The arguments in this paper lead to a new definition of thermodynamic equilibrium that remedies the deficiencies of the current forms. This definition relates thermodynamic equilibrium to its physical causes and accou...The arguments in this paper lead to a new definition of thermodynamic equilibrium that remedies the deficiencies of the current forms. This definition relates thermodynamic equilibrium to its physical causes and accounts for all factors that determine it for all types of equilibrium. Standard definitions of thermodynamic equilibrium are incomplete. They do not take account of all factors that determine such equilibriums, discuss the impediments which may prevent them being reached or relate the properties that define equilibriums to the physical reasons that determine them when impediments are present. The laws of thermodynamics determine the requirements for equilibrium. These laws arise from the physical behaviour of the molecules in molecular systems and are consequences of the conservation of energy, the energies of molecules, statistics, Newton＇s laws of motion, and the equi-partition of energy. The standard definition of thermodynamic equilibrium correctly defines equilibrium whenever impediments are not factors. The discussion demonstrates how impediments arise, accounts for their role in defining equilibrium and how they relate to the energies of molecules at the conditions of the system. The new definition applies to all types of equilibrium.展开更多
Electro-thermal accelerator uses high-voltage arc energy to heat the actuating medium, it being made from low-molecular weight material. Projectile acceleration is achieved by expansion of the actuating medium. Numeri...Electro-thermal accelerator uses high-voltage arc energy to heat the actuating medium, it being made from low-molecular weight material. Projectile acceleration is achieved by expansion of the actuating medium. Numerical method for calculating interior ballistics uses Lagrangian coordinates there the conservation of momentum and the energy balance are solved. A statement of the energy balance reflects the second law of thermodynamics. Lagrangian different grid and scheme for numerical calculation were used. Fully explicit scheme was employed. The solving includes two stability conditions： Courant and shock （artificial viscosity）. Numerical results were compared with the experimental research for pressure in the barrel in electro-thermal accelerator.展开更多
文摘The arguments in this paper lead to a new definition of thermodynamic equilibrium that remedies the deficiencies of the current forms. This definition relates thermodynamic equilibrium to its physical causes and accounts for all factors that determine it for all types of equilibrium. Standard definitions of thermodynamic equilibrium are incomplete. They do not take account of all factors that determine such equilibriums, discuss the impediments which may prevent them being reached or relate the properties that define equilibriums to the physical reasons that determine them when impediments are present. The laws of thermodynamics determine the requirements for equilibrium. These laws arise from the physical behaviour of the molecules in molecular systems and are consequences of the conservation of energy, the energies of molecules, statistics, Newton＇s laws of motion, and the equi-partition of energy. The standard definition of thermodynamic equilibrium correctly defines equilibrium whenever impediments are not factors. The discussion demonstrates how impediments arise, accounts for their role in defining equilibrium and how they relate to the energies of molecules at the conditions of the system. The new definition applies to all types of equilibrium.
文摘Electro-thermal accelerator uses high-voltage arc energy to heat the actuating medium, it being made from low-molecular weight material. Projectile acceleration is achieved by expansion of the actuating medium. Numerical method for calculating interior ballistics uses Lagrangian coordinates there the conservation of momentum and the energy balance are solved. A statement of the energy balance reflects the second law of thermodynamics. Lagrangian different grid and scheme for numerical calculation were used. Fully explicit scheme was employed. The solving includes two stability conditions： Courant and shock （artificial viscosity）. Numerical results were compared with the experimental research for pressure in the barrel in electro-thermal accelerator.
