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酶促反应热动力学方程的研究 被引量:3
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作者 梅付名 吴鼎泉 +2 位作者 屈松生 杜予民 詹东风 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 1991年第6期822-824,共3页
由酶促反应速率方程积分式和酶促反应中能量变化与物质参与反应量的关系推出了单底物酶促反应的热动力学方程。并用精氨酸的酶促水解反应进行了验证,求出的米氏常数K_m和最大速率Vmax与文献值相符。
关键词 酶促反应 热动力学方程 米氏常数
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普遍化的热动力学方程 被引量:2
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作者 杨奇 陈三平 +1 位作者 薛永强 高胜利 《大学化学》 CAS 2016年第7期80-82,共3页
叙述了建立一个普遍化热动力学方程的过程。
关键词 普遍化 热动力学方程
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黄金分割法在煤热动力学方程中求古地质时间的运用 被引量:1
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作者 丁心安 李美莹 +1 位作者 李东 张学梅 《地球科学前沿(汉斯)》 2022年第3期403-410,共8页
知道古地温和镜质体反射率,可以利用迭代算法求解煤热动力学方程中的古地质时间。选择所要求的古地质时间为迭代变量,建立一个能够进行迭代的关系式,即将一个有古地质时间数学计算放在方程等式的右边成为自变量,而另一个有古地质时间数... 知道古地温和镜质体反射率,可以利用迭代算法求解煤热动力学方程中的古地质时间。选择所要求的古地质时间为迭代变量,建立一个能够进行迭代的关系式,即将一个有古地质时间数学计算放在方程等式的右边成为自变量,而另一个有古地质时间数学计算放在方程等式的左边成为因变量。用前后所迭代值的差值控制迭代过程以免迭代过程无休止地执行下去。用黄金分割值0.618优化新迭代值与前一个迭代值的关系。用5个分别在石炭纪、侏罗纪、和白垩纪的例子说明计算的简洁和有效。 展开更多
关键词 热动力学方程 古地质时间 迭代算法 黄金分割法
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特征参量法──二级反应的热动力学研究
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作者 胡启山 张元勤 +1 位作者 秦自明 曾宪诚 《化学世界》 CAS CSCD 1996年第S1期176-177,共2页
特征参量法──二级反应的热动力学研究胡启山张元勤,秦自明,曾宪诚(达县师专化学系四川达县635000)(四川大学化学系成都610064)1基础理论对于发生在热导式量热计中的等浓度二级反应,根据文献[1],其热动力学方... 特征参量法──二级反应的热动力学研究胡启山张元勤,秦自明,曾宪诚(达县师专化学系四川达县635000)(四川大学化学系成都610064)1基础理论对于发生在热导式量热计中的等浓度二级反应,根据文献[1],其热动力学方程为:式(1)、(2)中各符号的意... 展开更多
关键词 特征参量法 二级反应 动力学研究 速率常数 冷却常数 等浓度 热动力学方程 苯甲酸乙酯 混合溶剂 高等学校化学学报
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厌氧菌生长过程热化学研究
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作者 刘义 谭安民 +2 位作者 谢昌礼 屈松生 赵必均 《化学世界》 CAS CSCD 1996年第S1期166-167,共2页
厌氧菌生长过程热化学研究刘义,谭安民,谢昌礼,屈松生赵必均(武汉大学化学系武汉430072)(广州军区武汉总医院武汉430070)在细菌生长过程中,由于各种环境因素的影响和限制,其生长发热曲线往往会成为不完整、非特征... 厌氧菌生长过程热化学研究刘义,谭安民,谢昌礼,屈松生赵必均(武汉大学化学系武汉430072)(广州军区武汉总医院武汉430070)在细菌生长过程中,由于各种环境因素的影响和限制,其生长发热曲线往往会成为不完整、非特征"S"型曲线。对于不同的细菌会有不... 展开更多
关键词 化学 生长过程 厌氧菌 热动力学方程 生长曲线 艰难梭状芽胞杆菌 国家自然科学基金 指数模型 化学研究 动力学模型
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猪胃蛋白酶的热敏度
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作者 Ю.В.科斯莫捷米扬斯基 冯景祥 《天津商业大学学报》 1987年第4期95-97,共3页
采用升华干燥法干燥猪胃蛋白酶一般得要20—24小时,这样一来就会大大降低酶的活度。酶活度取决于酶在干燥过程中的加热温度和酶的热敏度。酶的热敏度可用酶活度降低之速度与酶的加热温度的关系予以表示:
关键词 胃蛋白酶活度 敏度 温度 升华干燥 相对含水量 反应级数 热动力学方程 干燥过程 感应系数 时间
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陕北榆神矿区富油煤深成变质的古地质温度计算方法初探
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作者 张学梅 李东 +1 位作者 马青华 郝静远 《煤炭加工与综合利用》 CAS 2023年第6期63-69,共7页
根据陕北榆神矿区2-2号、3-1号、5-2号煤层的地质概况(位置、镜质体反射率和平均镜质体反射率),利用吴氏煤变质热动力学方程计算古地质温度为54.2~79.4℃,并将各煤层的古地质时间、镜质组反射率和古地质温度三者之间的相互关系用图加以... 根据陕北榆神矿区2-2号、3-1号、5-2号煤层的地质概况(位置、镜质体反射率和平均镜质体反射率),利用吴氏煤变质热动力学方程计算古地质温度为54.2~79.4℃,并将各煤层的古地质时间、镜质组反射率和古地质温度三者之间的相互关系用图加以显示。对于榆神矿区的富油煤层,要升高0.02%镜质组反射率,古地质温度只需要升高3℃;而古地质时间则需要延长大约5000万a。根据煤层的最大埋深,用地表恒温15℃、鄂尔多斯盆地现地温梯度2.88℃/100 m计算得出现埋深温度仅为32.5~35.6℃,还达不到褐煤变质的临界温度。利用以正常地温为热源的煤生成镜质组反射率梯度一般低于0.06%/100 m的结论,计算得古温度梯度为8.27~8.59℃/100 m,因此重新计算的埋深温度已经升至在67.1~74.1℃。采用吴氏煤变质热动力学方程计算出最大古地质温度和平均镜质组反射率的条件下的有效受热时间6800~9600万a。 展开更多
关键词 富油煤 吴氏煤变质热动力学方程 古地质温度 深成变质 古温度梯度 埋深温度
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基于回路系统的干旱研究 被引量:1
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作者 赵建华 张强 周广胜 《干旱气象》 2016年第6期1087-1098,共12页
干旱是一种损失最大、影响人口最多的自然灾害。陆面过程中,白天水分通常从土壤输送到植被与大气中,夜间相反,水分又部分回流到土壤中。这种水分在土壤、植被和大气之间的流动可以看作是一个回路,而构成该回路的土壤、植被和大气3个部... 干旱是一种损失最大、影响人口最多的自然灾害。陆面过程中,白天水分通常从土壤输送到植被与大气中,夜间相反,水分又部分回流到土壤中。这种水分在土壤、植被和大气之间的流动可以看作是一个回路,而构成该回路的土壤、植被和大气3个部件通过水分的纽带作用构成了一个表象上的完整开放系统,称为回路系统。由此系统可以对气象干旱、农业干旱和水文干旱进行统一研究,干旱是该系统内在矛盾运动状况的外在反映。对该回路系统的分析表明,该系统主要通过内外2个过程与温度控制过程维持。基于含水量、水分流量和热量3个物理量,给出回路各部件与系统统一的水分热动力学方程组,并给出描述无旱涝过程的正态方程与描述旱涝过程的差量方程。最后,在含水量不变、流量不变、无植被的裸地、植被覆盖密集的地方以及水分运动停止等特殊情况下对干旱进行理论分析。结果表明:(1)对于干旱半干旱地区或无植被的裸地,干旱发生与否取决于水分源差量S'的符号;(2)对于湿润区或植被覆盖度很大的地区,干旱发生与否取决于S'和W'/t的符号,其中W'/t是含水量差量的时间偏导数。随后简单讨论了干旱检测的问题。总之,以回路系统和水分热动力学方程组可以对干旱进行系统和定量研究,这对于干旱的基础理论研究、干旱模式以及干旱的预测具有重要意义。 展开更多
关键词 干旱 回路系统 内外过程 水分热动力学方程
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镜质组反射率梯度与古地温梯度间的关系研究——以陕北榆神矿区5-2富油煤层为例
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作者 马青华 张学梅 +2 位作者 赵晓东 魏亚玲 郝静远 《自然科学》 2022年第4期489-497,共9页
利用吴氏煤变质热动力学方程计算5-2富油煤层的变质温度为54.2℃~76.6℃,并画出古地质时间、镜质组反射率和变质温度三者之间的关系图。为了解释极大的埋深或地温梯度差距,利用不超过深成变质的镜质组反射率梯度值 -2富油煤层的地质数据... 利用吴氏煤变质热动力学方程计算5-2富油煤层的变质温度为54.2℃~76.6℃,并画出古地质时间、镜质组反射率和变质温度三者之间的关系图。为了解释极大的埋深或地温梯度差距,利用不超过深成变质的镜质组反射率梯度值 -2富油煤层的地质数据,计算得到在R0 = 0.53%,ΔR0= 0.06%/百米,t = 193百万年时产生的地温梯度是9.14℃/百米为最大值,计算得到在R0 = 0.53%,ΔR0= 0.01%/百米,t = 205百万年时产生的地温梯度是1.55℃/百米为最小值。即使是在相同的地质条件范围内(古地质时间、镜质组反射率、埋深),也能够满足转化为不同煤化阶段所需的温度。 展开更多
关键词 煤变质热动力学方程 变质温度 埋深温度 镜质组反射率梯度 温度梯度
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基于复合阻化剂T-A的补连塔矿1-2煤活化能研究
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作者 邢时超 《内蒙古煤炭经济》 2020年第7期35-36,共2页
采用三嗪类化合物(T)和磷系阻燃剂(A)联用组成复合阻化剂T-A,基于热动力学方程与热重分析技术,运用多重扫描速率法(Kissinger和Flynn-Wall-Ozawa法)研究了试验煤样的活化能大小。
关键词 热动力学方程 活化能 多重扫描速率法 重分析
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Complete Modeling for Systems of a Marine Diesel Engine 被引量:6
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作者 Hassan Moussa Nahim Rafic Younes +1 位作者 Chadi Nohra Mustapha Ouladsine 《Journal of Marine Science and Application》 CSCD 2015年第1期93-104,共12页
This paper presents a simulator model of a marine diesel engine based on physical, semi-physical, mathematical and thermodynamic equations, which allows fast predictive simulations The whole engine system is divided i... This paper presents a simulator model of a marine diesel engine based on physical, semi-physical, mathematical and thermodynamic equations, which allows fast predictive simulations The whole engine system is divided into several functional blocks: cooling, lubrication, air, injection, combustion and emissions. The sub-models and dynamic characteristics of individual blocks are established according to engine working principles equations and experimental data collected from a marine diesel engine test bench for SIMB Company under the reference 6M26SRP1. The overall engine system dynamics is expressed as a set of simultaneous algebraic and differential equations using sub-blocks and S-Functions of Matlab/Simulink. The simulation of this model, implemented on Matlab/Simulink has been validated and can be used to obtain engine performance, pressure, temperature, efficiency, heat release, crank angle, fuel rate, emissions at different sub-blocks. The simulator will be used, in future work, to study the engine performance in faulty conditions, and can be used to assist marine engineers in fault diagnosis and estimation (FDI) as well as designers to predict the behavior of the cooling system, lubrication system, injection system, combustion, emissions, in order to optimize the dimensions of different components. This program is a platform for fault simulator, to investigate the impact on sub-blocks engine's output of changing values for faults parameters such as: faulty fuel injector, leaky cylinder, worn fuel pump, broken piston rings, a dirty turbocharger, dirty air filter, dirty air cooler, air leakage, water leakage, oil leakage and contamination, fouling of heat exchanger, pumps wear, failure of injectors (and many others). 展开更多
关键词 marine diesel engine engine system cooling system lubrication system air system injection system combustion system emissions system fault diagnosis and estimation (FDI)
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Acarbose Isolation with Gel Type Strong Acid Cation Exchange Resin: Equilibrium, Kinetic and Thermodynamic Studies 被引量:3
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作者 王亚军 于蕾 +2 位作者 郑裕国 王远山 沈寅初 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2013年第10期1106-1113,共8页
Acarbose, a potent α-glucosidase inhibitor, is widely used as an oral anti-diabetic drug for the treatment of the type 2, non-insulin-dependent diabetes. In this work, a gel type strong acid cation exchange resin 001... Acarbose, a potent α-glucosidase inhibitor, is widely used as an oral anti-diabetic drug for the treatment of the type 2, non-insulin-dependent diabetes. In this work, a gel type strong acid cation exchange resin 001×4 was applied to isolate acarbose from fermentation broth. It was demonstrated that cation exchanger 001×4 displayed a large adsorption capacity and quick exchange rate for acarbose. The static adsorption equilibrium data were well fitted to the Langmuir equation. Column adsorption experiments demonstrated that high dynamic adsorption capacity was reached at bed height of 104.4 mm, feed flow rate of 1.0 ml·min 1and acarbose concentration of 4.0 mg·ml 1.Under the optimized conditions, the column chromatography packed with cation exchanger 001×4 recovered 74.3%(by mass) of acarbose from Actinoplanes utahensis ZJB-08196 fermentation broth with purity of 80.1%(by mass),demonstrating great potential in the practical applications in acarbose separation. 展开更多
关键词 ACARBOSE separation cation exchange CHROMATOGRAPHY
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One-Parameter Equation of State for Gases and Gas Mixtures
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作者 李鸿仪 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2000年第2期163-166,共4页
The simplest equation of state that can be applied to calculate the thermodynamic properties of gases is the virial equation with the second coefficient B. The probability of applying the one-coefficient equation Z = ... The simplest equation of state that can be applied to calculate the thermodynamic properties of gases is the virial equation with the second coefficient B. The probability of applying the one-coefficient equation Z = exp(A/V) for the calculation of compressibility factor at critical temperature of gases and gas mixtures is investigated. It was verified that the one-coefficient equation of state can be applied to calculated the thermodynamic properties for both normal and strongly polar gases and gas mixtures. 展开更多
关键词 equation of state virial equation GASES FUGACITY correlation MIXTURE POLAR NONPOLAR
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Necessity of Integral Formalism
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作者 陶勇 《Communications in Theoretical Physics》 SCIE CAS CSCD 2011年第10期648-654,共7页
To describe the physical reality, there are two ways of constructing the dynamical equation of field, differential formalism and integral formalism. The importance of this fact is firstly emphasized by Yang in case of... To describe the physical reality, there are two ways of constructing the dynamical equation of field, differential formalism and integral formalism. The importance of this fact is firstly emphasized by Yang in case of gauge field [Phys. Rev. Lett. 33 (1974) 44fi], where the fact has given rise to a deeper understanding for Aharonov-Bohm phase and magnetic monopole [Phys. Rev. D 12 (1975) 3846]. In this paper we shall point out that such a fact also holds in general wave function of matter, it may give rise to a deeper understanding for Berry phase. Most importantly, we shall prove a point that, for general wave function of matter, in the adiabatic limit, there is an intrinsic difference between its integral formalism and differential formalism. It is neglect of this difference that leads to an inconsistency of quantum adiabatic theorem pointed out by Marzlin and Sanders [Phys. Rev. Lett. 93 (2004) 160408]. It has been widely accepted that there is no physical difference of using differential operator or integral operator to construct the dynamical equation of field. Nevertheless, our study shows that the Schroedinger differential equation (i.e., differential formalism for wave function) shall lead to vanishing Berry phase and that the Schroedinger integral equation (i.e., integral formalism for wave function), in the adiabatic limit, can satisfactorily give the Berry phase. Therefore, we reach a conclusion: There are two ways of describing physical reality, differential formalism and integral formalism; but the integral formalism is a unique way of complete description. 展开更多
关键词 quantum adiabatic theorem integral formalism differential formalism Berry phase gauge field
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On the Significance and Use of the Generalized Moist Potential Vorticity Equation
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作者 FU Shen-Ming SUN Jian-Hua 《Atmospheric and Oceanic Science Letters》 2011年第3期131-135,共5页
In this paper,the continuity and thermodynamic equations including moisture forcings were derived.Using these two equations and the basic momentum equation of local Cartesian coordinates,the budget equation of general... In this paper,the continuity and thermodynamic equations including moisture forcings were derived.Using these two equations and the basic momentum equation of local Cartesian coordinates,the budget equation of generalized moist potential vorticity(GMPV) was derived.The GMPV equation is a good generalization of the Ertel potential vorticity(PV) and moist potential vorticity(MPV) equations.The GMPV equation is conserved under adiabatic,frictionless,barotropic,or saturated atmospheric conditions,and it is closely associated with the horizontal frontogenesis and stability of the real atmosphere.A real case study indicates that term diabatic heating could be a useful diagnostic tool for heavy rainfall events. 展开更多
关键词 potential vorticity moist potential vorticity
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Breather Dynamics of the Sine-Gordon Equation 被引量:1
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作者 Stephen Johnson Anjan Biswas 《Communications in Theoretical Physics》 SCIE CAS CSCD 2013年第6期664-670,共7页
This paper studies the adiabatic dynamics of the breather soliton of the sine-Gordon equation. The integrals of motion are found and then used in soliton perturbation theory to derive the differential equation governi... This paper studies the adiabatic dynamics of the breather soliton of the sine-Gordon equation. The integrals of motion are found and then used in soliton perturbation theory to derive the differential equation governing the soliton velocity. Time-dependent functions arise and their properties are studied. These functions are found to be bounded and periodic and affect the soliton velocity. The soliton velocity is numerically plotted against time for different combinations of initial velocities and perturbation terms. 展开更多
关键词 SOLITONS PHONONS conservation laws PERTURBATIONS NUMERICS
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A Few Integrable Dynamical Systems,Recurrence Operators,Expanding Integrable Models and Hamiltonian Structures by the r-Matrix Method 被引量:1
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作者 张玉峰 Iqbal Muhammad 岳超 《Communications in Theoretical Physics》 SCIE CAS CSCD 2017年第10期463-470,共8页
We extend two known dynamical systems obtained by Blaszak, et al. via choosing Casimir functions and utilizing Novikov-Lax equation so that a series of novel dynamical systems including generalized Burgers dynamical s... We extend two known dynamical systems obtained by Blaszak, et al. via choosing Casimir functions and utilizing Novikov-Lax equation so that a series of novel dynamical systems including generalized Burgers dynamical system, heat equation, and so on, are followed to be generated. Then we expand some differential operators presented in the paper to deduce two types of expanding dynamical models. By taking the generalized Burgers dynamical system as an example, we deform its expanding model to get a half-expanding system, whose recurrence operator is derived from Lax representation, and its Hamiltonian structure is also obtained by adopting a new way. Finally, we expand the generalized Burgers dynamical system to the (29-1)-dimensional case whose Hamiltonian structure is derived by Poisson tensor and gradient of the Casimir function. Besides, a kind of (29-1)-dimensional expanding dynamical model of the (29-1)-dimensionaJ dynamical system is generated as well. 展开更多
关键词 R-MATRIX poisson tensor expanding dynamical system
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Failure modeling of folded dielectric elastomer actuator
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作者 LIU LiWu ZHANG Zhen +1 位作者 LIU YanJu LENG JinSong 《Science China(Physics,Mechanics & Astronomy)》 SCIE EI CAS 2014年第2期263-272,共10页
When subjected to voltage,the dielectric elastomer membrane reduces its thickness and expands its area under the resulting compressive force.This characteristic enables the dielectric elastomer actuators of different ... When subjected to voltage,the dielectric elastomer membrane reduces its thickness and expands its area under the resulting compressive force.This characteristic enables the dielectric elastomer actuators of different structures to be designed and fabricated.By employing the thermodynamic theory and research method proposed by Suo et al.,an equilibrium equation of folded dielectric elastomer actuator with two generalized coordinates is established.The governing equations of failure models involving electromechanical instability,zero electric field,electrical breakdown,loss of tension,and rupture by stretch are also derived.The allowable areas of folded dielectric elastomer actuators are described.These results could provide a powerful guidance to the design and performance evaluation of the dielectric elastomer actuators. 展开更多
关键词 dielectric elastomer folded dielectric elastomer actuator failure modes allowable area
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