well recognized pseudopotential formalism. For description of the structure, well known Percus-Yevick （PY） hard sphere model is used as a reference system. By applying a variation method the best hard core diameters have been found which correspond to minimum free energy. With this procedure the thermodynamic properties such as entropy and heat of mixing have been computed. The influence of local field correction function viz; Hartree （H）, Taylor （T）, lehimaru-Utsumi （IU）, Farid et al. （F）, and Sarkar et al. （S） is also investigated. The computed results of the excess entropy compares favourably in the case of liquid alloys while the agreement with experiment is poor in the case of heats of mixing. This may be due to the sensitivity of the heats of mixing with the potential parameters and the dielectric function.

Modeling and simulation of dynamic performance of horizontal steam-launch system

Based on theory of variable-mass system thermodynamics, the dynamic mathematic models of each component of the horizontal steam-launch system were established, and by the numerical simulation of the system launching process, the thermodynamics and kinetics characteristics of the system with three valves of different flow characteristics were got. The simulation results show that the values of the peak-to-average ratios of dimensionless acceleration with the equal percentage valve, the linear valve and the quick opening valve are 1.355, 1.614 and 1.722, respectively, and the final values of the dimensionless velocities are 0.843, 0.957 and 1.0, respectively. In conclusion, the value of the dimensionless velocity with the equal percentage valve doesn't reach the set value of 0.90 when the dimensionless displacement is 0.82, while the system with the linear valve can meet the launching requirement, as well as the fluctuation range of dimensionless acceleration is less than that of the quick opening valve. Therefore, the system with the linear valve has the best performance among the three kinds of valves.

Influence of Condensing Temperature on Heat Pump Efficiency

The thermodynamic aspect of a compression type heat pump （HP） is briefly described and special attention is given to investigation of condensing temperature influence on heat pump efficiency in heating mode, expressed by its coefficient of performance （COP）. Heat pumps are usually applied for the purposes of heating and cooling of energy efficient buildings where they have advantages in low-temperature systems, as it is well documented in the paper. The comparison of real thermodynamic processes with thermodynamically most favorable Camot＇s process is made. The results in the paper show that COP is diminishing with increasing of condensing temperature and also depends on real properties of working fluids. The impact of compressor efficiency for two real working media is also analyzed in the paper. There is significant diminishing of COP with diminishing of compressor efficiency. The intension of the paper is to help better understanding of this very effective and prosperous technology, and to encourage its development, production, and efficient application.

Presence of Contaminants in Refrigerant and Their Effect on Refrigeration Cycle

Refrigerant is a medium used in refrigeration cycle. Until now in thermodynamic models calculations of refrigerant is not considered with lubricant and moist air but as an ideal pure gas （without any contaminants）. This is also the case in refrigeration cycle where the refrigerant is very often considered as an ideal one. Lubricant, air and water vapour are not considered in thermodynamic calculations in spite of their existence. The problems in the existing research are summarized. A further study is suggested on refrigerant systems. This circulation of such calculations is at the origin of a deviation from a theoretical behaviour. This article aims at reviewing the researches of oil-refrigerant, air-refrigerant, moist air-refrigerant or oil-moist air-refrigerant mixtures and focuses particularly on mixture enthalpy calculation. This paper deals with the description of the real mixture of refrigerant and contaminants （lubricant, water, moist air and other remains of refrigerants at elevated pressures and temperatures） which flow in a refrigerating cycle and the main point of this paper is to appoint thermodynamic parameters of such a mixture using the thermodynamic formulas.

Study on heat transfer for falling liquid film flow with consideration of interfacial evaporation

The interfacial evaporative heat transfer was included in the semi-empirical study of the heat transfer for the falling liquid film flow. The investigations showed that, the inclusion of the interfacial eveiporative heat transfer in the turbulent model would lower the predicted convective heat transfer coefficient. Predictions of the new model resulted in a prominent deviation from that predictions of the normal model in the case of large mass flow rate and low wall heat flux. This deviation will be decreased with increasing wall heat flux, such that it will be asymptotic zero at very high wall heat flux. Predictions of the new model agreed well with the current experimental measurements. This study has verified that the Reynolds number is not the sole crucial parameter for heat transfer of falling liquid film flow, and wall heat flux will be another important independent parameter. This result is consistent with our previous studies.

Concentration and temperature dependence of viscosity of uranium solutions in H2O and 3mol／L HNO3

Viscosities of uranium solutions in H2O and 3 mol/L HNO3 medium were measured by Ubbelhode flow vis-cometer in the concentration range of 0.5%3.0% from 10 篊 to 30 篊 at 5 篊 interval. Viscosity data were interpreted in terms of an empirical equation; h =aoexp(boM+coM2). Values of coefficients ao, bo and co were calculated for all the three systems studied. Flow activation energies and thermodynamic parameters were also evaluated.

Effect of nano-sized Al2O3 reinforcing particles on uniaxial and high cycle fatigue behaviors of hot-forged AZ31B magnesium alloy

The effect of hot-forging process was investigated on microstructural and mechanical properties of AZ31 B alloy and AZ31 B/1.5 vol.%Al2 O3 nanocomposite under static and cycling loading. The as-cast alloy and composite were firstly subjected to a homogenization heat treatment at 450 ℃ and then an open-die forging at 450 ℃. The results indicated that the presence of reinforcing particles led to grain refinement and improvement of dynamic recrystallization. The forging process was more effective to eliminate the porosity in the cast alloy workpiece. Microhardness of the forged composite was increased by up to 80% and 16%, in comparison with those of the cast and forged alloy samples, respectively. Ultimate tensile strength and maximum tensile strain of the composite were improved by up to 45% and 23%, compared with those of the forged alloy in similar regions. These enhancements were respectively 50% and 37% in the compression test. The composite exhibited a fatigue life improvement in the region with low applied strain;however, a degradation was observed in the high applied strain region. Unlike AZ31 B samples, tensile, compressive and high cycle fatigue behaviors of the composite showed less sensitivity to the applied strain, which can be attributed to the amount of porosity in the samples before and after the hot-forging.