Shape and quantity of helical baffles have great impact on the shell-side performance of helical baffled heat exchangers (HBHE). In this work, three physical models of HBHE with baffles of different shape (trisecti...Shape and quantity of helical baffles have great impact on the shell-side performance of helical baffled heat exchangers (HBHE). In this work, three physical models of HBHE with baffles of different shape (trisection, quadrant and sextant sector) were investigated. Numerical simulations were performed on HBHE at three helix an- gles (10°, 25° and 40°) by the software ANSYS CFX. Analyses of numerical results indicate that the sextant HBHE shows relatively better fluid flow performance because the leakage flow in the triangle area is evidently reduced and the fluid streamline appears much closer to an ideal spiral flow, while the trisection and quadrant HBHE show more scattered and disordered streamline distributions. The convective heat transfer coefficient and pressure drop in three types of HBHE were presented. Further investigations on the shell side performance with different helical baf- fles were implemented by the field synergy theory. Both theoretical and numerical analyses gave support on the re- lations between helical baffle shape and shell-side performance. This paper may provide useful reference for the selection of baffle shade and auantitv in HBHE.展开更多
The physical models of the outer and inner half coil jackets were simplified to two types of coiled ducts.The mathematic models of incompressible fluid at the condition of laminar flow and heat transfer in the two typ...The physical models of the outer and inner half coil jackets were simplified to two types of coiled ducts.The mathematic models of incompressible fluid at the condition of laminar flow and heat transfer in the two types of jackets for cooling process reactor were set up and solved by the semi-implicit method for pressure linked equa-tions consistent (SIMPLEC) algorithm based on a control volume method.The flow and temperature fields were given and the effects of Dean and Prandtl numbers on flow and heat transfer were studied.The results show that flow in the inner half coil jacket is found to exhibit transition of secondary flow pattern from two vortices to four vortices when the Dean number increases,but that in the outer half coil jacket is not found.The critical Dean num-ber is about 96.The inner half coil jacket has stronger heat transfer ability than the outer half coil jacket and this superiority is more evident with larger Prandtl number.However,as the Dean number is greater than 105,the flow resistance enhances more severely in the inner jacket than the outer jacket.For both jackets,the centers of the heated wall are the poorest for heat transfer.展开更多
The main objective of this work is to investigate analytically the steady nanofluid flow and heat transfer characteristics between nonparallel plane walls. Using appropriate transformations for the velocity and temper...The main objective of this work is to investigate analytically the steady nanofluid flow and heat transfer characteristics between nonparallel plane walls. Using appropriate transformations for the velocity and temperature, the basic nonlinear partial differential equations are reduced to the ordinary differential equations. Then, these equations have been solved analytically and numerically for some values of the governing parameters, Reynolds number, Re, channel half angle, α, Prandtl number, Pr, and Eckert number, Ec, using Adomian decomposition method and the Runge-Kutta method with mathematic package. Analytical and numerical results are searched for the skin friction coefficient, Nusselt number and the velocity and temperature profiles. It is found on one hand that the Nusselt number increases as Eckert number or channel half-angle increases, but it decreases as Reynolds number increases. On the other hand, it is also found that the presence of Cu nanoparticles in a water base fluid enhances heat transfer between nonparallel plane walls and in consequence the Nusselt number increases with the increase of nanoparticles volume fraction. Finally, an excellent agreement between analytical results and those obtained by numerical Runge-Kutta method is highly noticed.展开更多
The kinematical characteristics and thermophoretic deposition of inhalable particles with the diameters of 0-2.5μm (hereafter referred to as PM2.5) suspended in turbulent air flow in a rectangular duct with tempera...The kinematical characteristics and thermophoretic deposition of inhalable particles with the diameters of 0-2.5μm (hereafter referred to as PM2.5) suspended in turbulent air flow in a rectangular duct with temperature distribution were experimentally studied. Particle dynamics analyzer (PDA) was used for the on-line measurement of particle motion and particle concentration distribution in the cross-sections of the duct. The influences of the parameters such as the ratio of the bulk air temperature to the cold wall temperature and the air flow rate in the duct on the kinematical characteristics and the deposition efficiencies of PM2.5 were investigated. The experimental re- sults show that the deposition efficiencies of PM2.5 mainly depend on the temperature difference between the air and the cold wail, wffile the air flow rate and the particlecon^centration almost affect hardly tile clep0si-tion-effi ciency. The radial force thermophoresis to push PM2.5 to the cold wail is found the key factor for PM2.5 deposition.Based on the experimental results, an empirical modified Romay correlation for the calculation of thermophoretic deposition efficiency of PM2.5 is presenlext. The empirical correlation agrees reasonably well with the experimental data.展开更多
Thermogravimetric study of medical transfusion tube (MTT) waste containing polyvinyl chloride (PVC) was carried out using the thermogravimetric analyser (TGA) with N2, at different heating rates of 5, 10, 20, 30...Thermogravimetric study of medical transfusion tube (MTT) waste containing polyvinyl chloride (PVC) was carried out using the thermogravimetric analyser (TGA) with N2, at different heating rates of 5, 10, 20, 30, 50 ℃/min. The purpose is to obtain pyrolysis characteristics and kinetic parameters of medical waste. The experimental results indicate that the pyrolysis behavior of the MTT sample is in agreement with its main ingredient of PVC, appearing two stair stepping stages. The influence of the additives in MTT on pyrolysis behavior was also revealed, which could improve MTT pyrolysis at lower temperature in the first stage, and cause obvious unsmoothness and asymmetry of the second DTG peak. Four n-order kinetic models of Coats-Redfern, Ozawa, Kissinger and Freeman-carroll were used to get the kinetic parameters. Furthermore, a novel "two-step four-reaction model" was established to simulate the whole continuous process. The different methods and the kinetic parameters thus obtained were discussed and compared with each other in literatures. The reasons of deviation among kinetic values were tried to be elucidated. The new established model could more satisfactorily describe the pyrolysis process of MTT, being more mechanistic and conveniently serving for the engineering.展开更多
The plasma polymerization method and dynamic ion-beam mixed implantation method were employed to coat ultra-thin polymer films on copper plates. Experiments indicated that steady dropwise condensation of steam at atmo...The plasma polymerization method and dynamic ion-beam mixed implantation method were employed to coat ultra-thin polymer films on copper plates. Experiments indicated that steady dropwise condensation of steam at atmospheric pressure occurred. The condensation heat transfer coefficients increased by approximately 3 and 5-7 times for the polytrimethylvinylsilane film and polytetrafluoroethylene film respectively, compared with the value for film condensation under the same experimental conditions. The temperatures on the condensing surface and inside the test block were found to be rapidly and randomly fluctuated. The properties of the coated films and advantages of the methods used in this investigation were discussed briefly.展开更多
This research work numerically analyzes 2D,steady state,mixed convective heat transfer for Newtonian fluids in lid driven square enclosure with centered triangular block(blockage—10%or 30%)maintained either at the ...This research work numerically analyzes 2D,steady state,mixed convective heat transfer for Newtonian fluids in lid driven square enclosure with centered triangular block(blockage—10%or 30%)maintained either at the constant wall temperature or constant heat flux thermal conditions.The fluid flow in the enclosure is initiated by top moving wall in+x-direction,while all other walls are stationary.The top and bottom walls are thermally insulated.In particular,the governing field equations are solved for range of governing parameters such as,Reynolds number(1–1000),Prandtl number(1–100),and Grashof number展开更多
Laminar flow and heat transfer characteristics of jacketed vessel with triangular flow channels were numerically studied under hydrodynamically and thermally fully developed conditions. Constant heat flux at theheated...Laminar flow and heat transfer characteristics of jacketed vessel with triangular flow channels were numerically studied under hydrodynamically and thermally fully developed conditions. Constant heat flux at theheated wall was assumed. The numerical program code interms of vorticity, stream function, axial velocity com ponent and energy equations was written based on a finite volume method. Based on the numerical results, the flow and temperature field were given, and the effects of Dean and Prandtl numbers on flow and heat transfer were ex amined, and the correlations of flow resistance and mean Nusselt number were developed for the jacket. The results show that the structure of secondary flow is steady two vortices in the investigated range of dimensionless curvatureratio and Reynolds number. Two peaks of local Nusselt number increase significantly with Prandtl and Dean num ber increasing, but the local Nusselt numbers near two ends and at the center of the heated wall increase only slightly. The center and two ends of heated wall are the poor positions for heat transfer in the jacket. Compared with the outer half coil jacket at the same area of heated wall, curvature radius, Reynolds number and Prandtl number, e jacket of triangular flow chmnel has lower flow resistance and less mean Nusselt number.展开更多
Passive house has been constructed in China on a large-scale over the past couple years for its great energy saving potential.However,research indicates that there is a significant discrepancy in energy performance fo...Passive house has been constructed in China on a large-scale over the past couple years for its great energy saving potential.However,research indicates that there is a significant discrepancy in energy performance for heating and cooling between passive houses in different climate zones.Therefore,this research develops a comparative analysis on the energy saving potential of passive houses with the conventional around China.A sensitivity analysis of thermal characteristics of building envelope(insulation of exterior walls and windows,and airtightness)on energy consumption is further carried out to improve the climate adaptability of passive house.Moreover,the variation of energy consumption under different heat gain intensity is also compared,to evaluate the effects of envelope thermal characteristics comprehensively.Results suggest that the decrease of exterior wall insulation leads to the greatest increase in energy consumption,especially in severe cold zone in China.However,the optimal insulation may change with the internal heat gain intensity,for instance,the decrease of insulation(from 0.4 to 1.0 W/(m^(2)·K))could reduce the energy consumption by 4.65 kW·h/(m^(2)·a)when the heat gain increases to 20 W/m^(2)for buildings in Hot Summer and Cold Winter zone in China.展开更多
A low-cost adsorbent was prepared from sludge and straw by pyrolysis in a dried state with the surface area of the adsorbent of 829.49 ma. g-l, micropore volume of 0.176 cm2·g-1 and average pore radius of 5.0 nm....A low-cost adsorbent was prepared from sludge and straw by pyrolysis in a dried state with the surface area of the adsorbent of 829.49 ma. g-l, micropore volume of 0.176 cm2·g-1 and average pore radius of 5.0 nm. The kinetic, equilibrium isotherm and thermodynamic characteristics of trisodium 1-(1-naphthylazo)-2-hydroxynaphthalene- 4',6,8-trisulphonate (acid scarlet 3R) onto the adsorbent from sludge and straw were investigated. The results indicated that the pseudo second order adsorption was the predominant adsorption mechanism of acid scarlet 3R. Thus, the adsorption phenomenon was suggested as a chemical process. The adsorption data were fitted better with Langmuir model than Freundlich model, indicating that the adsorption of acid scarlet 3R belonged to the monolayer adsorption and mainly occurred in micropores.展开更多
A 2-D laminar flow model was established for CFD analysis of air-flow between louvered fins. Two louvered fins are studied based on commercial software FLUENT. Air-flow pressure drop characteristics are derived on the...A 2-D laminar flow model was established for CFD analysis of air-flow between louvered fins. Two louvered fins are studied based on commercial software FLUENT. Air-flow pressure drop characteristics are derived on the calculation of Reynolds number from 75.3 to 600. The numerical results are in good agreement with the experimental data when Reynolds is lower.展开更多
Numerical analysis was performed to investigate flow and heat transfer characteristics in spiral coiled tube heat exchanger. Radius of curvature of the spiral coiled tube was gradually increased as total rotating angl...Numerical analysis was performed to investigate flow and heat transfer characteristics in spiral coiled tube heat exchanger. Radius of curvature of the spiral coiled tube was gradually increased as total rotating angle reached 12n. As the varying radius of curvature became a dominant flow parameter, three-dimensional flow analysis was performed to this flow together with different Reynolds numbers while constant wall heat flux condition was set in thermal field. From the analysis, centrifugal force due to curvature effect is found to have significant role in behavior of pressure drop and heat transfer. The centrifugal force enhances pressure drop and heat transfer to have generally higher values in the spiral coiled tube than those in the straight tube. Even then, friction factor and Nusselt number are found to follow the proportionality with square root of the Dean number. Individual effect of flow parameters of Reynolds number and curvature ratio was investigated and effect of Reynolds number is found to be stronger than that of curvature effect.展开更多
The marine macroalgae Enteromorpha prolifera was one of the main algal genera that occurred in the widespread green tides in Qingdao, China, during the summers of 2007, 2008 and 2010. It is thus a plentiful source of ...The marine macroalgae Enteromorpha prolifera was one of the main algal genera that occurred in the widespread green tides in Qingdao, China, during the summers of 2007, 2008 and 2010. It is thus a plentiful source of biomass and could be used as a biofuel. In this study, the pyrolytic characteristics and kinetics of E. prolifera were investigated using thermogravimetric analysis (TGA) method. Cornstalk and sawdust were used as comparisons. Pyrolytic characteristics were studied using TG-DTG (thermogravimetry-derivative thermogravimetry) curves. Three stages in the pyrolytic process were determined: dehydration, dramatic weight loss and slow weight loss. E. prolifera was pyrolyzed at a lower initial temperature than the two terrestrial biomass forms. The apparent activation energy values for the three types of biomass were calculated and the mechanism functions were determined using 16 different mechanism functions, frequently used in thermal kinetics analysis. Activation energy values varied with mechanism function and the range of activation energy values for E. prolifera, cornstalk, and sawdust were 25-50 kJ/mol, 60-90 kJ/mol and 120-155 kJ/mol, respectively. This indicates that E. prolifera has low thermal stability for pyrolysis and good combustion characteristics.展开更多
A Brownian microscopic heat engine with a particle hopping on a one-dimensional lattice driven by adiscrete and periodic temperature field in a periodic sawtooth potential is investigated.In order to clarify the under...A Brownian microscopic heat engine with a particle hopping on a one-dimensional lattice driven by adiscrete and periodic temperature field in a periodic sawtooth potential is investigated.In order to clarify the underlyingphysical pictures of the heat engine, the heat flow via the potential energy and the kinetic energy of the particles areconsidered simultaneously.Based on describing the jumps among the three states, the expressions of the efficiency andpower output of the heat engine are derived analytically.The general performance characteristic curves are plotted bynumerical calculation.It is found that the power output-efficiency curve is a loop-shaped one, which is similar to onefor a real irreversible heat engine.The influence of the ratio of the temperature of the hot and cold reservoirs and thesawtooth potential on the maximum efficiency and power output is analyzed for some given parameters.When the heatflows via the kinetic energy is neglected, the power output-efficiency curve is an open-shaped one, which is similar to onefor an endroeversible heat engine.展开更多
Based on consideration of both thermodynamic and kinetic features of the subtropical summer monsoon in East Asia,a new index is defined by the moist potential vorticity (MPV) for this monsoon.Variation features of the...Based on consideration of both thermodynamic and kinetic features of the subtropical summer monsoon in East Asia,a new index is defined by the moist potential vorticity (MPV) for this monsoon.Variation features of the subtropical summer monsoon over 60 years are analyzed using National Centers for Environmental Prediction/National Center for Atmospheric Research (USA) data from 1948 to 2007.Results show that the new index can well reflect the seasonal,interannual,and interdecadal variations of the East Asian subtropical summer monsoon.Correlation analysis of the new index and precipitation data from 160 stations in China shows that in high-index years,the summer monsoon is strong,and more rain falls in eastern North China,southwestern China,and along the coast of South China and less rain falls in the Yangtze-Huaihe R.basin.In low-index years,the opposite occurs.Lastly,the new index is compared with four established monsoon indices.The new index is found to have an advantage in representing summer rainfall in the Yangtze-Huaihe R.basin.展开更多
A 3D numerical investigation has been carried out to examine periodic laminar flow and heat transfer characteristics in a circular tube with 45°V-baffles with isothermal wall.The computations are based on the fin...A 3D numerical investigation has been carried out to examine periodic laminar flow and heat transfer characteristics in a circular tube with 45°V-baffles with isothermal wall.The computations are based on the finite volume method(FVM),and the SIMPLE algorithm has been implemented.The fluid flow and heat transfer characteristics are presented for Reynolds numbers ranging from 100 to 2000.To generate main longitudinal vortex flows through the tested section,V-baffles with an attack angle of 45°are mounted in tandem and in-line arrangement on the opposite positions of the circular tube.Effects of tube blockage ratio,flow direction on heat transfer and pressure drop in the tube are studied.It is apparent that a pair of longitudinal twisted vortices(P-vortex)created by a V-baffle can induce impingement on a wall of the inter-baffle cavity and lead a drastic increase in heat transfer rate at tube wall.In addition,the larger blockage ratio results in the higher Nusselt number and friction factor values.The computational results show that the optimum thermal enhancement factor is around 3.20 at baffle height of B=0.20 and B=0.25 times of the tube diameter for the V-upstream and V-downstream,respectively.展开更多
The thermal decomposition characteristics of methyl oleate were preliminarily investigated under nitrogen atmo-sphere by a thermogravimetric analyzer when the ester was heated at a heating rate of 10℃/min from room t...The thermal decomposition characteristics of methyl oleate were preliminarily investigated under nitrogen atmo-sphere by a thermogravimetric analyzer when the ester was heated at a heating rate of 10℃/min from room temperature to 600℃. Furthermore, the pyrolytic and kinetic characteristics of methyl oleate were intensively studied at different heating rates. The gaseous species obtained during thermal decomposition were also identiifed by the TG-FTIR coupling analysis. The results showed that the pyrolysis of methyl oleate proceeded in three stages, viz. the drying stage, the main pyrolysis stage and the residual pyrolysis stage. The initial decomposition temperature, the maximum weight loss temperature, the peak decomposition temperature and the rate of maximum weight loss of methyl oleate increased with the increasing heating rates. Gaseous CO, CO2 and H2O were the typical decomposition products from pyrolysis of methyl oleate. In addition, a kinetic model for thermal decomposition of methyl oleate was built up based on the experimental results using the Coats-Redfern integral method and the multiplelinear regression method. The activation energy, the preexponential factor, the reaction order and the kinetic equation for thermal decomposition of methyl oleate were obtained. Comparison of the experimental data with the calculated ones and analysis of statistical errors of pyrolysis ratios demonstrated that the kinetic model was reliable for studying the pyrolysis of methyl oleate. Finally, the kinetic compensation effect between the preexponential factors and the activation energy in the pyrolysis of methyl oleate was also conifrmed.展开更多
As an important high-energy chemical power source, lithium-ion power batteries come up to application problems of thermal performance, such as extended temperature range and high power charge & discharge. LiFeP04 bat...As an important high-energy chemical power source, lithium-ion power batteries come up to application problems of thermal performance, such as extended temperature range and high power charge & discharge. LiFeP04 battery is applied and developed well recently, its charge and discharge experiment at different temperatures and hybrid pulse power characterization (HPPC) test are analyzed, and the optimal temperature range of LiFeP04 battery is put forward. In order to provide experimental suggestion of power battery application and its thermal management, internal resistance, influencing factor of electromotive force and entropy change state of charge (SOC), battery thermal characteristic of different charge & discharge rates are summarized.展开更多
To obtain the pyrolysis characteristics and kinetics of preparation process of sludge-based activated carbon by ZnCl2 activation method (i.e.the pyrolysis process of the sludge with ZnCl2 activation),the characteris...To obtain the pyrolysis characteristics and kinetics of preparation process of sludge-based activated carbon by ZnCl2 activation method (i.e.the pyrolysis process of the sludge with ZnCl2 activation),the characteristic of mass loss and gas products generated during pyrolysis of the sludge with ZnCl2 activation were analyzed by thermogravimetric analysis coupled with Fourier Transform Infrared Spectroscopy (TG-FTIR).The kinetic parameters were calculated by the Coats-Redfem method and the mechanism models were established.The role of ZnCl2 in the pyrolysis process of the sludge with ZnCl2 activation was also illustrated through the comparison of the pyrolysis characteristics and kinetics of the sludge with and without ZnCl2 activation.The results showed that the pyrolysis process of the sludge with ZnCl2 activation can be divided into four stages including the dehydration of sludge and initial depolymerization of a small portion of organics matters,the decomposition of large molecular organic matters into small molecular intermediates,the further degradation of intermediates and volatilization of ZnCl2,and the decomposition of inorganic minerals and undecomposed organic matters.CO2,CO,CH4,H2O,some aldehydes and carboxylic acids are the major pyrolysis gaseous products.The activation energies and pre-exponential factors are in the range of 28.84-206.42 kJ/mol and 9885.16-8.08× 1011 min-1,respectively.During the pyrolysis of sludge,ZnC12 not only can function as a dehydration agent and inhibit the formation of tar,but also can peptize the organic matters in the sludge,making them easier to be decomposed.展开更多
基金Supported by the National Natural Science Foundation of China(51106090)the National Key Basic Research Program of China(2013CB228305)the Independent Innovation Foundation of Shandong University(2012TS190)
文摘Shape and quantity of helical baffles have great impact on the shell-side performance of helical baffled heat exchangers (HBHE). In this work, three physical models of HBHE with baffles of different shape (trisection, quadrant and sextant sector) were investigated. Numerical simulations were performed on HBHE at three helix an- gles (10°, 25° and 40°) by the software ANSYS CFX. Analyses of numerical results indicate that the sextant HBHE shows relatively better fluid flow performance because the leakage flow in the triangle area is evidently reduced and the fluid streamline appears much closer to an ideal spiral flow, while the trisection and quadrant HBHE show more scattered and disordered streamline distributions. The convective heat transfer coefficient and pressure drop in three types of HBHE were presented. Further investigations on the shell side performance with different helical baf- fles were implemented by the field synergy theory. Both theoretical and numerical analyses gave support on the re- lations between helical baffle shape and shell-side performance. This paper may provide useful reference for the selection of baffle shade and auantitv in HBHE.
基金Supported by the National Key Technologies Research and Development Program during the 10th Five-year Plan Period(2004BA319B1)the Educational Commission of Liaoning Province of China(2008S117)
文摘The physical models of the outer and inner half coil jackets were simplified to two types of coiled ducts.The mathematic models of incompressible fluid at the condition of laminar flow and heat transfer in the two types of jackets for cooling process reactor were set up and solved by the semi-implicit method for pressure linked equa-tions consistent (SIMPLEC) algorithm based on a control volume method.The flow and temperature fields were given and the effects of Dean and Prandtl numbers on flow and heat transfer were studied.The results show that flow in the inner half coil jacket is found to exhibit transition of secondary flow pattern from two vortices to four vortices when the Dean number increases,but that in the outer half coil jacket is not found.The critical Dean num-ber is about 96.The inner half coil jacket has stronger heat transfer ability than the outer half coil jacket and this superiority is more evident with larger Prandtl number.However,as the Dean number is greater than 105,the flow resistance enhances more severely in the inner jacket than the outer jacket.For both jackets,the centers of the heated wall are the poorest for heat transfer.
文摘The main objective of this work is to investigate analytically the steady nanofluid flow and heat transfer characteristics between nonparallel plane walls. Using appropriate transformations for the velocity and temperature, the basic nonlinear partial differential equations are reduced to the ordinary differential equations. Then, these equations have been solved analytically and numerically for some values of the governing parameters, Reynolds number, Re, channel half angle, α, Prandtl number, Pr, and Eckert number, Ec, using Adomian decomposition method and the Runge-Kutta method with mathematic package. Analytical and numerical results are searched for the skin friction coefficient, Nusselt number and the velocity and temperature profiles. It is found on one hand that the Nusselt number increases as Eckert number or channel half-angle increases, but it decreases as Reynolds number increases. On the other hand, it is also found that the presence of Cu nanoparticles in a water base fluid enhances heat transfer between nonparallel plane walls and in consequence the Nusselt number increases with the increase of nanoparticles volume fraction. Finally, an excellent agreement between analytical results and those obtained by numerical Runge-Kutta method is highly noticed.
基金the Special Funds for Major State Basic Research Project of China (2002CB211604)
文摘The kinematical characteristics and thermophoretic deposition of inhalable particles with the diameters of 0-2.5μm (hereafter referred to as PM2.5) suspended in turbulent air flow in a rectangular duct with temperature distribution were experimentally studied. Particle dynamics analyzer (PDA) was used for the on-line measurement of particle motion and particle concentration distribution in the cross-sections of the duct. The influences of the parameters such as the ratio of the bulk air temperature to the cold wall temperature and the air flow rate in the duct on the kinematical characteristics and the deposition efficiencies of PM2.5 were investigated. The experimental re- sults show that the deposition efficiencies of PM2.5 mainly depend on the temperature difference between the air and the cold wail, wffile the air flow rate and the particlecon^centration almost affect hardly tile clep0si-tion-effi ciency. The radial force thermophoresis to push PM2.5 to the cold wail is found the key factor for PM2.5 deposition.Based on the experimental results, an empirical modified Romay correlation for the calculation of thermophoretic deposition efficiency of PM2.5 is presenlext. The empirical correlation agrees reasonably well with the experimental data.
基金Project(50378062) supported by the National Natural Science Foundation of ChinaProject(09JCYBJC08100) supported by the Natural Science Foundation of Tianjin City,China
文摘Thermogravimetric study of medical transfusion tube (MTT) waste containing polyvinyl chloride (PVC) was carried out using the thermogravimetric analyser (TGA) with N2, at different heating rates of 5, 10, 20, 30, 50 ℃/min. The purpose is to obtain pyrolysis characteristics and kinetic parameters of medical waste. The experimental results indicate that the pyrolysis behavior of the MTT sample is in agreement with its main ingredient of PVC, appearing two stair stepping stages. The influence of the additives in MTT on pyrolysis behavior was also revealed, which could improve MTT pyrolysis at lower temperature in the first stage, and cause obvious unsmoothness and asymmetry of the second DTG peak. Four n-order kinetic models of Coats-Redfern, Ozawa, Kissinger and Freeman-carroll were used to get the kinetic parameters. Furthermore, a novel "two-step four-reaction model" was established to simulate the whole continuous process. The different methods and the kinetic parameters thus obtained were discussed and compared with each other in literatures. The reasons of deviation among kinetic values were tried to be elucidated. The new established model could more satisfactorily describe the pyrolysis process of MTT, being more mechanistic and conveniently serving for the engineering.
基金the National Natural Science Foundation of China (No. 59906002) and the Foundation for Young Teachers of Dalian University of Technology.
文摘The plasma polymerization method and dynamic ion-beam mixed implantation method were employed to coat ultra-thin polymer films on copper plates. Experiments indicated that steady dropwise condensation of steam at atmospheric pressure occurred. The condensation heat transfer coefficients increased by approximately 3 and 5-7 times for the polytrimethylvinylsilane film and polytetrafluoroethylene film respectively, compared with the value for film condensation under the same experimental conditions. The temperatures on the condensing surface and inside the test block were found to be rapidly and randomly fluctuated. The properties of the coated films and advantages of the methods used in this investigation were discussed briefly.
文摘This research work numerically analyzes 2D,steady state,mixed convective heat transfer for Newtonian fluids in lid driven square enclosure with centered triangular block(blockage—10%or 30%)maintained either at the constant wall temperature or constant heat flux thermal conditions.The fluid flow in the enclosure is initiated by top moving wall in+x-direction,while all other walls are stationary.The top and bottom walls are thermally insulated.In particular,the governing field equations are solved for range of governing parameters such as,Reynolds number(1–1000),Prandtl number(1–100),and Grashof number
基金Supported by the Speciai Pogram forLocal Universities Development of Central Finance of China (2050205), the National Natural Science Foundation of China (21106086), and the Program for Liaoning Excellent Talents in University (LJQ2012035).
文摘Laminar flow and heat transfer characteristics of jacketed vessel with triangular flow channels were numerically studied under hydrodynamically and thermally fully developed conditions. Constant heat flux at theheated wall was assumed. The numerical program code interms of vorticity, stream function, axial velocity com ponent and energy equations was written based on a finite volume method. Based on the numerical results, the flow and temperature field were given, and the effects of Dean and Prandtl numbers on flow and heat transfer were ex amined, and the correlations of flow resistance and mean Nusselt number were developed for the jacket. The results show that the structure of secondary flow is steady two vortices in the investigated range of dimensionless curvatureratio and Reynolds number. Two peaks of local Nusselt number increase significantly with Prandtl and Dean num ber increasing, but the local Nusselt numbers near two ends and at the center of the heated wall increase only slightly. The center and two ends of heated wall are the poor positions for heat transfer in the jacket. Compared with the outer half coil jacket at the same area of heated wall, curvature radius, Reynolds number and Prandtl number, e jacket of triangular flow chmnel has lower flow resistance and less mean Nusselt number.
基金Project(51825802)supported by the National Science Foundation for Distinguished Young Scholars of ChinaProject(2018YFE0106100)supported by the National Key R&D Program of China。
文摘Passive house has been constructed in China on a large-scale over the past couple years for its great energy saving potential.However,research indicates that there is a significant discrepancy in energy performance for heating and cooling between passive houses in different climate zones.Therefore,this research develops a comparative analysis on the energy saving potential of passive houses with the conventional around China.A sensitivity analysis of thermal characteristics of building envelope(insulation of exterior walls and windows,and airtightness)on energy consumption is further carried out to improve the climate adaptability of passive house.Moreover,the variation of energy consumption under different heat gain intensity is also compared,to evaluate the effects of envelope thermal characteristics comprehensively.Results suggest that the decrease of exterior wall insulation leads to the greatest increase in energy consumption,especially in severe cold zone in China.However,the optimal insulation may change with the internal heat gain intensity,for instance,the decrease of insulation(from 0.4 to 1.0 W/(m^(2)·K))could reduce the energy consumption by 4.65 kW·h/(m^(2)·a)when the heat gain increases to 20 W/m^(2)for buildings in Hot Summer and Cold Winter zone in China.
基金Supported by the Shanxi Science and Technology Agency Research Project(20100321085)the Scientific Research Foun-dation of the Shanxi Education Department(20111029)
文摘A low-cost adsorbent was prepared from sludge and straw by pyrolysis in a dried state with the surface area of the adsorbent of 829.49 ma. g-l, micropore volume of 0.176 cm2·g-1 and average pore radius of 5.0 nm. The kinetic, equilibrium isotherm and thermodynamic characteristics of trisodium 1-(1-naphthylazo)-2-hydroxynaphthalene- 4',6,8-trisulphonate (acid scarlet 3R) onto the adsorbent from sludge and straw were investigated. The results indicated that the pseudo second order adsorption was the predominant adsorption mechanism of acid scarlet 3R. Thus, the adsorption phenomenon was suggested as a chemical process. The adsorption data were fitted better with Langmuir model than Freundlich model, indicating that the adsorption of acid scarlet 3R belonged to the monolayer adsorption and mainly occurred in micropores.
文摘A 2-D laminar flow model was established for CFD analysis of air-flow between louvered fins. Two louvered fins are studied based on commercial software FLUENT. Air-flow pressure drop characteristics are derived on the calculation of Reynolds number from 75.3 to 600. The numerical results are in good agreement with the experimental data when Reynolds is lower.
基金supported by the Second Stage of Brain Korea 21 Projects,Korea
文摘Numerical analysis was performed to investigate flow and heat transfer characteristics in spiral coiled tube heat exchanger. Radius of curvature of the spiral coiled tube was gradually increased as total rotating angle reached 12n. As the varying radius of curvature became a dominant flow parameter, three-dimensional flow analysis was performed to this flow together with different Reynolds numbers while constant wall heat flux condition was set in thermal field. From the analysis, centrifugal force due to curvature effect is found to have significant role in behavior of pressure drop and heat transfer. The centrifugal force enhances pressure drop and heat transfer to have generally higher values in the spiral coiled tube than those in the straight tube. Even then, friction factor and Nusselt number are found to follow the proportionality with square root of the Dean number. Individual effect of flow parameters of Reynolds number and curvature ratio was investigated and effect of Reynolds number is found to be stronger than that of curvature effect.
基金Supported by the National Natural Science Foundation of China (No. 21076117)Shandong Province Higher Educational Science and Technology Program (Nos. J09LC22 and J10LC15)+1 种基金the Knowledge Innovation Program of the Chinese Academy of Sciences (No. KZCX2-YW-209)the Open Fund of the Key Laboratory of Experimental Marine Biology, Institute of Oceanology, Chinese Academy of Sciences (No. Kf201016)
文摘The marine macroalgae Enteromorpha prolifera was one of the main algal genera that occurred in the widespread green tides in Qingdao, China, during the summers of 2007, 2008 and 2010. It is thus a plentiful source of biomass and could be used as a biofuel. In this study, the pyrolytic characteristics and kinetics of E. prolifera were investigated using thermogravimetric analysis (TGA) method. Cornstalk and sawdust were used as comparisons. Pyrolytic characteristics were studied using TG-DTG (thermogravimetry-derivative thermogravimetry) curves. Three stages in the pyrolytic process were determined: dehydration, dramatic weight loss and slow weight loss. E. prolifera was pyrolyzed at a lower initial temperature than the two terrestrial biomass forms. The apparent activation energy values for the three types of biomass were calculated and the mechanism functions were determined using 16 different mechanism functions, frequently used in thermal kinetics analysis. Activation energy values varied with mechanism function and the range of activation energy values for E. prolifera, cornstalk, and sawdust were 25-50 kJ/mol, 60-90 kJ/mol and 120-155 kJ/mol, respectively. This indicates that E. prolifera has low thermal stability for pyrolysis and good combustion characteristics.
基金Supported by the National Natural Science Foundation of China under Grant No.10765004
文摘A Brownian microscopic heat engine with a particle hopping on a one-dimensional lattice driven by adiscrete and periodic temperature field in a periodic sawtooth potential is investigated.In order to clarify the underlyingphysical pictures of the heat engine, the heat flow via the potential energy and the kinetic energy of the particles areconsidered simultaneously.Based on describing the jumps among the three states, the expressions of the efficiency andpower output of the heat engine are derived analytically.The general performance characteristic curves are plotted bynumerical calculation.It is found that the power output-efficiency curve is a loop-shaped one, which is similar to onefor a real irreversible heat engine.The influence of the ratio of the temperature of the hot and cold reservoirs and thesawtooth potential on the maximum efficiency and power output is analyzed for some given parameters.When the heatflows via the kinetic energy is neglected, the power output-efficiency curve is an open-shaped one, which is similar to onefor an endroeversible heat engine.
基金Chinese Universities Scientific fund and National Natural Science Foundation of China (40505008)
文摘Based on consideration of both thermodynamic and kinetic features of the subtropical summer monsoon in East Asia,a new index is defined by the moist potential vorticity (MPV) for this monsoon.Variation features of the subtropical summer monsoon over 60 years are analyzed using National Centers for Environmental Prediction/National Center for Atmospheric Research (USA) data from 1948 to 2007.Results show that the new index can well reflect the seasonal,interannual,and interdecadal variations of the East Asian subtropical summer monsoon.Correlation analysis of the new index and precipitation data from 160 stations in China shows that in high-index years,the summer monsoon is strong,and more rain falls in eastern North China,southwestern China,and along the coast of South China and less rain falls in the Yangtze-Huaihe R.basin.In low-index years,the opposite occurs.Lastly,the new index is compared with four established monsoon indices.The new index is found to have an advantage in representing summer rainfall in the Yangtze-Huaihe R.basin.
基金Supported by the King Mongkut's Institute of Technology Ladkrabang research fund,Thailand(KREF015611)
文摘A 3D numerical investigation has been carried out to examine periodic laminar flow and heat transfer characteristics in a circular tube with 45°V-baffles with isothermal wall.The computations are based on the finite volume method(FVM),and the SIMPLE algorithm has been implemented.The fluid flow and heat transfer characteristics are presented for Reynolds numbers ranging from 100 to 2000.To generate main longitudinal vortex flows through the tested section,V-baffles with an attack angle of 45°are mounted in tandem and in-line arrangement on the opposite positions of the circular tube.Effects of tube blockage ratio,flow direction on heat transfer and pressure drop in the tube are studied.It is apparent that a pair of longitudinal twisted vortices(P-vortex)created by a V-baffle can induce impingement on a wall of the inter-baffle cavity and lead a drastic increase in heat transfer rate at tube wall.In addition,the larger blockage ratio results in the higher Nusselt number and friction factor values.The computational results show that the optimum thermal enhancement factor is around 3.20 at baffle height of B=0.20 and B=0.25 times of the tube diameter for the V-upstream and V-downstream,respectively.
基金the financial support provided by the National Natural Science Foundation of China(Project No.51375491)the Natural Science Foundation of Chongqing(No.CSTC,2014 JCYAA 50021)
文摘The thermal decomposition characteristics of methyl oleate were preliminarily investigated under nitrogen atmo-sphere by a thermogravimetric analyzer when the ester was heated at a heating rate of 10℃/min from room temperature to 600℃. Furthermore, the pyrolytic and kinetic characteristics of methyl oleate were intensively studied at different heating rates. The gaseous species obtained during thermal decomposition were also identiifed by the TG-FTIR coupling analysis. The results showed that the pyrolysis of methyl oleate proceeded in three stages, viz. the drying stage, the main pyrolysis stage and the residual pyrolysis stage. The initial decomposition temperature, the maximum weight loss temperature, the peak decomposition temperature and the rate of maximum weight loss of methyl oleate increased with the increasing heating rates. Gaseous CO, CO2 and H2O were the typical decomposition products from pyrolysis of methyl oleate. In addition, a kinetic model for thermal decomposition of methyl oleate was built up based on the experimental results using the Coats-Redfern integral method and the multiplelinear regression method. The activation energy, the preexponential factor, the reaction order and the kinetic equation for thermal decomposition of methyl oleate were obtained. Comparison of the experimental data with the calculated ones and analysis of statistical errors of pyrolysis ratios demonstrated that the kinetic model was reliable for studying the pyrolysis of methyl oleate. Finally, the kinetic compensation effect between the preexponential factors and the activation energy in the pyrolysis of methyl oleate was also conifrmed.
基金Supported by the National High Technology Research and Development Programme of China (No. 2006AA11A192)
文摘As an important high-energy chemical power source, lithium-ion power batteries come up to application problems of thermal performance, such as extended temperature range and high power charge & discharge. LiFeP04 battery is applied and developed well recently, its charge and discharge experiment at different temperatures and hybrid pulse power characterization (HPPC) test are analyzed, and the optimal temperature range of LiFeP04 battery is put forward. In order to provide experimental suggestion of power battery application and its thermal management, internal resistance, influencing factor of electromotive force and entropy change state of charge (SOC), battery thermal characteristic of different charge & discharge rates are summarized.
基金Sponsored by the National Natural Science Foundation of China(Grant No.51008106)
文摘To obtain the pyrolysis characteristics and kinetics of preparation process of sludge-based activated carbon by ZnCl2 activation method (i.e.the pyrolysis process of the sludge with ZnCl2 activation),the characteristic of mass loss and gas products generated during pyrolysis of the sludge with ZnCl2 activation were analyzed by thermogravimetric analysis coupled with Fourier Transform Infrared Spectroscopy (TG-FTIR).The kinetic parameters were calculated by the Coats-Redfem method and the mechanism models were established.The role of ZnCl2 in the pyrolysis process of the sludge with ZnCl2 activation was also illustrated through the comparison of the pyrolysis characteristics and kinetics of the sludge with and without ZnCl2 activation.The results showed that the pyrolysis process of the sludge with ZnCl2 activation can be divided into four stages including the dehydration of sludge and initial depolymerization of a small portion of organics matters,the decomposition of large molecular organic matters into small molecular intermediates,the further degradation of intermediates and volatilization of ZnCl2,and the decomposition of inorganic minerals and undecomposed organic matters.CO2,CO,CH4,H2O,some aldehydes and carboxylic acids are the major pyrolysis gaseous products.The activation energies and pre-exponential factors are in the range of 28.84-206.42 kJ/mol and 9885.16-8.08× 1011 min-1,respectively.During the pyrolysis of sludge,ZnC12 not only can function as a dehydration agent and inhibit the formation of tar,but also can peptize the organic matters in the sludge,making them easier to be decomposed.