The purpose of this work was to study the potential to enhance biogas production from pulp and paper mill sludge by the use of thermal pre-treatment in combination with chemical pre-treatment. Biogas from waste is a r...The purpose of this work was to study the potential to enhance biogas production from pulp and paper mill sludge by the use of thermal pre-treatment in combination with chemical pre-treatment. Biogas from waste is a renewable fuel with very low emissions during combustion. To further reduce the use of fossil fuels, more biogas substrates are necessary. Pulp and paper mill sludge is a large untapped reservoir of potential biogas. Pulp and paper mill sludge was collected from a mill that produces both pulp and paper and has a modified waste activated sludge system as part of its wastewater treatment. Pre-treatments were chosen heat （70 ~C or 140℃） combined with either acid （pH 2 or pH 4） or base （pH 9 or pH 11, obtained with Ca（OH）2 or NaOH）. Biogas potential was tested by anaerobic digestion batch assays under mesophilic conditions. All pre-treatments were tested in six replicates. Biogas volume was measured with a gas-tight syringe and methane concentration was measured with a gas chromatograph. The methane yield from sludge subjected to thermal pre-treatment at 70℃ did not differ from the untreated sludge, but thermal pre-treatment at 140℃ had a positive effect. Within the 70℃ thermal pre-treatment group, the pH 2 acid was the most successful chemical pre-treatment, and Ca（OH）2 pH 9 had the least effect with no measurable improvement in methane yield. For the 140 ℃ thermal pre-treatment group, acid and NaOH impacted methane production negatively, while the Ca（OH）2-treated sludge did not differ from sludge with no chemical pre-treatment. In conclusion, thermal pre-treatment at 70℃ showed no effect, whereas, pre-treatment at 140℃ improved methane yield with 170%, and for this sludge additional, chemical pre-treatments are unnecessary.展开更多
In order to study the effects of chemical osmotic pretreatment on the characteristics and quality of blueberry under hot air drying,fresh blueberries were pretreated with 2.5 g/100 mL K2CO3+0.6 g/100 mL olive oil,and ...In order to study the effects of chemical osmotic pretreatment on the characteristics and quality of blueberry under hot air drying,fresh blueberries were pretreated with 2.5 g/100 mL K2CO3+0.6 g/100 mL olive oil,and 5.0 g/100 mL K2CO3+0.6 g/100 mL olive oil at(45±0.5)℃,respectively.The changes of water content,rehydration,hardness,microstructure,color difference,active ingredient anthocyanin,total phenol and DPPH radical scavenging capacity of dried blueberries in different treatment groups under hot air drying were compared and analyzed.The results showed that the dehydration rates of blueberries vary greatly according to the type of pretreatments when the samples were dried to the same water content with hot air.Specifically,the dehydration rate of dried blueberries pretreated by 5.0%K2CO3 solution was the highest,followed by 2.5%K2CO3 osmotic pretreatment and lastly the control group;the corresponding dehydration time was 10,14 and 20h,respectively.The physical qualities of dried blueberries,involving the browning degree,color difference,rehydration and microstructure,were significantly different between the chemical osmotic pretreatment group and the control group(P<0.05).The chemical osmotic pretreatment of K2CO3 solution increased the dehydration rate of the samples,shortened the drying time and maintained the quality of blueberries dried with hot air.There was no significant difference between the physical quality of dried blueberries pretreated by 2.5%and 5.0%K2CO3 solution(P>0.05),whereas there was significant difference in drying time and nutrient quality which is characterized by total phenols,anthocyanins,DPPH radical scavenging rate,soluble total sugar(P<0.05).Conclusion:5.0%K2CO3 osmotic pretreatment combining with hot air drying can improve the dehydration rate,shorten the drying time and maintain the physical and nutritional quality.展开更多
文摘The purpose of this work was to study the potential to enhance biogas production from pulp and paper mill sludge by the use of thermal pre-treatment in combination with chemical pre-treatment. Biogas from waste is a renewable fuel with very low emissions during combustion. To further reduce the use of fossil fuels, more biogas substrates are necessary. Pulp and paper mill sludge is a large untapped reservoir of potential biogas. Pulp and paper mill sludge was collected from a mill that produces both pulp and paper and has a modified waste activated sludge system as part of its wastewater treatment. Pre-treatments were chosen heat （70 ~C or 140℃） combined with either acid （pH 2 or pH 4） or base （pH 9 or pH 11, obtained with Ca（OH）2 or NaOH）. Biogas potential was tested by anaerobic digestion batch assays under mesophilic conditions. All pre-treatments were tested in six replicates. Biogas volume was measured with a gas-tight syringe and methane concentration was measured with a gas chromatograph. The methane yield from sludge subjected to thermal pre-treatment at 70℃ did not differ from the untreated sludge, but thermal pre-treatment at 140℃ had a positive effect. Within the 70℃ thermal pre-treatment group, the pH 2 acid was the most successful chemical pre-treatment, and Ca（OH）2 pH 9 had the least effect with no measurable improvement in methane yield. For the 140 ℃ thermal pre-treatment group, acid and NaOH impacted methane production negatively, while the Ca（OH）2-treated sludge did not differ from sludge with no chemical pre-treatment. In conclusion, thermal pre-treatment at 70℃ showed no effect, whereas, pre-treatment at 140℃ improved methane yield with 170%, and for this sludge additional, chemical pre-treatments are unnecessary.
基金Supported by Science and Technology Innovation Project in Hunan Academy of Agricultural Sciences(2017JC66)International Science and Technology Innovation Cooperation Base Construction Project in Hunan(2018WK4011)~~
文摘In order to study the effects of chemical osmotic pretreatment on the characteristics and quality of blueberry under hot air drying,fresh blueberries were pretreated with 2.5 g/100 mL K2CO3+0.6 g/100 mL olive oil,and 5.0 g/100 mL K2CO3+0.6 g/100 mL olive oil at(45±0.5)℃,respectively.The changes of water content,rehydration,hardness,microstructure,color difference,active ingredient anthocyanin,total phenol and DPPH radical scavenging capacity of dried blueberries in different treatment groups under hot air drying were compared and analyzed.The results showed that the dehydration rates of blueberries vary greatly according to the type of pretreatments when the samples were dried to the same water content with hot air.Specifically,the dehydration rate of dried blueberries pretreated by 5.0%K2CO3 solution was the highest,followed by 2.5%K2CO3 osmotic pretreatment and lastly the control group;the corresponding dehydration time was 10,14 and 20h,respectively.The physical qualities of dried blueberries,involving the browning degree,color difference,rehydration and microstructure,were significantly different between the chemical osmotic pretreatment group and the control group(P<0.05).The chemical osmotic pretreatment of K2CO3 solution increased the dehydration rate of the samples,shortened the drying time and maintained the quality of blueberries dried with hot air.There was no significant difference between the physical quality of dried blueberries pretreated by 2.5%and 5.0%K2CO3 solution(P>0.05),whereas there was significant difference in drying time and nutrient quality which is characterized by total phenols,anthocyanins,DPPH radical scavenging rate,soluble total sugar(P<0.05).Conclusion:5.0%K2CO3 osmotic pretreatment combining with hot air drying can improve the dehydration rate,shorten the drying time and maintain the physical and nutritional quality.
