Sol-Gel法合成NaBiO_3多晶粉末

本文以醇盐为前驱体,以相应醇盐的母体醇为介质合成铋酸钠多晶粉末,考察了不同前驱体对产物的影响。探讨了三价铋的还原性能和铋酸钠的形态。

Grain refinement in AZ31 magnesium alloy rod fabricated by extrusion-shearing severe plastic deformation process

A new severe plastic deformation （SPD） method that is extrusion-shearing （ES）, which includes initial forward extrusion and shearing process subsequently, was developed to fabricate the fine grained AZ31 Mg alloys. The components of ES die were manufactured and installed to gleeble1500D thermo-mechanical simulator. Microstructure observations were carried out in different positions of ES formed rods. The results show that homogeneous microstructures with mean grain size of 2 μm are obtained at lower temperature as the accumulated true strain is 2.44. Occurring of continuous dynamic recrystallization （DRX） is the main reason for grain refinement during ES process. The experimental results show that the ES process effectively refines the grains of AZ31 magnesium. The production results of ES extrusion with industrial extruder under different extrusion conditions show that the ES extrusion can be applied in large-scale industry.

Hot pressing densification of WC-Mo_xC binderless carbide

WC-6MoxC-0.47Cr3C2-0.28VC binderless carbide was prepared by hot pressing （1700 °C, 20 MPa）. The sample was observed and analyzed by scanning electron microscopy, energy dispersive X–ray spectroscopy and X–ray diffraction. The results show that during the hot pressing process, W atoms dissolve substantially into the MoxC crystal lattices; whilst, the reverse dissolution of Mo atoms into the WC crystal lattices takes place. Consequently, the main phase and binder phase structure are formed. The phase compositions of the main phase and binder phase are a WC-based solid solution containing Mo and a Mo2C-based solid solution containing W, respectively. The isotropic dissolution and precipitation of W and Mo atoms do not result in substantial carbide coarsening. The mechanism for the densification was discussed.

Effects of hot compression on carbide precipitation behavior of Ni-20Cr-18W-1Mo superalloy

The effect of hot compression on the grain boundary segregation and precipitation behavior of M6C carbide in theNi-20Cr-18W-1Mo superalloy was investigated by thermomechanical simulator, scanning electronic microscope （SEM） and X-raydiffraction （XRD）. Results indicate that the amount of M6C carbides obviously increases in the experimental alloy after hotcompression. Composition analyses reveal that secondary M6C carbides at grain boundaries are highly enriched in tungsten.Meanwhile, the secondary carbide size of compressive samples is 3？5 μm in 10% deformation degree, while the carbide size ofundeformed specimens is less than 1 μm under aging treatment at 900 and 1000 ℃. According to the thermodynamic calculationresults, the Gibbs free energy of γ-matrix and carbides decreases with increase of the compression temperature, and the W-rich M6Ccarbide is more stable than Cr-rich M23C6. Compared with the experimental results, it is found that compressive stress accelerates theW segregation rate in grain boundary region, and further rises the rapid growth of W-rich M6C as compared with the undeformedone.

Optimization of deformation parameters of dynamic recrystallization for 7055 aluminum alloy by cellular automaton

In order to simulate the microstructure evolution during hot compressive deformation,models of dynamic recrystallization(DRX)by cellular automaton(CA)method for7055aluminum alloy were established.The hot compression tests were conducted toobtain material constants,and models of dislocation density,nucleation rate and recrystallized grain growth were fitted by leastsquare method.The effects of strain,strain rate,deformation temperature and initial grain size on microstructure variation werestudied.The results show that the DRX plays a vital role in grain refinement in hot deformation.Large strain,high temperature andsmall strain rate are beneficial to grain refinement.The stable size of recrystallized grain is not concerned with initial grain size,butdepends on strain rate and temperature.Kinetic characteristic of DRX process was analyzed.By comparison of simulated andexperimental flow stress–strain curves and metallographs,it is found that the established CA models can accurately predict themicrostructure evolution of7055aluminum alloy during hot compressive deformation.

Microstructure and mechanical properties of fine grained uranium prepared by ECAP and subsequent intermediate heat treatment

The microstructure and mechanical properties of fine grained uranium prepared by equal channel angular pressing(ECAP)and subsequent intermediate heat treatment were investigated systematically by the confocal laser scanning microscope(CLSM),electron backscatter diffraction(EBSD)and split Hopkinson pressure bar(SHPB).The results show that the initial coarse grained uranium was refined from about 1000 to 6.5μm prepared by ECAP at 3 passes and subsequent heat treatment,and the corresponding dynamic yield strength increased from 135 to 390 MPa.For the ECAPed uranium samples,the relationship between grain size and yield strength could be described by classical Hall−Petch relationship,and the fitting Hall−Petch relationship for the fine grained uranium samples prepared by ECAP was drawn.

Dynamic recrystallization and silicide precipitation behavior of titanium matrix composites under different strains

In order to elucidate the microstructure evolution and silicide precipitation behavior during high-temperature deformation,TiB reinforced titanium matrix composites were subjected to isothermal hot compression at 950℃,strain rate of 0.05 s^(−1) and employing different strains of 0.04,0.40,0.70 and 1.00.The results show that with the increase of strain,a decrease in the content,dynamic recrystallization of theαphase and the vertical distribution of TiB along the compression axis lead to stress stability.Meantime,continuous dynamic recrystallization reduces the orientation difference of the primaryαphase,which weakens the texture strength of the matrix.The recrystallization mechanisms are strain-induced grain boundary migration and particle stimulated nucleation by TiB.The silicide of Ti_(6)Si_(3) is mainly distributed at the interface of TiB andαphase.The precipitation of silicide is affected by element diffusion,and TiB whisker accelerates the precipitation behavior of silicide by hindering the movement of dislocations and providing nucleation particles.

Hot deformation behavior of AZ91 magnesium alloy in temperature ranging from 350℃ to 425℃

The flow behavior and microstructure evolution of AZ91 magnesium alloy during a thermomechanical process, hot compression test, was investigated. The specimens were hot compressed at a temperature ranging from 350 ℃ to 425 ℃ and at strain rate of 0.1 s-1 to the strains of 0.3, 0.5 and peak. Microstructural evolutions were studied using optical and scanning electron microscopes. The results show that during the compression process, the recrystallized grains nucleate along the pre-existing grain boundaries. The amount of dynamically recrystallized grains is increased with strain in a sigmoid scheme followed by Avrami equation. The size of dynamically recrystallized grains also increases at the beginning and decreases after reaching the maximum value.