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基于AutoCAD的工业汽轮机热力平衡图动态绘制系统 被引量:2
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作者 张春成 徐静霞 +2 位作者 钱小东 李蔚 盛德仁 《机电工程》 CAS 2010年第12期20-22,39,共4页
针对手工绘制汽轮机热力平衡图费时间、图形格式各异和通用性差等问题,开发了工业汽轮机热力平衡图的动态绘制系统。首先建立规范的图例库,包括部件图例、管道连线图例和文本图例,然后在Visual Studio 2005中进行程序编写,最后基于Auto... 针对手工绘制汽轮机热力平衡图费时间、图形格式各异和通用性差等问题,开发了工业汽轮机热力平衡图的动态绘制系统。首先建立规范的图例库,包括部件图例、管道连线图例和文本图例,然后在Visual Studio 2005中进行程序编写,最后基于AutoCAD应用程序,实现工业汽轮机热力平衡图的动态绘制输出。研究结果表明,该绘制系统可以和热力设计软件无缝集成,绘制不同工况、不同机型机组的热力平衡图,操作简便、高效,制图规范正确,为设计人员提高工作效率提供了很好的开发工具。 展开更多
关键词 AUTOCAD 热力平衡图 工业汽轮机
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钙盐沉钒的热力学研究 被引量:5
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作者 李贺 刘旭恒 何利华 《稀有金属与硬质合金》 CAS CSCD 北大核心 2014年第1期15-19,共5页
根据同时平衡原理以及质量守恒定律,绘制了在不同的游离总钙浓度下Ca-V(V)-H2O体系25℃时的热力学平衡图,并进行了热力学分析。结果表明,随着溶液pH值的增大,体系中依次出现V2O5、Ca(VO3)2、CazV2O7、Ca3(VO4)2、Ca3(VO4)7... 根据同时平衡原理以及质量守恒定律,绘制了在不同的游离总钙浓度下Ca-V(V)-H2O体系25℃时的热力学平衡图,并进行了热力学分析。结果表明,随着溶液pH值的增大,体系中依次出现V2O5、Ca(VO3)2、CazV2O7、Ca3(VO4)2、Ca3(VO4)7+Ca(OH)2、Ca(OH)2六个沉淀稳定区。当沉钒反应平衡后液游离总钙浓度为0.01mol/L时,在pH=5.1~9.8范围内,钒以Ca(VO3)。形式沉淀,钒浓度最低可降至2.2×10^-3mol/L;在pH-9.8~10.3范围内,钒以Ca2V2O7形式沉淀,钒浓度最低可降至1.2×10^-2mol/L;在pH=10.3~12.6范围内,钒以Ca3(VO4)2形式沉淀,钒浓度最低可降至2.4×10^-4mol/L,沉钒效果最佳。当游离总钙浓度为0.01~1.0mol/L时,理论最佳沉钒pH值基本维持在11.0~12.6。 展开更多
关键词 钙盐沉钒 Ca-V(V)-H2O体系 热力平衡 沉淀稳定区
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Feasibility of flue-gas desulfurization by manganese oxides 被引量:3
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作者 叶万奇 李运姣 +2 位作者 孔龙 任苗苗 韩强 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2013年第10期3089-3094,共6页
For the purpose of effective and economic desulfurization of flue-gas, the predominance area diagram of the Mn-S-O system at different temperatures was constructed based on the thermodynamic data obtained from the lit... For the purpose of effective and economic desulfurization of flue-gas, the predominance area diagram of the Mn-S-O system at different temperatures was constructed based on the thermodynamic data obtained from the literatures. It is seen from this figure that flue-gas desulfurization by manganese oxides is feasible from the thermodynamic point of view. Additionally, the most appropriate temperature range for flue-gas desulfurization is between 600 and 800 K, and the reaction is strongly exothermic to maintain the heat balance. The natural manganese ores encompass large tunnels that exhibit large surface areas and highly chemical activity, which can provide a high enough SO2 removing efficiency. From the superposition of the diagrams of Mn-S-O and Fe-S-O systems, it is found that there is a coexistent stability region of MnSO4 and Fe2O3, which provides the possibility of desulfurization by selective sulfation without ferric sulfate forming. A multi-stage desulfurization system has been discussed briefly. 展开更多
关键词 predominance area diagram DESULFURIZATION manganese oxides dry FGD processes
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Thermodynamic equilibrium diagram of CaCl_2-Ca(OH)_2-H_2O system
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作者 刘卫平 徐徽 +2 位作者 杨喜云 石西昌 陈亚 《Journal of Central South University》 SCIE EI CAS 2012年第10期2751-2754,共4页
The lg c-pH diagram of the CaCl2-Ca(OH)2-H2O system and its two subsystems at 298.15 K are constructed according to the theory of thermodynamic equilibrium. The interaction characteristics between the solubility of ... The lg c-pH diagram of the CaCl2-Ca(OH)2-H2O system and its two subsystems at 298.15 K are constructed according to the theory of thermodynamic equilibrium. The interaction characteristics between the solubility of CaCl2 and Ca(OH)e can be found out from the diagrams. CaCl26H2O (s), Ca(OH)2(s) and solution coexist when the pH value of solution is about 10.8. CaC12 with the minimum solubility of 1 682.4 g/L is in equilibrium with solution when the pH value is lower than 9.4, and Ca(OH)2 with the minimum solubility of 2.749 g/L is in equilibrium with solution at the pH value over 12.1, which provides a theoretical basis for the treatment and reuse of calcium chloride mother liquor for collocating lime cream which is the precipitant in the process of synthesizing magnesium hydroxide. 展开更多
关键词 CaCl2-Ca(OH)2-H2O system SOLUBILITY lgc-pH diagram thermodynam0ic equilibrium magnesium hydroxide
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