The influences of hot stamping parameters such as heating temperature,soaking time,deformation temperature and cooling medium on the phase transformation,microstructure and mechanical properties of 30MnB5 and 22MnB5 a...The influences of hot stamping parameters such as heating temperature,soaking time,deformation temperature and cooling medium on the phase transformation,microstructure and mechanical properties of 30MnB5 and 22MnB5 are investigated and analyzed in this work.The quenching experiment,tensile testing,hardness measurement and microstructure observation were conducted to obtain the mechanical and microstructural data.The results indicate that 30MnB5 possesses a higher tensile strength but a lower elongation than 22MnB5,if hot stamped at the same process parameter.The tensile strength and hardness of the hot stamped specimens decrease under inappropriate heating conditions for two reasons,insufficient austenitization or coarse austenite grains.The austenitic forming rate of 30MnB5 is higher than that of 22MnB5,because more cementite leads to higher nucleation rate and diffusion coefficient of carbon atom.More amount of fine martensite forms under the higher deformation temperature or the quicker cooling rate.展开更多
The adsorption capability of D318 resin for Cr（Ⅵ） was investigated by chemistry analysis. Experimental results show that D318 resin has the best adsorption ability for Cr（Ⅵ） at pH=3.16 in HAc-NaAc medium. The st...The adsorption capability of D318 resin for Cr（Ⅵ） was investigated by chemistry analysis. Experimental results show that D318 resin has the best adsorption ability for Cr（Ⅵ） at pH=3.16 in HAc-NaAc medium. The statically saturated adsorption capacity of the resin is 265.4 mg/g. The thermodynamic adsorption parameters, enthalpy change AH and free energy change AG298 of the adsorption reaction are 4.81 and -5.16 kJ/mol, respectively. The apparent activation energy Ea is 22.4 kJ/mol. The adsorption behavior obeys the Freundlich isotherm. The molar coordination ratio of the functional group of resin to Cr（Ⅵ） is 3：2. Cr（Ⅵ） adsorbed on D318 resin can be eluted by 5%NaOH-5%NaCl quantitatively.展开更多
Cubic equations of state(EOSs) are simple and easy at calculation. One way of improving the accuracy of a cubic EOS is through the modification of temperature-dependent energy parameter by using alpha-function.The ind...Cubic equations of state(EOSs) are simple and easy at calculation. One way of improving the accuracy of a cubic EOS is through the modification of temperature-dependent energy parameter by using alpha-function.The industrial applications of natural gas are very wide and as a result, prediction of thermodynamic properties and phase behavior of natural gas is an important part of design for such processes. In this work we develop a newα-function for the Peng-Robinson(PR) EOS with the parameters optimized especially for natural gas components.The parameters are generalized as a linear function of acentric factor. The results are compared to the predictions from original PR EOS and other α-functions in literature. It is shown that the new α-function presents a good accuracy with the average deviation of 1.42% for natural gas components.展开更多
In this paper, the spot welding technology of a new kind of 22MnMoB hot stamping quenched steel sheet was systematically studied by power frequency spot welder. Through a series of technology and test experiments, we ...In this paper, the spot welding technology of a new kind of 22MnMoB hot stamping quenched steel sheet was systematically studied by power frequency spot welder. Through a series of technology and test experiments, we have obtained the optimal spot welding technological parameter condition. According to the results, the relations among spot welding technological parameter, welding nugget, mechanical property and fracture mode were discussed. The effects of all the welding parameters such as welding current, welding time and electrode force on the quality of joint can be boiled down to one thing--the diameter of welding nugget. The experimental results showed that welding nugget diameter determines the mechanical property of spot welding joint and the relation between welding nugget diameter and the mechanical property of joint presents a kind of linear mathematic representation. There are two typical fracture models of 22MnMoB hot stamping quenched steel sheet, i.e., interracial fracture and nugget pullout. Other than mild steel or normal high strength steel, in the shearing tensile test, hot stamping quenched steel has a great tendency to fail in interfacial mode due to the effects of high strength matrix structure, welding soft zone and the porosity level of fusion zone.展开更多
The lattice parameters, elastic constants, cohesive energy, structural energy differences, as well as the properties of point defects and planar defects of hexagonal closepacked yttrium （hcpY） have been studied with...The lattice parameters, elastic constants, cohesive energy, structural energy differences, as well as the properties of point defects and planar defects of hexagonal closepacked yttrium （hcpY） have been studied with ab initio density functional theory for constructing an ex tensive database. Based on an analytical bondorder poial scheme, empirical manybody interatomic potential for hcpY has been developed. The model is fitted to some properties of Y, e.g., the lattice parameters, elastic constants, bulk modulus, cohesive energy, vacancy formation energy, and the structural energy differences. The present potential has ability to reproduce defect properties including the selfinterstitial atoms formation energies, vacancy formation energy, divacancy binding energy, as well as the bulk properties and the thermal dynamic properties.展开更多
基金Projects(51705018,U1564202)supported by the National Natural Science Foundation of China
文摘The influences of hot stamping parameters such as heating temperature,soaking time,deformation temperature and cooling medium on the phase transformation,microstructure and mechanical properties of 30MnB5 and 22MnB5 are investigated and analyzed in this work.The quenching experiment,tensile testing,hardness measurement and microstructure observation were conducted to obtain the mechanical and microstructural data.The results indicate that 30MnB5 possesses a higher tensile strength but a lower elongation than 22MnB5,if hot stamped at the same process parameter.The tensile strength and hardness of the hot stamped specimens decrease under inappropriate heating conditions for two reasons,insufficient austenitization or coarse austenite grains.The austenitic forming rate of 30MnB5 is higher than that of 22MnB5,because more cementite leads to higher nucleation rate and diffusion coefficient of carbon atom.More amount of fine martensite forms under the higher deformation temperature or the quicker cooling rate.
基金Project (Y304121) supported by the Natural Science Foundation of Zhejiang Province,China
文摘The adsorption capability of D318 resin for Cr（Ⅵ） was investigated by chemistry analysis. Experimental results show that D318 resin has the best adsorption ability for Cr（Ⅵ） at pH=3.16 in HAc-NaAc medium. The statically saturated adsorption capacity of the resin is 265.4 mg/g. The thermodynamic adsorption parameters, enthalpy change AH and free energy change AG298 of the adsorption reaction are 4.81 and -5.16 kJ/mol, respectively. The apparent activation energy Ea is 22.4 kJ/mol. The adsorption behavior obeys the Freundlich isotherm. The molar coordination ratio of the functional group of resin to Cr（Ⅵ） is 3：2. Cr（Ⅵ） adsorbed on D318 resin can be eluted by 5%NaOH-5%NaCl quantitatively.
文摘Cubic equations of state(EOSs) are simple and easy at calculation. One way of improving the accuracy of a cubic EOS is through the modification of temperature-dependent energy parameter by using alpha-function.The industrial applications of natural gas are very wide and as a result, prediction of thermodynamic properties and phase behavior of natural gas is an important part of design for such processes. In this work we develop a newα-function for the Peng-Robinson(PR) EOS with the parameters optimized especially for natural gas components.The parameters are generalized as a linear function of acentric factor. The results are compared to the predictions from original PR EOS and other α-functions in literature. It is shown that the new α-function presents a good accuracy with the average deviation of 1.42% for natural gas components.
文摘In this paper, the spot welding technology of a new kind of 22MnMoB hot stamping quenched steel sheet was systematically studied by power frequency spot welder. Through a series of technology and test experiments, we have obtained the optimal spot welding technological parameter condition. According to the results, the relations among spot welding technological parameter, welding nugget, mechanical property and fracture mode were discussed. The effects of all the welding parameters such as welding current, welding time and electrode force on the quality of joint can be boiled down to one thing--the diameter of welding nugget. The experimental results showed that welding nugget diameter determines the mechanical property of spot welding joint and the relation between welding nugget diameter and the mechanical property of joint presents a kind of linear mathematic representation. There are two typical fracture models of 22MnMoB hot stamping quenched steel sheet, i.e., interracial fracture and nugget pullout. Other than mild steel or normal high strength steel, in the shearing tensile test, hot stamping quenched steel has a great tendency to fail in interfacial mode due to the effects of high strength matrix structure, welding soft zone and the porosity level of fusion zone.
文摘The lattice parameters, elastic constants, cohesive energy, structural energy differences, as well as the properties of point defects and planar defects of hexagonal closepacked yttrium （hcpY） have been studied with ab initio density functional theory for constructing an ex tensive database. Based on an analytical bondorder poial scheme, empirical manybody interatomic potential for hcpY has been developed. The model is fitted to some properties of Y, e.g., the lattice parameters, elastic constants, bulk modulus, cohesive energy, vacancy formation energy, and the structural energy differences. The present potential has ability to reproduce defect properties including the selfinterstitial atoms formation energies, vacancy formation energy, divacancy binding energy, as well as the bulk properties and the thermal dynamic properties.
