Most of the crude oils contain waxes which precipitate when temperature drops, resulting in deposition in pipelines and production equipment. It is necessary to set up a model which can predict the wax appearance tem-...Most of the crude oils contain waxes which precipitate when temperature drops, resulting in deposition in pipelines and production equipment. It is necessary to set up a model which can predict the wax appearance tem-perature and the amount of solid precipitated in the different conditions. A modified thermodynamic solid-liquid equilibrium model to calculate wax precipitation in crude oil systems has been developed recently. The assumption that precipitated waxes consist of several solid phases is adopted in this research, and the solid-solid transition is also considered in the modified model. The properties of the pseudo-components are determined by using empirical correlations. New correlations for properties of solid-solid and solid-liquid transitions are also established in this work on the basis of the data from the literature. The results predicted by the proposed model for three crude oil systems are compared with the experimental data and the calculated results from the literature, and good agreement is observed.展开更多
Considering the special resistance characteristics of fluids flowing through ducts with small gaps, experiments are performed to investigate the resistance characteristics of single-phase water, which is forced to flo...Considering the special resistance characteristics of fluids flowing through ducts with small gaps, experiments are performed to investigate the resistance characteristics of single-phase water, which is forced to flow through ver tical annuli. The gap sizes are 0.9, 1.4 and 2.4mm, respectively. The experiments are conducted under condition of 1atm. The water in the annuli is heated by high temperature water reversely flowing through the inner tube and the outer annulus. The results show that the flow pattern begin to change from laminar to turbulent before Reynolds number approaches 2000, the flow resistance in annulus has little relations with the temperature difference and ways of being heated, but mainly depends on the ratio of mass flux to the width of annulus.展开更多
An approach was presented to intensify the mixing process. Firstly, a novel concept, the dissipation of mass transfer ability(DMA) associated with convective mass transfer, was defined via an analogy to the heat-work ...An approach was presented to intensify the mixing process. Firstly, a novel concept, the dissipation of mass transfer ability(DMA) associated with convective mass transfer, was defined via an analogy to the heat-work conversion. Accordingly, the focus on mass transfer enhancement can be shifted to seek the extremum of the DMA of the system. To this end, an optimization principle was proposed. A mathematical model was then developed to formulate the optimization into a variational problem. Subsequently, the intensification of the mixing process for a gas mixture in a micro-tube was provided to demonstrate the proposed principle. In the demonstration example, an optimized velocity field was obtained in which the mixing ability was improved, i.e., the mixing process should be intensified by adjusting the velocity field in related equipment. Therefore, a specific procedure was provided to produce a mixer with geometric irregularities associated with an ideal velocity.展开更多
The non-isothermal kinetics of CdO nanoparticles prepared from CdCO3 precursor using thermal decomposition method was investigated. A model-fitting Malek approach and a model-free advanced isoconversional method of Vy...The non-isothermal kinetics of CdO nanoparticles prepared from CdCO3 precursor using thermal decomposition method was investigated. A model-fitting Malek approach and a model-free advanced isoconversional method of Vyazovkin were applied to the analysis of the DSC and TGA data. The results showed that CdO nanoparticles prepared from CdCO3 followed an autocatalytic reaction. Sestak–Berggren model could favorably describe the studied reaction process. Moreover, the apparent activation energy of CdCO3 decomposition was calculated to be (119.19±9.97) kJ/mol and the explicit rate equation form of CdCO3 decomposition was established.展开更多
This paper deals about testing thermal properties of the cooling device with heat pipes at inclination position, in consequence of using the natural convection to improve heat transfer properties. Head point testing o...This paper deals about testing thermal properties of the cooling device with heat pipes at inclination position, in consequence of using the natural convection to improve heat transfer properties. Head point testing of cooling device is monitoring temperature on the aluminium block of energy converter, heat pipes and ribs under temperature condition 30 ℃ in thermostatic chamber. Testing of the device was performed at tilt angles positions 0, 10 and 20° from the vertical level. The heat flux loaded to energy converter was 450 W. The next goal of the paper is to research on influence working position of the wick heat pipe on their thermal performance. In this research heat pipes were made with capillary structure sintered from copper powder granularity 100, 63 and 50 μm filled with water and ethanol. Next heat pipe thermal performance was performed by measuring heat source and working positions. Knowledge of these two research goals can bring potential improvements in purpose of cooling device for effective heat sink from high power electronic components.展开更多
A numerical study based on direct thermal to electric energy conversion was performed in a reciprocal flow porous media burner embedded with two layers of thermoelements. The burner lean combustibility limit was sough...A numerical study based on direct thermal to electric energy conversion was performed in a reciprocal flow porous media burner embedded with two layers of thermoelements. The burner lean combustibility limit was sought in order to maximize global efficiency of thermal to electrical energy conversion by minimizing fuel consumption. Once the pairs of operational variables, composition and filtrational velocity of gas inlet mixture were found, the optimal length and placement of thermoelectric elements within the reactor high thermal gradients were sought to maximize the electric current, thermoelements and system overall efficiency. A two temperature-resistance model for finite time thermodynamics was developed for the thermoelectric elements energy fluxes. Results indicate a distribution of current and efficiencies that presents a maximum at different themoelements length. Maximum values for current and system efficiency obtained were 44.3 m A and 2.5%, respectively.展开更多
This work discusses the combination of two thermodynamic cycles seeking to improve the overall chemical energy conversion rate into mechanical energy. Here one engine operates according a Rankine cycle in order to use...This work discusses the combination of two thermodynamic cycles seeking to improve the overall chemical energy conversion rate into mechanical energy. Here one engine operates according a Rankine cycle in order to use part of the thermal energy released to the boundary, i.e., the neighboring atmosphere. The analysis of this combined cycle shows that it might, under proper condition, represent a gain of 1.2% in the overall delivered engine power.展开更多
The effect of pressure on combustion and heat transfer is analyzed. The research is based on the basic combustion and heat transfer theorem. A correction for the heat calculation method for pressurized furnace is made...The effect of pressure on combustion and heat transfer is analyzed. The research is based on the basic combustion and heat transfer theorem. A correction for the heat calculation method for pressurized furnace is made on the basis of the normal pressure case. The correction takes the effect of pressurizing into account. The results show that the correction is reasonable and the method is applicable to combustion and heat transfer of the marine supercharged boiler.展开更多
In this paper, the endoreversible Otto cycle is analyzed with the entropy generation minimization and the entransy theory. The output power and the heat-work conversion efficiency are taken as the optimization objecti...In this paper, the endoreversible Otto cycle is analyzed with the entropy generation minimization and the entransy theory. The output power and the heat-work conversion efficiency are taken as the optimization objectives, and the relationships of the output power, the heat-work conversion efficiency, the entropy generation rate, the entropy generation numbers, the entransy loss rate, the entransy loss coefficient, the entransy dissipation rate and the entransy variation rate associated with work are discussed. The applicability of the entropy generation minimization and the entransy theory to the analyses is also analyzed. It is found that smaller entropy generation rate does not always lead to larger output power, while smaller entropy generation numbers do not always lead to larger heat-work conversion efficiency, either. In our calculations, both larger entransy loss rate and larger entransy variation rate associated with work correspond to larger output power, while larger entransy loss coefficient results in larger heat-work conversion efficiency. It is also found that the concept of entransy dissipation is not always suitable for the analyses because it was developed for heat transfer.展开更多
The author considers a thermal convection problem with infinite Prandtl number in two or three dimensions. The mathematical model of such problem is described as an initial boundary value problem made up of three part...The author considers a thermal convection problem with infinite Prandtl number in two or three dimensions. The mathematical model of such problem is described as an initial boundary value problem made up of three partial differential equations. One equation of the convection-dominated diffusion type for the temperature, and another two of the Stokes type for the normalized velocity and pressure. The approximate solution is obtained by a penalty finite volume method for the Stokes equation and a multistep upwind finite volume method for the convection-diffusion equation. Under suitable smoothness of the exact solution, error estimates in some discrete norms are derived.展开更多
基金Supported by the National Natural Science Foundation of China (No.10272029).
文摘Most of the crude oils contain waxes which precipitate when temperature drops, resulting in deposition in pipelines and production equipment. It is necessary to set up a model which can predict the wax appearance tem-perature and the amount of solid precipitated in the different conditions. A modified thermodynamic solid-liquid equilibrium model to calculate wax precipitation in crude oil systems has been developed recently. The assumption that precipitated waxes consist of several solid phases is adopted in this research, and the solid-solid transition is also considered in the modified model. The properties of the pseudo-components are determined by using empirical correlations. New correlations for properties of solid-solid and solid-liquid transitions are also established in this work on the basis of the data from the literature. The results predicted by the proposed model for three crude oil systems are compared with the experimental data and the calculated results from the literature, and good agreement is observed.
文摘Considering the special resistance characteristics of fluids flowing through ducts with small gaps, experiments are performed to investigate the resistance characteristics of single-phase water, which is forced to flow through ver tical annuli. The gap sizes are 0.9, 1.4 and 2.4mm, respectively. The experiments are conducted under condition of 1atm. The water in the annuli is heated by high temperature water reversely flowing through the inner tube and the outer annulus. The results show that the flow pattern begin to change from laminar to turbulent before Reynolds number approaches 2000, the flow resistance in annulus has little relations with the temperature difference and ways of being heated, but mainly depends on the ratio of mass flux to the width of annulus.
基金Supported by the National Basic Research Program of China("973" Program,No.2012CB720500)the National Natural Science Foundation of China(No.21176171)
文摘An approach was presented to intensify the mixing process. Firstly, a novel concept, the dissipation of mass transfer ability(DMA) associated with convective mass transfer, was defined via an analogy to the heat-work conversion. Accordingly, the focus on mass transfer enhancement can be shifted to seek the extremum of the DMA of the system. To this end, an optimization principle was proposed. A mathematical model was then developed to formulate the optimization into a variational problem. Subsequently, the intensification of the mixing process for a gas mixture in a micro-tube was provided to demonstrate the proposed principle. In the demonstration example, an optimized velocity field was obtained in which the mixing ability was improved, i.e., the mixing process should be intensified by adjusting the velocity field in related equipment. Therefore, a specific procedure was provided to produce a mixer with geometric irregularities associated with an ideal velocity.
文摘The non-isothermal kinetics of CdO nanoparticles prepared from CdCO3 precursor using thermal decomposition method was investigated. A model-fitting Malek approach and a model-free advanced isoconversional method of Vyazovkin were applied to the analysis of the DSC and TGA data. The results showed that CdO nanoparticles prepared from CdCO3 followed an autocatalytic reaction. Sestak–Berggren model could favorably describe the studied reaction process. Moreover, the apparent activation energy of CdCO3 decomposition was calculated to be (119.19±9.97) kJ/mol and the explicit rate equation form of CdCO3 decomposition was established.
文摘This paper deals about testing thermal properties of the cooling device with heat pipes at inclination position, in consequence of using the natural convection to improve heat transfer properties. Head point testing of cooling device is monitoring temperature on the aluminium block of energy converter, heat pipes and ribs under temperature condition 30 ℃ in thermostatic chamber. Testing of the device was performed at tilt angles positions 0, 10 and 20° from the vertical level. The heat flux loaded to energy converter was 450 W. The next goal of the paper is to research on influence working position of the wick heat pipe on their thermal performance. In this research heat pipes were made with capillary structure sintered from copper powder granularity 100, 63 and 50 μm filled with water and ethanol. Next heat pipe thermal performance was performed by measuring heat source and working positions. Knowledge of these two research goals can bring potential improvements in purpose of cooling device for effective heat sink from high power electronic components.
文摘A numerical study based on direct thermal to electric energy conversion was performed in a reciprocal flow porous media burner embedded with two layers of thermoelements. The burner lean combustibility limit was sought in order to maximize global efficiency of thermal to electrical energy conversion by minimizing fuel consumption. Once the pairs of operational variables, composition and filtrational velocity of gas inlet mixture were found, the optimal length and placement of thermoelectric elements within the reactor high thermal gradients were sought to maximize the electric current, thermoelements and system overall efficiency. A two temperature-resistance model for finite time thermodynamics was developed for the thermoelectric elements energy fluxes. Results indicate a distribution of current and efficiencies that presents a maximum at different themoelements length. Maximum values for current and system efficiency obtained were 44.3 m A and 2.5%, respectively.
文摘This work discusses the combination of two thermodynamic cycles seeking to improve the overall chemical energy conversion rate into mechanical energy. Here one engine operates according a Rankine cycle in order to use part of the thermal energy released to the boundary, i.e., the neighboring atmosphere. The analysis of this combined cycle shows that it might, under proper condition, represent a gain of 1.2% in the overall delivered engine power.
文摘The effect of pressure on combustion and heat transfer is analyzed. The research is based on the basic combustion and heat transfer theorem. A correction for the heat calculation method for pressurized furnace is made on the basis of the normal pressure case. The correction takes the effect of pressurizing into account. The results show that the correction is reasonable and the method is applicable to combustion and heat transfer of the marine supercharged boiler.
基金supported by the Scientific and Technological Research Program of Chongqing Municipal Education Commission(Grant No.KJ1710251)
文摘In this paper, the endoreversible Otto cycle is analyzed with the entropy generation minimization and the entransy theory. The output power and the heat-work conversion efficiency are taken as the optimization objectives, and the relationships of the output power, the heat-work conversion efficiency, the entropy generation rate, the entropy generation numbers, the entransy loss rate, the entransy loss coefficient, the entransy dissipation rate and the entransy variation rate associated with work are discussed. The applicability of the entropy generation minimization and the entransy theory to the analyses is also analyzed. It is found that smaller entropy generation rate does not always lead to larger output power, while smaller entropy generation numbers do not always lead to larger heat-work conversion efficiency, either. In our calculations, both larger entransy loss rate and larger entransy variation rate associated with work correspond to larger output power, while larger entransy loss coefficient results in larger heat-work conversion efficiency. It is also found that the concept of entransy dissipation is not always suitable for the analyses because it was developed for heat transfer.
文摘The author considers a thermal convection problem with infinite Prandtl number in two or three dimensions. The mathematical model of such problem is described as an initial boundary value problem made up of three partial differential equations. One equation of the convection-dominated diffusion type for the temperature, and another two of the Stokes type for the normalized velocity and pressure. The approximate solution is obtained by a penalty finite volume method for the Stokes equation and a multistep upwind finite volume method for the convection-diffusion equation. Under suitable smoothness of the exact solution, error estimates in some discrete norms are derived.