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聚合物的热压力系数及内压 被引量:2
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作者 刘国杰 虞大红 《化学学报》 SCIE CAS CSCD 北大核心 1996年第2期113-118,共6页
本文将我们在前文中提出的修正van der Waals模型,推广到了液态聚合物中,从而建立了一个能在宽阔温度范围内准确计算聚合物热压力系数的关系式γ=RMv/(Mv)~2-AMv+0.2535A^2式中v和M分别为聚合物的比体积和链节的摩尔质量,A为聚合物的特... 本文将我们在前文中提出的修正van der Waals模型,推广到了液态聚合物中,从而建立了一个能在宽阔温度范围内准确计算聚合物热压力系数的关系式γ=RMv/(Mv)~2-AMv+0.2535A^2式中v和M分别为聚合物的比体积和链节的摩尔质量,A为聚合物的特性常数.对于本文考察的五种聚合物,发现它们的链节大小均为聚合物的三个结构单元. 展开更多
关键词 聚合物 热压力系数 内压 范德华模型
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醇类的缔合与热压力系数测定
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作者 胡宇军 张锐 +1 位作者 黑恩成 刘国杰 《化学世界》 CAS CSCD 1996年第S1期75-77,共3页
醇类的缔合与热压力系数测定胡宇军,张锐,黑恩成,刘国杰(华东理工大学化学系上海200237)醇类是一种强缔合物质,由于氢键的缔合作用,使它们的许多性质与一般流体不同。因此搞清缔合作用,不仅在理论上,而且在工程应用上都... 醇类的缔合与热压力系数测定胡宇军,张锐,黑恩成,刘国杰(华东理工大学化学系上海200237)醇类是一种强缔合物质,由于氢键的缔合作用,使它们的许多性质与一般流体不同。因此搞清缔合作用,不仅在理论上,而且在工程应用上都具有重要意义。目前研究缔合的主要手... 展开更多
关键词 热压力系数 环己烷混合物 自缔合 刘国杰 乙醇 缔合作用 排斥体积 二元液体混合物 力学关系式 华东理工大学
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醇类液体的热压力系数及内压 被引量:4
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作者 李继敏 朱良 +2 位作者 史济斌 黑恩成 刘国杰 《化学学报》 SCIE CAS CSCD 北大核心 1995年第1期1-8,共8页
本文测定25~85℃温度范围内正戊醇、正己醇、正庚醇和正辛醇的热压力系数,发现这些醇类液体的内压几乎不随温度而变.本文还将修正的van der Waals模型推广到了醇类液体,与非缔合液体一样,它们的排斥体积亦与密度呈线性关系.但是,模型... 本文测定25~85℃温度范围内正戊醇、正己醇、正庚醇和正辛醇的热压力系数,发现这些醇类液体的内压几乎不随温度而变.本文还将修正的van der Waals模型推广到了醇类液体,与非缔合液体一样,它们的排斥体积亦与密度呈线性关系.但是,模型参数之比B/A^2不再是个常数,而是随醇分子中碳原子数的增多而快速地减小,这个比值可作为自缔合能力的一种量度. 展开更多
关键词 缔合液体 内压 范德华模型 热压力系数
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聚二甲基硅氧烷的热压力系数与聚合度 被引量:2
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作者 杜唯 虞大红 刘国杰 《高校化学工程学报》 EI CAS CSCD 1995年第4期358-363,共6页
本文测定了在20~100℃温度范围内,四个不同聚合度的聚二甲基硅氧烷的热压力系数和密度。建立了一个能够计算各种聚合度的PDMS热压力系数的公式,并据此得到了它们的恒温压缩系数、内压等重要物理性质。PDMS的这些性质对... 本文测定了在20~100℃温度范围内,四个不同聚合度的聚二甲基硅氧烷的热压力系数和密度。建立了一个能够计算各种聚合度的PDMS热压力系数的公式,并据此得到了它们的恒温压缩系数、内压等重要物理性质。PDMS的这些性质对聚合度都不太敏感。 展开更多
关键词 聚二甲基硅氧烷 聚合度 热压力系数
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简化刚体状态方程及其应用 Ⅱ.液体热压力系数和内压的预测
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作者 陈孝国 朱自强 《宁波大学学报(理工版)》 CAS 1991年第2期22-30,共9页
应用前文提出的刚体状态方程,结合所给出的假设,预测了20℃时60多种液体和不同温度下11种液体的热压力系数和内压。预测结果和文献中的实验值符合良好。又从另一侧面验证了所提出的刚体状态方程确能较好地代表实际流体分子的斥力项,为... 应用前文提出的刚体状态方程,结合所给出的假设,预测了20℃时60多种液体和不同温度下11种液体的热压力系数和内压。预测结果和文献中的实验值符合良好。又从另一侧面验证了所提出的刚体状态方程确能较好地代表实际流体分子的斥力项,为开发较好的立方型方程提供了参考。 展开更多
关键词 状态方程 液体 热压力系数 内压
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乙醇和环己烷混合物的某些热力学性质
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作者 张锐 胡宇军 +1 位作者 黑恩成 刘国杰 《华东理工大学学报(自然科学版)》 CAS CSCD 北大核心 1998年第2期216-220,共5页
测定了乙醇/环己烷混合物在25~65℃的热压力系数,并利用文献提供的过量体积和恒压热容数据得到了这个系统在25、35和45℃时的热膨胀系数、恒温和绝热压缩系数、恒容热容、内压、声速和Grüneisen参数等热力学... 测定了乙醇/环己烷混合物在25~65℃的热压力系数,并利用文献提供的过量体积和恒压热容数据得到了这个系统在25、35和45℃时的热膨胀系数、恒温和绝热压缩系数、恒容热容、内压、声速和Grüneisen参数等热力学性质。 展开更多
关键词 乙醇 环乙烷 混合物 热压力系数 力学性质
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液体内压模型评价 被引量:5
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作者 徐云蕾 黑恩成 +1 位作者 沈晓燕 刘国杰 《华东理工大学学报(自然科学版)》 CAS CSCD 北大核心 1998年第5期574-579,共6页
用10种有代表性液体的内压值对4个内压模型进行了评价。评价结果表明,对应状态模型和修正的vanderWaals模型明显优于自由体积模型和硬球模型。
关键词 液体 热压力系数 内压 模型 评价 溶液
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聚合物内压测定及对应状态模型 被引量:1
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作者 徐云蕾 黑恩成 刘国杰 《化学学报》 SCIE CAS CSCD 北大核心 2000年第3期303-307,共5页
实验测定了PEG((?)_n=200),PEG((?)_n=300),PEG((?)_n=400),PEG((?)_w=15000)和PDMS((?)_w=20000)在20~90℃温度范围的热压力系数和密度,它们的热压力系数和内压几乎与分子量无关.据此还建立了一个聚合物内压的对应状态模型,它只含一... 实验测定了PEG((?)_n=200),PEG((?)_n=300),PEG((?)_n=400),PEG((?)_w=15000)和PDMS((?)_w=20000)在20~90℃温度范围的热压力系数和密度,它们的热压力系数和内压几乎与分子量无关.据此还建立了一个聚合物内压的对应状态模型,它只含一个可调参数,能满意地适用于各种聚合物. 展开更多
关键词 聚合物 内压 热压力系数 PEG PDMS 内压模型
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推广的van der Waals压缩因子及其对超临界流体的应用 被引量:1
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作者 窦晓冬 刘国杰 《高校化学工程学报》 EI CAS CSCD 北大核心 2001年第6期511-515,共5页
利用实验测得的液体的热压力系数,修正原始van der Waals模型中的排斥体积,得到了一个适用于高密度流体的推广的van der Waals压缩因子。将它与Redlich和Kwong提出的吸引项相结合,建立了一个流体状态方程。用某些有代表性的超临界流体的... 利用实验测得的液体的热压力系数,修正原始van der Waals模型中的排斥体积,得到了一个适用于高密度流体的推广的van der Waals压缩因子。将它与Redlich和Kwong提出的吸引项相结合,建立了一个流体状态方程。用某些有代表性的超临界流体的pVT数据检验,结果表明,其对体积、压力和逸度系数的计算准确度可与CS-RK方程相媲美。 展开更多
关键词 热压力系数 压缩因子 流体状态方程 超临界流体 vanderWaals方程
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液体混合物的推广Vander Waals理论
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作者 刘国杰 赵隽扬 胡英 《化学学报》 SCIE CAS 1988年第10期952-960,共9页
本文通过对Van der Waals模型中排斥体积的修正,建立了一个液体状态方程式,并将它推广到了二元液体混合物,预测和关联了液体混合物的过量性质.计算结果表明,可与Flory理论相比拟,但所需提供的纯组分性质比Flory理论少,计算也得到了简化.
关键词 液体混合物 计算值 Vander Waals 热压力系数 过量性质 液体状态方程
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液态聚合物的内压与状态方程 被引量:5
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作者 肖国军 史济斌 刘国杰 《化工学报》 EI CAS CSCD 北大核心 2004年第4期526-530,共5页
由热力学关系建立了一个液态聚合物的状态方程 .聚合物的热压力由对应状态原理得到 ,内压力由Lennard Jones (6 ,12 )势能函数导得 .状态方程包含 3个有明确物理意义的特性参数 ,能够满意地关联各种液态聚合物的pVT数据 .对 18个均聚物... 由热力学关系建立了一个液态聚合物的状态方程 .聚合物的热压力由对应状态原理得到 ,内压力由Lennard Jones (6 ,12 )势能函数导得 .状态方程包含 3个有明确物理意义的特性参数 ,能够满意地关联各种液态聚合物的pVT数据 .对 18个均聚物和 4个共聚物的比体积关联结果表明 ,总的平均绝对偏差在 0~ 5 0MPa压力范围内为 0 0 0 0 4 2cm3 ·g-1,在全部实验压力范围内为 0 0 0 0 6 3cm3 ·g-1,优于Simha Somcynsky方程算得的结果 . 展开更多
关键词 液态聚合物 状态方程 热压力系数 压力
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NUMERICAL PREDICTION OF AIRCRAFT HYDRAULIC SYSTEM BASED ON THERMAL DYNAMIC ANALYSIS
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作者 苏向辉 许锋 昂海松 《Transactions of Nanjing University of Aeronautics and Astronautics》 EI 2003年第2期159-164,共6页
A mathematical model of principal elements of the aircraft hydraulic system is presented based on the heat transfer theory. The dynamic heat transfer process of the hydraulic oil and the pump shells within an aircraft... A mathematical model of principal elements of the aircraft hydraulic system is presented based on the heat transfer theory. The dynamic heat transfer process of the hydraulic oil and the pump shells within an aircraft hydraulic system are analyzed by the difference method. A kind of means for the prediction to variational trends of the aircraft hydraulic system temperature is provided during operation. The numerical prediction and simulation under the operational conditions are presented for ground trial running and the decelerated operation in flight. Computational results show that there is a good coincidence between the experimental data and the numerical predictions. 展开更多
关键词 hydraulic system head loss thermal dynamic analysis numerical prediction
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Thermal performance of tubular heat exchanger with multiple twisted-tape inserts 被引量:9
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作者 Suriya Chokphoemphun Monsak Pimsarn +1 位作者 Chinaruk Thianpong Pongjet Promvonge 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2015年第5期755-762,共8页
The paper presents an experimental investigation on enhanced heat transfer and pressure loss characteristics by using single, double, triple, and quadruple twisted-tape inserts in a round tube having a uniform heat-fl... The paper presents an experimental investigation on enhanced heat transfer and pressure loss characteristics by using single, double, triple, and quadruple twisted-tape inserts in a round tube having a uniform heat-fluxed wall. The investigation has been conducted in the heat exchanger tube inserted with various twisted-tape numbers for co- and counter-twist arrangements for the turbulent air flow, Reynolds number (Re) from 5300 to 24000. The typical single twisted-tape inserts at two twist ratios, y/w = 4 and 5, are used as the base case, while the other multiple twisted-tape inserts are aty/w = 4 only. The experimental results of heat transfer and pressure drop in terms of Nusselt number (Nu) and friction factor 00, respectively, reveal that Nu increases with the increment of Re and of twisted-tape number. The values of Nu for the inserted tube are in a range of 1.15-2.12 times that for the plain tube while f is 1.9-4.1 times. The thermal enhancement factor of the inserted tube under similar pumping power is evaluated and found to be above unity except for the single and the double co-twisted tapes. The quadruple counter-twisted tape insert provides the maximum thermal performance. 展开更多
关键词 Thermal performance Twisted tape arrangement Turbulator Nusselt number Friction factor
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Pool Boiling Heat Transfer in Dilute Water/Triethyleneglycol Solutions 被引量:1
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作者 S. A. Alavi Fazel A.A. Safekordi M. Jamialahmadi 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2009年第4期552-561,共10页
Boiling of water/triethyleneglycol(TEG)binary solution has a wide-ranging application in the gas processing engineering.Design,operation and optimization of the involved boilers require accurate prediction of boiling ... Boiling of water/triethyleneglycol(TEG)binary solution has a wide-ranging application in the gas processing engineering.Design,operation and optimization of the involved boilers require accurate prediction of boiling heat transfer coefficient between surface and solution.In this investigation,nucleate pool boiling heat transfer coefficient has been experimentally measured on a horizontal rod heater in water/TEG binary solutions in a wide range of concentrations and heat fluxes under ambient condition.The present experimental data are correlated using major existing correlations.In addition a correlation is presented for prediction of pool boiling heat transfer for the system in which the vapour pressure of one component is negligible.This model is based on the mass transfer rate equation for prediction of the concentration at the bubble vapor/liquid interface.Based on this prediction,the temperature of the interface and accordingly,the boiling heat transfer coefficient could be straightforwardly calculated from the known concentration at the interface.It is shown that this simple model has sufficient accuracy and is acceptable below the medium concentrations of TEG when the vapor equilibrium concentration of TEG is almost zero.The presented model excludes any tuning parameter and requires very few physical properties to apply. 展开更多
关键词 pool boiling heat transfer coefficient water/triethyleneglycol
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Experimental investigation of thermal performance characteristics of sintered copper wicked and grooved heat pipes:A comparative study
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作者 Saif Ullah KHALID Hafiz Muhammad ALI +4 位作者 Muhammad Ali NASIR Riffat Asim PASHA ZAFAR SAID L.Syam SUNDAR Ahmed Kadhim HUSSEIN 《Journal of Central South University》 SCIE EI CAS CSCD 2021年第11期3507-3520,共14页
Heat pipes are most frequently used for thermal management solutions.Selection of right type of heat pipe for a specific scenario is utmost necessary for best outcomes.The purpose of this research is comparison of the... Heat pipes are most frequently used for thermal management solutions.Selection of right type of heat pipe for a specific scenario is utmost necessary for best outcomes.The purpose of this research is comparison of thermal performance characteristics of sintered copper wicked and grooved heat pipes,which are mostly used types of heat pipes.Distilled water filled heat pipes were tested through experimentation in gravity assisted position.Experimental outcomes have been compiled in terms of capillary pressure,operating temperature,thermal resistance and heat transfer coefficient.Capillary pressure is high in sintered heat pipes compared to grooved heat pipes irrespective of groove dimensions.Grooved heat pipes have lower operating temperature compared to sintered heat pipes at the same heat load.At 8 W,compared to sintered heat pipes,grooved heat pipes have 8.24% lower condenser surface temperature,4.41% lower evaporator surface temperature and 7.79% lower saturation temperature.Thermal resistance of sintered heat pipe is much lower than grooved heat pipe.The maximum relative difference of 63.8% was observed at 8 W.Heat transfer coefficient of sintered heat pipe was observed double compared to grooved heat pipe at 8 W heat load.Thermal resistance and hence heat transfer coefficient of sintered heat pipe change almost in a linear manner with respect to heat load but unexpectedly turning point is observed in thermal resistance and heat transfer coefficient of grooved heat pipe.Grooved heat pipes attain equilibrium much earlier compared to sintered ones.Varying heat loads from 4 to 20 W causes variation in equilibrium establishment time from 7 to 4 min for grooved and from 10 to 7 min for sintered heat pipes. 展开更多
关键词 heat pipe thermal resistance heat transfer coefficient thermal performance capillary pressure
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Radial heat transport in packed beds-I: Experimental investigation of heat transfer coefficients of pellets and monolith catalysts at atmospheric and high pressures
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作者 Mohamed A. Al-Meshragi Hadi A. Elakrami Hesham G. Ibrahim 《Journal of Chemistry and Chemical Engineering》 2009年第6期1-14,共14页
The effect of operating pressure on the radial heat transfer coefficients, in a non-adiabatic fixed packed bed was studied at atmospheric and higher pressures, The study was concerned with investigating the effect of ... The effect of operating pressure on the radial heat transfer coefficients, in a non-adiabatic fixed packed bed was studied at atmospheric and higher pressures, The study was concerned with investigating the effect of the pressure on the radial thermal conductivity (K^r) and wall heat transfer coefficient (h~) for both pellets and monolith catalysts. The study included beds that were packed with pellets and monoliths, separately. The radial temperature distribution was measured at different beds heights and feed flow rates for both types of packing. Steady-state temperatures were measured using nine chromel-alumel thermocouples arranged on a stainless steel-cross. After temperatures were collected, the radial thermal conductivity and wall heat transfer coefficient were calculated using a two-dimensional pseudo-homogeneous model. The results showed that, the radial temperature profile at the entrance of the heating section was nearly even, and a constant temperature along the radius (0F/0r=0) taken as a boundary condition to solve the partial differential equation controlling the heat transfer. Temperature profiles obtained at elevated pressures were smoother at the center of the reactor and increased sharply near the wall, than profiles at atmospheric pressure. It could also be observed, that the radial temperature profiles in the center of the reactor using a monolith catalyst at elevated pressure were more even and smoother than those of pellets. Temperature profiles in fixed beds were found to be very sensitive to Ker and hw. In pressures between atmospheric and 10 bars, there was no change in the effective heat transport parameters (i.e. they are independent of pressure in this range). Both parameters were strongly affected by the pressure changes, above 10 bars. For the same Reynolds number (Ker) increased by 27% and 53% at 11 and 20 bars, respectively, in pellets catalyst. And they increased by factors of 2.3 and 4, when the pressure increased to the same pressures, in monolith catalyst. On the other hand, the effect of pressure on (hw) was completely the opposite, h,~ for pellets and monolith catalysts were found to be decreasing with increasing the pressure. Moreover, both coefficients increased with the Reynolds number at all applied pressures. This increase was higher for pellets than it for monoliths. 展开更多
关键词 heat transfer packed beds pseudo-homogeneous model pressure effect
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Temperature in High Temperature SHPB Experiments
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作者 邓志方 谢若泽 +2 位作者 颜怡霞 李思忠 黄西成 《Transactions of Tianjin University》 EI CAS 2008年第B10期536-539,共4页
As an experimental technique, it’s desired that the temperature in specimen is uniform in high temperature split Hopkinson pressure bar (SHPB) experiments. However, the temperature in specimen decreases and the tempe... As an experimental technique, it’s desired that the temperature in specimen is uniform in high temperature split Hopkinson pressure bar (SHPB) experiments. However, the temperature in specimen decreases and the temperature of bars increases when specimen starts to contact with bars, which induces the nonuniform temperature distribution in specimen, and may result in inac-curacy of experimental results. In this paper, the temperature distributions of specimen and bars in high temperature SHPB experiments were investigated while the specimen was heated alone. Firstly, the temperature history of specimen was measured at different initial temperatures by ex-periments, then simulation was carried out. Simulation results were consistent with experimental results by adjusting the thermal contact coefficient between specimen and bars. By this way, the thermal contact coefficient and simulation results were validated, and the proper cold contact times of specimen and bars in high temperature SHPB experiments were discussed. Finally, the results were compared with those in references. 展开更多
关键词 high temperature SHPB experiment heat transfer thermal contact coefficient cold contact time
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碳纳米管/聚乙烯复合物分子动力学模拟研究 被引量:13
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作者 孙伟峰 高俊国 郭宁 《复合材料学报》 EI CAS CSCD 北大核心 2014年第2期286-294,共9页
采用分子动力学方法模拟了碳纳米管/聚乙烯复合物的结构、热力学和力学特性,分析其随模拟温度和碳纳米管填充率的变化。模拟结果表明,碳纳米管/聚乙烯复合物为各向同性的无定形结构,聚乙烯和碳纳米管通过较强的范德华作用结合在一起,在... 采用分子动力学方法模拟了碳纳米管/聚乙烯复合物的结构、热力学和力学特性,分析其随模拟温度和碳纳米管填充率的变化。模拟结果表明,碳纳米管/聚乙烯复合物为各向同性的无定形结构,聚乙烯和碳纳米管通过较强的范德华作用结合在一起,在聚乙烯基体作用下,碳纳米管壁上的碳原子排列的周期性下降,出现弯曲和褶皱。从能量上看,填充率较高的复合物更加稳定。碳纳米管/聚乙烯复合物具有比聚乙烯体系更高的等容热容和与聚乙烯体系相反的负值热压力系数,热容随碳纳米管填充率的变化较小,但随温度的升高而明显减小,具有显著的温度效应;热压力系数随温度的变化较小,温度稳定性比聚乙烯更好,但随填充率增加而减小。碳纳米管/聚乙烯复合物的力学特性表现出各向同性材料的弹性常数张量,弹性模量和泊松比比纯聚乙烯体系高得多,并且都随温度的升高和碳纳米管含量的降低而减小,说明加入碳纳米管可显著改善聚乙烯的力学性质。 展开更多
关键词 分子动力学模拟 聚合物纳米复合物 聚乙烯 碳纳米管 热压力系数
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Interaction between Struts and Swirl Flow in Gas Turbine Exhaust Diffusers 被引量:2
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作者 Roman Z.PIETRASCH Joerg R.SEUME 《Journal of Thermal Science》 SCIE EI CAS CSCD 2005年第4期314-320,共7页
The increasing use of gas turbines in combined cycle power plants together with the high amount of kinetic energy in modem gas turbine exhaust flows focuses attention on the design of gas turbine diffusers as the conn... The increasing use of gas turbines in combined cycle power plants together with the high amount of kinetic energy in modem gas turbine exhaust flows focuses attention on the design of gas turbine diffusers as the connecting part between the Brayton/Joule and the Rankine parts of the combined cycle. A scale model of a typical gas turbine exhaust diffuser is investigated experimentally. The test rig consists of a radial type, variable swirl generator which provides the exhaust flow corresponding to different gas turbine operating conditions. Static pressure measurements are carried out along the outer diffuser walls and along the hub of the annular part and along the centerline of the conical diffuser. Velocity distributions at several axial positions in the annular and conical diffuser have been measured using a Laser Doppler Velocimeter (LDV). Pressure recovery coefficients and velocity profiles are depicted as a function of diffuser length for several combinations of swirl strength, tip flow and strut geometries. The diffuser without struts achieved a higher pressure recovery than the diffuser with struts at all swirl angle settings. The diffuser with cylindrical struts achieved a higher pressure recovery than the diffuser with profiled struts at all swirl angle seO.ings. Inlet flows with swirl angles over 18° affected the pressure recovery negatively for all strut configurations. 展开更多
关键词 gas turbine exhaust diffuser SWIRL STRUTS pressure recovery coefficient.
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Controlling Thermal Conductivity of Few-Layer Graphene Nanoribbons by Using the Transversal Pressure
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作者 钟伟荣 杨明明 +1 位作者 张茂平 艾保全 《Communications in Theoretical Physics》 SCIE CAS CSCD 2013年第9期353-356,共4页
We study the thermal transport of few-layer graphene nanoribbons in the presence of the transversal pressure by using molecular dynamics simulations. It is reported that the pressure can improve the thermal conductivi... We study the thermal transport of few-layer graphene nanoribbons in the presence of the transversal pressure by using molecular dynamics simulations. It is reported that the pressure can improve the thermal conductivity of few-layer graphene nanoribbons. This improvement can reach 37.5% in the low temperature region. The pressure dependence of thermal conductivity is also investigated for different length, width and thickness of few-layer graphene. Our results provide an alternative option to tuning thermal conductivity of few-layer graphene nanoribbons, b-arthermore, it maybe indicate a so-called pressure-thermM effect in nanomaterials. 展开更多
关键词 thermal conductivity GRAPHENE molecular dynamics simulation PRESSURE
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