According to the differences in melting point between aluminum alloy and steel, 6013-T4 aluminum alloy was joined to galvanized steel by large spot Nd：YAG laser ＋ MIG arc hybrid brazing-fusion welding with ER4043（A...According to the differences in melting point between aluminum alloy and steel, 6013-T4 aluminum alloy was joined to galvanized steel by large spot Nd：YAG laser ＋ MIG arc hybrid brazing-fusion welding with ER4043（AlSi5） filler wire. The microstructures and mechanical properties of the brazed-fusion welded joint were investigated. The joint is divided into two parts of fusion weld and brazed seam. There is a zinc-rich zone at fusion weld toe, which consists of α（Al）-Zn solid solution and Al-Zn eutectic. The brazed seam is the Fe-Al intermetallic compounds （IMCs） layer of 2-4μm in thickness, and the IMCs include FeAl2, Fe2Al5 and Fe4Al13. FeAl2 and Fe2Al5 are located in the compact reaction layer near the steel side, and Fe4Al13 with tongue shape or sawtooth shape grows towards the fusion weld. The tensile strength of the joint firstly increases and then decreases as the welding current and laser power increase, the highest tensile strength can be up to 247.3 MPa, and the fracture usually occurs at fusion zone of the fusion weld. The hardness is the highest at the brazed seam because of hard Fe-Al IMCs, and gradually decreases along the fusion weld and galvanized steel, respectively.展开更多
We investigate the low-temperature statistical properties of a harmonic oscillator coupled to a heat bath, where the low-frequency spectrum vanishes. We obtain the exact result of the zero point energy. Due to the low...We investigate the low-temperature statistical properties of a harmonic oscillator coupled to a heat bath, where the low-frequency spectrum vanishes. We obtain the exact result of the zero point energy. Due to the low frequency shortage of environmental oscillators＇ spectral density, the coordinate and momentum correlation functions decay as T^-4 arid T^-6 respectively at zero temperature, where T is the correlation time. The low-temperature behavior of the mean energy does not violate the third law of thermodynamics, but differs largely from the Ohmic spectrum case.展开更多
The first available label standardizing a zero-balanced type of building is the Swiss Standard Minergie-A. The standard prescribes an annual net zero primary energy balance for heating, domestic hot water and ventilat...The first available label standardizing a zero-balanced type of building is the Swiss Standard Minergie-A. The standard prescribes an annual net zero primary energy balance for heating, domestic hot water and ventilation. Electricity consumption for appliances and lighting is excluded. Additionally, Minergie-A is the first standard worldwide which includes a requirement in regard to embodied energy. Based on an analysis of 39 Minergie-A buildings, this paper shows that a wide range of different energy concepts and embodied energy strategies are possible in the scope of the label. The basis of all Minergie-A buildings is a well-insulated building envelope. However, the step from the Swiss Standard Minergie-A to a Net ZEB （net zero energy building） standard which includes electricity consumption for appliances and lighting is not a very big one. Increasing the size of the photovoltaic system is sufficient in most cases. Anyway, some of the Minergie-A buildings evaluated are also Net ZEBs. In this paper, it is also shown that the net zero balance during the operational phase of Net ZEBs clearly outweighs the increased embodied energy for additional materials in a life cycle energy analysis.展开更多
Steady-state model of a high-temperature solid oxide fuel cell （SOFC） is considered, which refers to constant chemical potentials of incoming hydrogen fuel and oxidant. Lowering of the cell voltage below its reversi...Steady-state model of a high-temperature solid oxide fuel cell （SOFC） is considered, which refers to constant chemical potentials of incoming hydrogen fuel and oxidant. Lowering of the cell voltage below its reversible value is attributed to polarizations and imperfect conversions of reactions. An imperfect power formula summarizes the effect of transport laws, irreversible polarizations and efficiency of power yield. Reversible electrochemical theory is extended to the case with dissipative chemical reactions; this case includes systems with incomplete conversions, characterized by ＂reduced affinities＂ and an idle run voltage. Efficiency drop is linked with thermodynamic and electrochemical irreversibilities expressed in terms of polarizations （activation, concentration and ohmic）. Effect of incomplete conversions is modeled by assuming that substrates can be remained after the reaction and that side reactions may occur. Optimum and feasibility conditions are discussed for basic input parameters of the cell. Calculations of maximum power show that the data differ for power generated and consumed and depend on current intensity, number of mass transfer units, polarizations, electrode surface area, average chemical rate, etc.. These data provide bounds for SOFC energy generators, which are more exact and informative than reversible bounds for electrochemical transformation.展开更多
The high potential of geothermal energy in quantity and availability can be a great option, facing the huge problem of growing energy use linked with the climatic problems. Therefore, it is necessary to reduce costs a...The high potential of geothermal energy in quantity and availability can be a great option, facing the huge problem of growing energy use linked with the climatic problems. Therefore, it is necessary to reduce costs and risks for the use of geothermal energy sources. Because most of the problems have to do with insufficient knowledge about the conditions in the earth crust, the key to take root of geothermal energy is widespread research. The cooling system allows the use of all needed devices in deep boreholes without strict time or temperature limitations, which promotes the achieving of comprehensive information. To develop the purpose-built components among conducting experiments about the thermodynamic processes, a prototype is provided step by step.展开更多
An effective thermodynamic transformation analysis method was proposed in this study. According to the phenomenon of ex- ergy consumption always coupling with heat transfer process, the effective thermodynamic tempera...An effective thermodynamic transformation analysis method was proposed in this study. According to the phenomenon of ex- ergy consumption always coupling with heat transfer process, the effective thermodynamic temperatures were defined, then the actual power cycle or refrigeration/heat pump cycle was transformed into the equivalent reversible Carnot or reverse Carnot cycles for thermodynamic analysis. The derived effective thermodynamic temperature of the hot reservoir of the equivalent reverse Camot cycle is the basis of the proposed method. The combined diagram of TR-h and TR-q was adopted for the analy- sis of the system performance and the exergy consumption, which takes advantage of the visual expression of the heat/work exchange and the enthalpy change, and is convenient for the calculation of the coefficient of performance and exergy con- sumptions. Take a heat pump water heater with refrigerant of R22 for example, the proposed method was systematically intro- duced, and the fitting formulas of the effective thermodynamic temperatures were given as demonstration. The results show that the proposed method has advantage and well application foreground in the performance simulation and estimation under the variable working conditions.展开更多
We first propose fundamental solutions of wave propagation in dispersive chain subject to a localized initial perturbation in the displacement. Analytical solutions are obtained for both second order nonlinear dispers...We first propose fundamental solutions of wave propagation in dispersive chain subject to a localized initial perturbation in the displacement. Analytical solutions are obtained for both second order nonlinear dispersive chain and homogenous harmonic chain using stationary phase approximation. Solution is also compared with numerical results from molecular dynamics （MD） simulations. Locally dominant phonon modes （k-space） are introduced based on these solutions. These locally defined spatially and temporally varying phonon modes k（x, t） are critical to the concept of the local thermodynamic equilibrium （LTE）. Wave propagation accompanying with the nonequilibrium dynamics leads to the excitation of these locally defined phonon modes. It is found that the system energy is gradually redistributed among these excited phonons modes （k-space）. This redistribution process is only possible with nonlinear dispersion and requires a finite amount of time to achieve a steady state distribution. This time scale is dependent on the spatial distribution （or frequency content） of the initial perturbation and the dispersion relation. Sharper and more concentrated perturbation leads to a faster energy redistribution and dissipation. This energy redistribution generates localized phonons with various frequencies that can be important for phonon-phonon interaction and energy dissipation in nonlinear systems. Depending on the initial perturbation and temperature, the time scale associated with this energy distribution can be critical for energy dissipation compared to the Umklapp scattering process. Ballistic type of heat transport along the harmonic chain reveals that at any given position, the lowest mode （k = O） is excited first and gradually expanding to the highest mode （km^（x,t））, where km^（x,t） can only asymptotically approach the maximum mode kB of the first Brillouin zone （kmax（x,t） --~ kB）. NO energy distributed into modes with k_max（x,t） 〈 k 〈 k^B demonstrates that the local thermodynamic equilibrium cannot be established in harmonic chain. Energy is shown to be uniformly distributed in all available phonon modes k ≤ _max（x, t） at any position with heat transfer along the harmonic chain. The energy flux along the chain is shown to be a constant with time and proportional to the sound speed （ballistic transport）. Comparison with the Fourier＇s law leads to a time-dependent thermal conductivity that diverges with time.展开更多
基金Project (50905099) supported by the National Natural Science Foundation of ChinaProject (20090131120027) supported by the Specialized Research Fund for the Doctoral Program of Higher Education,China
文摘According to the differences in melting point between aluminum alloy and steel, 6013-T4 aluminum alloy was joined to galvanized steel by large spot Nd：YAG laser ＋ MIG arc hybrid brazing-fusion welding with ER4043（AlSi5） filler wire. The microstructures and mechanical properties of the brazed-fusion welded joint were investigated. The joint is divided into two parts of fusion weld and brazed seam. There is a zinc-rich zone at fusion weld toe, which consists of α（Al）-Zn solid solution and Al-Zn eutectic. The brazed seam is the Fe-Al intermetallic compounds （IMCs） layer of 2-4μm in thickness, and the IMCs include FeAl2, Fe2Al5 and Fe4Al13. FeAl2 and Fe2Al5 are located in the compact reaction layer near the steel side, and Fe4Al13 with tongue shape or sawtooth shape grows towards the fusion weld. The tensile strength of the joint firstly increases and then decreases as the welding current and laser power increase, the highest tensile strength can be up to 247.3 MPa, and the fracture usually occurs at fusion zone of the fusion weld. The hardness is the highest at the brazed seam because of hard Fe-Al IMCs, and gradually decreases along the fusion weld and galvanized steel, respectively.
文摘We investigate the low-temperature statistical properties of a harmonic oscillator coupled to a heat bath, where the low-frequency spectrum vanishes. We obtain the exact result of the zero point energy. Due to the low frequency shortage of environmental oscillators＇ spectral density, the coordinate and momentum correlation functions decay as T^-4 arid T^-6 respectively at zero temperature, where T is the correlation time. The low-temperature behavior of the mean energy does not violate the third law of thermodynamics, but differs largely from the Ohmic spectrum case.
文摘The first available label standardizing a zero-balanced type of building is the Swiss Standard Minergie-A. The standard prescribes an annual net zero primary energy balance for heating, domestic hot water and ventilation. Electricity consumption for appliances and lighting is excluded. Additionally, Minergie-A is the first standard worldwide which includes a requirement in regard to embodied energy. Based on an analysis of 39 Minergie-A buildings, this paper shows that a wide range of different energy concepts and embodied energy strategies are possible in the scope of the label. The basis of all Minergie-A buildings is a well-insulated building envelope. However, the step from the Swiss Standard Minergie-A to a Net ZEB （net zero energy building） standard which includes electricity consumption for appliances and lighting is not a very big one. Increasing the size of the photovoltaic system is sufficient in most cases. Anyway, some of the Minergie-A buildings evaluated are also Net ZEBs. In this paper, it is also shown that the net zero balance during the operational phase of Net ZEBs clearly outweighs the increased embodied energy for additional materials in a life cycle energy analysis.
文摘Steady-state model of a high-temperature solid oxide fuel cell （SOFC） is considered, which refers to constant chemical potentials of incoming hydrogen fuel and oxidant. Lowering of the cell voltage below its reversible value is attributed to polarizations and imperfect conversions of reactions. An imperfect power formula summarizes the effect of transport laws, irreversible polarizations and efficiency of power yield. Reversible electrochemical theory is extended to the case with dissipative chemical reactions; this case includes systems with incomplete conversions, characterized by ＂reduced affinities＂ and an idle run voltage. Efficiency drop is linked with thermodynamic and electrochemical irreversibilities expressed in terms of polarizations （activation, concentration and ohmic）. Effect of incomplete conversions is modeled by assuming that substrates can be remained after the reaction and that side reactions may occur. Optimum and feasibility conditions are discussed for basic input parameters of the cell. Calculations of maximum power show that the data differ for power generated and consumed and depend on current intensity, number of mass transfer units, polarizations, electrode surface area, average chemical rate, etc.. These data provide bounds for SOFC energy generators, which are more exact and informative than reversible bounds for electrochemical transformation.
文摘The high potential of geothermal energy in quantity and availability can be a great option, facing the huge problem of growing energy use linked with the climatic problems. Therefore, it is necessary to reduce costs and risks for the use of geothermal energy sources. Because most of the problems have to do with insufficient knowledge about the conditions in the earth crust, the key to take root of geothermal energy is widespread research. The cooling system allows the use of all needed devices in deep boreholes without strict time or temperature limitations, which promotes the achieving of comprehensive information. To develop the purpose-built components among conducting experiments about the thermodynamic processes, a prototype is provided step by step.
基金supported by the National Natural Science Foundation of China (Grant No. 51076147)
文摘An effective thermodynamic transformation analysis method was proposed in this study. According to the phenomenon of ex- ergy consumption always coupling with heat transfer process, the effective thermodynamic temperatures were defined, then the actual power cycle or refrigeration/heat pump cycle was transformed into the equivalent reversible Carnot or reverse Carnot cycles for thermodynamic analysis. The derived effective thermodynamic temperature of the hot reservoir of the equivalent reverse Camot cycle is the basis of the proposed method. The combined diagram of TR-h and TR-q was adopted for the analy- sis of the system performance and the exergy consumption, which takes advantage of the visual expression of the heat/work exchange and the enthalpy change, and is convenient for the calculation of the coefficient of performance and exergy con- sumptions. Take a heat pump water heater with refrigerant of R22 for example, the proposed method was systematically intro- duced, and the fitting formulas of the effective thermodynamic temperatures were given as demonstration. The results show that the proposed method has advantage and well application foreground in the performance simulation and estimation under the variable working conditions.
文摘We first propose fundamental solutions of wave propagation in dispersive chain subject to a localized initial perturbation in the displacement. Analytical solutions are obtained for both second order nonlinear dispersive chain and homogenous harmonic chain using stationary phase approximation. Solution is also compared with numerical results from molecular dynamics （MD） simulations. Locally dominant phonon modes （k-space） are introduced based on these solutions. These locally defined spatially and temporally varying phonon modes k（x, t） are critical to the concept of the local thermodynamic equilibrium （LTE）. Wave propagation accompanying with the nonequilibrium dynamics leads to the excitation of these locally defined phonon modes. It is found that the system energy is gradually redistributed among these excited phonons modes （k-space）. This redistribution process is only possible with nonlinear dispersion and requires a finite amount of time to achieve a steady state distribution. This time scale is dependent on the spatial distribution （or frequency content） of the initial perturbation and the dispersion relation. Sharper and more concentrated perturbation leads to a faster energy redistribution and dissipation. This energy redistribution generates localized phonons with various frequencies that can be important for phonon-phonon interaction and energy dissipation in nonlinear systems. Depending on the initial perturbation and temperature, the time scale associated with this energy distribution can be critical for energy dissipation compared to the Umklapp scattering process. Ballistic type of heat transport along the harmonic chain reveals that at any given position, the lowest mode （k = O） is excited first and gradually expanding to the highest mode （km^（x,t））, where km^（x,t） can only asymptotically approach the maximum mode kB of the first Brillouin zone （kmax（x,t） --~ kB）. NO energy distributed into modes with k_max（x,t） 〈 k 〈 k^B demonstrates that the local thermodynamic equilibrium cannot be established in harmonic chain. Energy is shown to be uniformly distributed in all available phonon modes k ≤ _max（x, t） at any position with heat transfer along the harmonic chain. The energy flux along the chain is shown to be a constant with time and proportional to the sound speed （ballistic transport）. Comparison with the Fourier＇s law leads to a time-dependent thermal conductivity that diverges with time.
