The Collins model is introduced into the two-dimensional (2D) alternative ternary system having the Lennard-Jones (L-J) potential. The Gibbs free energy of this ternary system is calculated, and according to thermodyn...The Collins model is introduced into the two-dimensional (2D) alternative ternary system having the Lennard-Jones (L-J) potential. The Gibbs free energy of this ternary system is calculated, and according to thermodynamic theory, a group of equations that determine the solid-liquid diagram of ternary system are derived, someisothermal sectional diagrams of the 2D ternary system are obtained. The results are quite similar to the behavior ofthree-dimensional substances.展开更多
The lg c-pH diagram of the CaCl2-Ca（OH）2-H2O system and its two subsystems at 298.15 K are constructed according to the theory of thermodynamic equilibrium. The interaction characteristics between the solubility of ...The lg c-pH diagram of the CaCl2-Ca（OH）2-H2O system and its two subsystems at 298.15 K are constructed according to the theory of thermodynamic equilibrium. The interaction characteristics between the solubility of CaCl2 and Ca（OH）e can be found out from the diagrams. CaCl26H2O （s）, Ca（OH）2（s） and solution coexist when the pH value of solution is about 10.8. CaC12 with the minimum solubility of 1 682.4 g/L is in equilibrium with solution when the pH value is lower than 9.4, and Ca（OH）2 with the minimum solubility of 2.749 g/L is in equilibrium with solution at the pH value over 12.1, which provides a theoretical basis for the treatment and reuse of calcium chloride mother liquor for collocating lime cream which is the precipitant in the process of synthesizing magnesium hydroxide.展开更多
基金The project supported by National Natural Science Foundation of China
文摘The Collins model is introduced into the two-dimensional (2D) alternative ternary system having the Lennard-Jones (L-J) potential. The Gibbs free energy of this ternary system is calculated, and according to thermodynamic theory, a group of equations that determine the solid-liquid diagram of ternary system are derived, someisothermal sectional diagrams of the 2D ternary system are obtained. The results are quite similar to the behavior ofthree-dimensional substances.
基金Project(2008BAB35B04) supported by National High Technology Research and Development Program of ChinaProject(2010QZZD003) supported by Advanced Research Program of Central South University,China
文摘The lg c-pH diagram of the CaCl2-Ca（OH）2-H2O system and its two subsystems at 298.15 K are constructed according to the theory of thermodynamic equilibrium. The interaction characteristics between the solubility of CaCl2 and Ca（OH）e can be found out from the diagrams. CaCl26H2O （s）, Ca（OH）2（s） and solution coexist when the pH value of solution is about 10.8. CaC12 with the minimum solubility of 1 682.4 g/L is in equilibrium with solution when the pH value is lower than 9.4, and Ca（OH）2 with the minimum solubility of 2.749 g/L is in equilibrium with solution at the pH value over 12.1, which provides a theoretical basis for the treatment and reuse of calcium chloride mother liquor for collocating lime cream which is the precipitant in the process of synthesizing magnesium hydroxide.
