The influence of R/v ratio on joint quality in 2024-T351 aluminum alloy was studied. Specimens were subjected to friction stir welding with the rotation rates of 750, 950 and 1180 r/min and welding speed between 73 an...The influence of R/v ratio on joint quality in 2024-T351 aluminum alloy was studied. Specimens were subjected to friction stir welding with the rotation rates of 750, 950 and 1180 r/min and welding speed between 73 and 190 mm/min, providing R/v ratio between 5.00 and 10.27. The welded joints were tested by means of both non-destructive (visual, penetrant and X-ray inspection) and destructive (metallographic, tension and hardness) testing. In all specimens typical zones are revealed, with corresponding differences in grain size. Tensile efficiency of the joints obtained is in the range of 52.2%to 82.3%. The results show that the best quality is obtained at R/v ratio of 8.06, 10.17 and 10.27. This behavior is attributed to the assumption that the material flows around the pin with an optimal speed, i.e. sufficient amount of material is available to fill the gap and prevent tunnel formation. R/v ratio also showed influence on hardness distribution, onion features and crack initiation/propagation zones.展开更多
We do a new Li-ion battery evaluation research on the effects of cell resistance and polariza- tion on the energy loss in batteries based on thermal property and heat generation behavior of battery. Series of 18650 ce...We do a new Li-ion battery evaluation research on the effects of cell resistance and polariza- tion on the energy loss in batteries based on thermal property and heat generation behavior of battery. Series of 18650 cells with different capacities and electrode materials are evalu- ated by measuring input and output energy which change with charge-discharge time and current. Based on the results of these tests, we build a model of energy loss in cells' charge- discharge process, which include Joule heat and polarization heat impact factors. It was reported that Joule heat was caused by cell resistance, which included De-resistance and reaction resistance, and reaction resistance could not be easily obtained through routine test method. Using this new method, we can get the total resistance R and the polarization parameter U. The relationship between R, η, and temperature is also investigated in order to build a general model for series of different Li-ion batteries, and the research can be used in the performance evaluation, state of charge prediction and the measuring of consistency of the batteries.展开更多
Pure WC-6%Co nanosized composite powders were synthesized via a low-temperature method.The effects of carbon source on microstructure characteristic of composite powders were investigated,and the effects of heat-treat...Pure WC-6%Co nanosized composite powders were synthesized via a low-temperature method.The effects of carbon source on microstructure characteristic of composite powders were investigated,and the effects of heat-treatment parameter on carbon content of composite powders were also discussed.The results of SEM and XRD revealed that the carbon decomposing from glucose was more active than carbon black.Therefore,WC-Co nanosized composite powders could be synthesized at 900°C for 1 h under a hydrogen atmosphere.The individual WC grains were bonded together into a long strip under the action of cobalt.The results of carbon analysis revealed that the total carbon content decreased with the increase of the temperature in the range of 800-1000°C.Moreover,the total carbon content and the compounded carbon increased with the increase of the flow rate of H2 in the range of 1.1-1.9 m3/h.展开更多
Compared to potential temperature (θ) in the dry atmosphere and equivalent potential temperature (θc) in the saturated atmosphere, generalized potential tem- perature (θ") has already proven a better thermod...Compared to potential temperature (θ) in the dry atmosphere and equivalent potential temperature (θc) in the saturated atmosphere, generalized potential tem- perature (θ") has already proven a better thermodynamic parameter in describing the non-uniformly saturated real atmosphere. To add otherwise absent graphic explanations, this paper first presents the physical definition of θ through a tephigram. Then, the utility of the measurement in identifying and forecasting the locations of precipita- tion maxima and heat wave areas with diagnostic com- parison studies and traditionally used thermodynamic parameters is shown.展开更多
AA5083 friction stir welds were produced using systematic experimental design, the process forces and heat input with varying parameters were studied. Helpful empirical models were developed in designing friction stir...AA5083 friction stir welds were produced using systematic experimental design, the process forces and heat input with varying parameters were studied. Helpful empirical models were developed in designing friction stir welding (FSW) tools and FSW welders. These models may be further helpful for making process parameter choice for this sort of alloy, defining welding program and control of process parameters by using computer numerical control friction stir welding welders. The results show that tool rotational speed, welding speed and tool shoulder diameter are most significant parameters affecting axial force and heat input, while longitudinal force is significantly affected by welding speed and probe diameter.展开更多
Laser transformation hardening(LTH)of unalloyed titanium of 1.6 mm-thick sheet,nearer to ASTM Grade 3 of chemical composition was investigated using 2 kW CW Nd:YAG laser.The effects of laser power(750-1 250 W),scannin...Laser transformation hardening(LTH)of unalloyed titanium of 1.6 mm-thick sheet,nearer to ASTM Grade 3 of chemical composition was investigated using 2 kW CW Nd:YAG laser.The effects of laser power(750-1 250 W),scanning speed(1 000-3 000 mm/min)and focal point position(from-10 to-30 mm)on the heat input,and hardened-bead geometry(i.e.hardened bead width(HBW),hardened depth(HD)and angle of entry of hardened bead profile with the surface(AEHB))were investigated using response surface methodology(RSM).The experimental plan is based on Box-Behnken design matrix method.Linear and quadratic polynomial equations for predicting the heat input and the hardened bead geometry were developed.The results indicate that the proposed models predict the responses adequately within the limits of hardening parameters being used.It is suggested that regression equations can be used to find optimum hardening conditions for desired criteria.展开更多
The adsorption properties of a novel macroporous weak acid resin (D152) for Pb^2+ were investigated with chemical methods. The optimal adsorption condition of D152 resin for Pb^2+ is at pH 6.00 in HAc-NaAc medium....The adsorption properties of a novel macroporous weak acid resin (D152) for Pb^2+ were investigated with chemical methods. The optimal adsorption condition of D152 resin for Pb^2+ is at pH 6.00 in HAc-NaAc medium. The statically saturated adsorption capacity is 527 mg/g at 298 K. Pb^2+ adsorbed on D152 resin can be eluted with 0.05 mol/L HCI quantitatively. The adsorption rate constants determined under various temperatures are k288 n=2.22×10-5 s^-1, k298 K=2.51 × 10^-5 s^-1, and k308 K= 2.95 × 10^-5 s^-1, respectively. The apparent activation energy, Ea is 10.5 kJ/mol, and the adsorption parameters of thermodynamics are ΔH^Θ=13.3 kJ/mol, ΔS^Θ=119 J/(mol·K), and ΔG^Θ298 K =-22.2 kJ/mol, respectively. The adsorption behavior of D152 resin for Pb^2+ follows Langmuir model.展开更多
The thermal quantum discord (QD) is studied in a two-qubit Heisenberg XXZ system with DzyaloshinskiiMoriya (DM) interaction. We compare the thermal QD with thermal entanglement in this system and find remarkable d...The thermal quantum discord (QD) is studied in a two-qubit Heisenberg XXZ system with DzyaloshinskiiMoriya (DM) interaction. We compare the thermal QD with thermal entanglement in this system and find remarkable differences between them. For instance, we show situations where QD decreases asymptotically to zero with temperature T while entanglement decreases to zero at the point of critical temperature, situations where QD decreases with certain tunable parameters such as Dx and Dx when entanglement increases. We find that the characteristic of QD is exotic in this system and this possibly offers a potential solution to enhance entanglement of a system. We also show that tunable parameter Dx is more efficient than parameter Dz in most regions for controlling the QD.展开更多
基金Ministry of Education and Science of Serbia for financial support through Project TR34018
文摘The influence of R/v ratio on joint quality in 2024-T351 aluminum alloy was studied. Specimens were subjected to friction stir welding with the rotation rates of 750, 950 and 1180 r/min and welding speed between 73 and 190 mm/min, providing R/v ratio between 5.00 and 10.27. The welded joints were tested by means of both non-destructive (visual, penetrant and X-ray inspection) and destructive (metallographic, tension and hardness) testing. In all specimens typical zones are revealed, with corresponding differences in grain size. Tensile efficiency of the joints obtained is in the range of 52.2%to 82.3%. The results show that the best quality is obtained at R/v ratio of 8.06, 10.17 and 10.27. This behavior is attributed to the assumption that the material flows around the pin with an optimal speed, i.e. sufficient amount of material is available to fill the gap and prevent tunnel formation. R/v ratio also showed influence on hardness distribution, onion features and crack initiation/propagation zones.
文摘We do a new Li-ion battery evaluation research on the effects of cell resistance and polariza- tion on the energy loss in batteries based on thermal property and heat generation behavior of battery. Series of 18650 cells with different capacities and electrode materials are evalu- ated by measuring input and output energy which change with charge-discharge time and current. Based on the results of these tests, we build a model of energy loss in cells' charge- discharge process, which include Joule heat and polarization heat impact factors. It was reported that Joule heat was caused by cell resistance, which included De-resistance and reaction resistance, and reaction resistance could not be easily obtained through routine test method. Using this new method, we can get the total resistance R and the polarization parameter U. The relationship between R, η, and temperature is also investigated in order to build a general model for series of different Li-ion batteries, and the research can be used in the performance evaluation, state of charge prediction and the measuring of consistency of the batteries.
基金Project(51274107)supported by the National Natural Science Foundation of ChinaProject(2015FB127)supported by the Yunnan Natural Science Foundation,ChinaProject(2016P20151130003)supported by Analysis Foundation of Kunming University of Science and Technology,China
文摘Pure WC-6%Co nanosized composite powders were synthesized via a low-temperature method.The effects of carbon source on microstructure characteristic of composite powders were investigated,and the effects of heat-treatment parameter on carbon content of composite powders were also discussed.The results of SEM and XRD revealed that the carbon decomposing from glucose was more active than carbon black.Therefore,WC-Co nanosized composite powders could be synthesized at 900°C for 1 h under a hydrogen atmosphere.The individual WC grains were bonded together into a long strip under the action of cobalt.The results of carbon analysis revealed that the total carbon content decreased with the increase of the temperature in the range of 800-1000°C.Moreover,the total carbon content and the compounded carbon increased with the increase of the flow rate of H2 in the range of 1.1-1.9 m3/h.
基金supported by the National Basic Research Program of China (2009CB421505)the National Natural Science Foundation of China (41075044 and 41075079)
文摘Compared to potential temperature (θ) in the dry atmosphere and equivalent potential temperature (θc) in the saturated atmosphere, generalized potential tem- perature (θ") has already proven a better thermodynamic parameter in describing the non-uniformly saturated real atmosphere. To add otherwise absent graphic explanations, this paper first presents the physical definition of θ through a tephigram. Then, the utility of the measurement in identifying and forecasting the locations of precipita- tion maxima and heat wave areas with diagnostic com- parison studies and traditionally used thermodynamic parameters is shown.
文摘AA5083 friction stir welds were produced using systematic experimental design, the process forces and heat input with varying parameters were studied. Helpful empirical models were developed in designing friction stir welding (FSW) tools and FSW welders. These models may be further helpful for making process parameter choice for this sort of alloy, defining welding program and control of process parameters by using computer numerical control friction stir welding welders. The results show that tool rotational speed, welding speed and tool shoulder diameter are most significant parameters affecting axial force and heat input, while longitudinal force is significantly affected by welding speed and probe diameter.
文摘Laser transformation hardening(LTH)of unalloyed titanium of 1.6 mm-thick sheet,nearer to ASTM Grade 3 of chemical composition was investigated using 2 kW CW Nd:YAG laser.The effects of laser power(750-1 250 W),scanning speed(1 000-3 000 mm/min)and focal point position(from-10 to-30 mm)on the heat input,and hardened-bead geometry(i.e.hardened bead width(HBW),hardened depth(HD)and angle of entry of hardened bead profile with the surface(AEHB))were investigated using response surface methodology(RSM).The experimental plan is based on Box-Behnken design matrix method.Linear and quadratic polynomial equations for predicting the heat input and the hardened bead geometry were developed.The results indicate that the proposed models predict the responses adequately within the limits of hardening parameters being used.It is suggested that regression equations can be used to find optimum hardening conditions for desired criteria.
基金Project(2008F70059) supported by the Scientific and Technological Research Planning of Zhejiang Province, China
文摘The adsorption properties of a novel macroporous weak acid resin (D152) for Pb^2+ were investigated with chemical methods. The optimal adsorption condition of D152 resin for Pb^2+ is at pH 6.00 in HAc-NaAc medium. The statically saturated adsorption capacity is 527 mg/g at 298 K. Pb^2+ adsorbed on D152 resin can be eluted with 0.05 mol/L HCI quantitatively. The adsorption rate constants determined under various temperatures are k288 n=2.22×10-5 s^-1, k298 K=2.51 × 10^-5 s^-1, and k308 K= 2.95 × 10^-5 s^-1, respectively. The apparent activation energy, Ea is 10.5 kJ/mol, and the adsorption parameters of thermodynamics are ΔH^Θ=13.3 kJ/mol, ΔS^Θ=119 J/(mol·K), and ΔG^Θ298 K =-22.2 kJ/mol, respectively. The adsorption behavior of D152 resin for Pb^2+ follows Langmuir model.
基金Supported by the National Natural Science Foundation of China under Grant Nos.90503009,10775116973 Program under Grant No.2005CB724508
文摘The thermal quantum discord (QD) is studied in a two-qubit Heisenberg XXZ system with DzyaloshinskiiMoriya (DM) interaction. We compare the thermal QD with thermal entanglement in this system and find remarkable differences between them. For instance, we show situations where QD decreases asymptotically to zero with temperature T while entanglement decreases to zero at the point of critical temperature, situations where QD decreases with certain tunable parameters such as Dx and Dx when entanglement increases. We find that the characteristic of QD is exotic in this system and this possibly offers a potential solution to enhance entanglement of a system. We also show that tunable parameter Dx is more efficient than parameter Dz in most regions for controlling the QD.