Al-doped ZnO (AZO) target was prepared by hot pressing using ZnO and Al2O3 powder in mass ratio of 98:2.The effects of hot pressing conditions including temperature,pressure and preserving time on relative density ...Al-doped ZnO (AZO) target was prepared by hot pressing using ZnO and Al2O3 powder in mass ratio of 98:2.The effects of hot pressing conditions including temperature,pressure and preserving time on relative density were investigated.Pore evolution and phase structure change during densification process were studied.The results show that AZO target with super high relative density of 99% was prepared by two-stage hot pressing method under pressure of 35MPa,temperature of 1 050℃ and 1 150℃ with preserving time of 1 h,respectively.At temperature around 1 050℃,the number of isolated pore wasminimum.At temperature lower than 900℃,there existed Al2O3 phase.At temperature higher than 1 000℃,ZnAl2O4 phase was generated and its content was increased with temperature increasing.Hot pressing method had the advantage over pressureless sintering that the content of ZnAl2O4 was lower and sintering temperature could be also lower.With increasing the hot pressing temperature and preserving time,the electric resistivity of AZO target decreased greatly.A low resistivity of 3 10-3 cm was achieved under the temperature of 1 100℃,pressure of 35MPa and preserving time of 10 h.展开更多
A new method for manufacturing explosive charge liner of petroleum perforation bullet, using hot press sintering technique, has been introduced in the paper. The sintering process of making explosive charge liner has...A new method for manufacturing explosive charge liner of petroleum perforation bullet, using hot press sintering technique, has been introduced in the paper. The sintering process of making explosive charge liner has been investigated. The mechanical test and SEM analysis indicate that the property of the liner produced by the process is satisfied.展开更多
Lotus-type porous silicon with elongated pores was fabricated by unidirectional solidification under pressurized hydrogen. Porosity, pore diameter, and pore length can be adjusted by changing solidification speed and ...Lotus-type porous silicon with elongated pores was fabricated by unidirectional solidification under pressurized hydrogen. Porosity, pore diameter, and pore length can be adjusted by changing solidification speed and hydrogen pressure. The porosity of the ingot is nearly constant under different solidification speeds, but decreases with the increase of hydrogen pressure. The overall porosities of ingots fabricated at different hydrogen pressures were evaluated through a theoretical model. Findings are in good agreement with experimental values. The average pore diameter and pore length increase simultaneously while the average pore aspect ratio changes slightly with the decreases of solidification speed and hydrogen pressure. The average pore length is raised from 7 to 24 mm and the pore aspect ratio is raised from 8 to 20 respectively with the average pore diameter promoted by about 0.3 mm through improving the superheat degree of the melt from 200 to 300 K.展开更多
Dual equal channel lateral extrusion(DECLE)process with various passes followed by sheet extrusion process was performed to produce fine-grained ZK60 alloy sheets.The coarse grain structure of the annealed sample afte...Dual equal channel lateral extrusion(DECLE)process with various passes followed by sheet extrusion process was performed to produce fine-grained ZK60 alloy sheets.The coarse grain structure of the annealed sample after applying sheet extrusion(size:68μm)changed to fine grains of 6.0 and 5.2μm after 3 and 5 passes of DECLE and following extrusion.The hot shear deformation behavior of samples was studied by developing constitutive equations based on shear punch test(SPT)results.SPT was carried out in the temperature range of 200−300℃ and strain rate range of 0.003−0.33 s^(–1).The activation energy of 125−139 kJ/mol and the stress exponent of 3.5−4.2 were calculated for all conditions,which indicated that dislocation creep,controlled by dislocation climb and solute drag mechanism,acted as the main hot deformation mechanism.It was concluded that material constants of n and Q are dependent on the microstructural factors such as grain size and second phase particle fraction,and the relationship of which was anticipated using a 3D surface curve.Moreover,the similar strong basal texture of extruded sheets gave rise to the same deformation mechanisms during SPT and similar n and Q values for ZK60 alloy.展开更多
Effects of heat softening on the initiation of slide surface(shear banding) in clayey slopes during fast deformation were discussed.Controlling equations considering heat,pore pressure and mechanical movement were pre...Effects of heat softening on the initiation of slide surface(shear banding) in clayey slopes during fast deformation were discussed.Controlling equations considering heat,pore pressure and mechanical movement were presented.By perturbation method,the instability condition of localized zone(i.e.criterion for initiation of shear banding) for thermal related soils,such as clayey slope,was obtained.It is shown that slide surface initiates once the thermal-softening effects overcome the strain-hardening effects whether it is adiabatic or not.Without strain hardening effects,strain rate hardening obviously plays a role in initiation of shear band.During initiating process,heat is trapped inside the shear band,which leads rapidly to a pore pressure increase and fast loss of strength.The localized shear strain is concentrated in a narrow zone with a width of several centimeters at most and increases fast.This zone forms the sliding surface.Temperature can increase more than 2?C,pore pressure can increase 160% in about 0.1s inside this zone.These changes cause the fast decrease in friction-coefficient by about 36% over the initial value.That is how shear band initiated and developed in clayey slopes.展开更多
To investigate the effects of pressure on the hot isostatic pressing(HIP) process of a stainless steel powder,density distribution and deformation of the powder at four different applied pressure levels were predicted...To investigate the effects of pressure on the hot isostatic pressing(HIP) process of a stainless steel powder,density distribution and deformation of the powder at four different applied pressure levels were predicted and compared by using finite element method(FEM).Constitutive relations of porous compacts during HIP process were derived based on the yield criterion of porous metal materials.Thermo-mechanical coupling calculations were carried out by the MSC.Marc.Densification mechanisms were studied through evolutions of relative density,equivalent plastic strain and equivalent viscoplastic strain rate for compacts.The simulation results were also compared with experimental data.The results show that the densification rate and final density of compacts increase dramatically with the increase in the applied pressure level when it is below 100 MPa during HIP process,and the creep for compacts evolves into steady stage with the improvement of density.展开更多
Pore structure of C/C (Carbon-Carbon) composite after several stages of pitch impregnation under the high pressure and heat treatment was investigated by means of low temperature nitrogen adsorption and the standard...Pore structure of C/C (Carbon-Carbon) composite after several stages of pitch impregnation under the high pressure and heat treatment was investigated by means of low temperature nitrogen adsorption and the standard contact porosimetry. Total pore volume, pore size distribution and specific surface area were calculated for samples of composite after several successive stages of treatment. The radius of pores presented in the material changes from 1 nm to 90 tam. Total pore volume and specific surface area both decrease after successive stages of pitch impregnation under the pressure, whereas heat treatment up to 1,750 ℃ and 2,000 ℃ leads to creation of some porous space and pore volume expansion. The bulk porosity of C/C composite comes down from 33.7% to 13.7% after the serial stages of treatment and the specific surface area is reduced by half compared to the initial material.展开更多
Consider the systemwhich can be used to model the adiabatic gas flow through porous media. Here v is specific volume, u denotes velocity, s stands for entropy, p denotes pressure with pv <0 for v >0. It is prove...Consider the systemwhich can be used to model the adiabatic gas flow through porous media. Here v is specific volume, u denotes velocity, s stands for entropy, p denotes pressure with pv <0 for v >0. It is proved that the solutions of (1) tend to those of the following nonlinear parabolic equation time-asymptotically:展开更多
The initial boundary value problems (IBVP) for the system of compressible adiabatic flow through porous media and the IBVP for its corresponding reduced system through Darcy’ laws on [0, 1] x [0, +] are considered re...The initial boundary value problems (IBVP) for the system of compressible adiabatic flow through porous media and the IBVP for its corresponding reduced system through Darcy’ laws on [0, 1] x [0, +] are considered respectively. The global existence of smooth solutions to the IBVP problems for two systems are proved, and their large-time behavior is analyzed. The time-asymptotic equivalence of these two systems are investigated, the decay rate of the difference of solutions between these two systems are shown to be determined explicitly by the initial perturbations and boundary effects. It is found that the oscillation of the specific volume can be cancelled by that of entropy, i.e., the oscillation of the specific volume and entropy is not required to be small.展开更多
Gas hydrate decomposition in sediments involves complicated multiphase flow and heat and mass transfer processes because of heat absorption by solid hydrates. Factors affecting gas hydrate decomposition in sediments i...Gas hydrate decomposition in sediments involves complicated multiphase flow and heat and mass transfer processes because of heat absorption by solid hydrates. Factors affecting gas hydrate decomposition in sediments include sediment type, mineral composition, pore size distribution, particle size, pore water composition, hydrate saturation distribution, initial formation pressure and temperature and cement characteristics. In this paper, experimental simulations of gas hydrate decomposition are carried out on an artificial core to investigate the effects of initial pressure and temperature, particle size and pore size. The experiments show that the characteristics of gas hydrate decomposition in sediments differ completely from those in a pure water system. The decomposition rate of hydrate sediments increases with the initial pressure increasing and decreasing temperatures. Furthermore, the decomposition rate of hydrate sediments decreases with decreasing particle size and increasing pore size.展开更多
基金Project(31001) supported by the Technology Development Foundation of Ministry of Science and Technology,China
文摘Al-doped ZnO (AZO) target was prepared by hot pressing using ZnO and Al2O3 powder in mass ratio of 98:2.The effects of hot pressing conditions including temperature,pressure and preserving time on relative density were investigated.Pore evolution and phase structure change during densification process were studied.The results show that AZO target with super high relative density of 99% was prepared by two-stage hot pressing method under pressure of 35MPa,temperature of 1 050℃ and 1 150℃ with preserving time of 1 h,respectively.At temperature around 1 050℃,the number of isolated pore wasminimum.At temperature lower than 900℃,there existed Al2O3 phase.At temperature higher than 1 000℃,ZnAl2O4 phase was generated and its content was increased with temperature increasing.Hot pressing method had the advantage over pressureless sintering that the content of ZnAl2O4 was lower and sintering temperature could be also lower.With increasing the hot pressing temperature and preserving time,the electric resistivity of AZO target decreased greatly.A low resistivity of 3 10-3 cm was achieved under the temperature of 1 100℃,pressure of 35MPa and preserving time of 10 h.
文摘A new method for manufacturing explosive charge liner of petroleum perforation bullet, using hot press sintering technique, has been introduced in the paper. The sintering process of making explosive charge liner has been investigated. The mechanical test and SEM analysis indicate that the property of the liner produced by the process is satisfied.
基金Project(51271096)supported by the National Natural Science Foundation of ChinaProject(NCET-12-0310)supported by the Program for New Century Excellent Talents in University,China
文摘Lotus-type porous silicon with elongated pores was fabricated by unidirectional solidification under pressurized hydrogen. Porosity, pore diameter, and pore length can be adjusted by changing solidification speed and hydrogen pressure. The porosity of the ingot is nearly constant under different solidification speeds, but decreases with the increase of hydrogen pressure. The overall porosities of ingots fabricated at different hydrogen pressures were evaluated through a theoretical model. Findings are in good agreement with experimental values. The average pore diameter and pore length increase simultaneously while the average pore aspect ratio changes slightly with the decreases of solidification speed and hydrogen pressure. The average pore length is raised from 7 to 24 mm and the pore aspect ratio is raised from 8 to 20 respectively with the average pore diameter promoted by about 0.3 mm through improving the superheat degree of the melt from 200 to 300 K.
文摘Dual equal channel lateral extrusion(DECLE)process with various passes followed by sheet extrusion process was performed to produce fine-grained ZK60 alloy sheets.The coarse grain structure of the annealed sample after applying sheet extrusion(size:68μm)changed to fine grains of 6.0 and 5.2μm after 3 and 5 passes of DECLE and following extrusion.The hot shear deformation behavior of samples was studied by developing constitutive equations based on shear punch test(SPT)results.SPT was carried out in the temperature range of 200−300℃ and strain rate range of 0.003−0.33 s^(–1).The activation energy of 125−139 kJ/mol and the stress exponent of 3.5−4.2 were calculated for all conditions,which indicated that dislocation creep,controlled by dislocation climb and solute drag mechanism,acted as the main hot deformation mechanism.It was concluded that material constants of n and Q are dependent on the microstructural factors such as grain size and second phase particle fraction,and the relationship of which was anticipated using a 3D surface curve.Moreover,the similar strong basal texture of extruded sheets gave rise to the same deformation mechanisms during SPT and similar n and Q values for ZK60 alloy.
基金funded by the National Natural Science Foundation of China (Grant No. 11272314 No. 51239010)+1 种基金the Specialized Research Fund for the Doctoral Program of Higher Education of China (Grant No. 20133514110004)the Research Project of Chinese Ministry of Transport (Grant No. 201331849A130)
文摘Effects of heat softening on the initiation of slide surface(shear banding) in clayey slopes during fast deformation were discussed.Controlling equations considering heat,pore pressure and mechanical movement were presented.By perturbation method,the instability condition of localized zone(i.e.criterion for initiation of shear banding) for thermal related soils,such as clayey slope,was obtained.It is shown that slide surface initiates once the thermal-softening effects overcome the strain-hardening effects whether it is adiabatic or not.Without strain hardening effects,strain rate hardening obviously plays a role in initiation of shear band.During initiating process,heat is trapped inside the shear band,which leads rapidly to a pore pressure increase and fast loss of strength.The localized shear strain is concentrated in a narrow zone with a width of several centimeters at most and increases fast.This zone forms the sliding surface.Temperature can increase more than 2?C,pore pressure can increase 160% in about 0.1s inside this zone.These changes cause the fast decrease in friction-coefficient by about 36% over the initial value.That is how shear band initiated and developed in clayey slopes.
基金Project(2007AA03Z115) supported by the National High Technology Research and Development Program of ChinaProject(2009ZX04005-041-03) supported by the National Science and Technology Major Program of ChinaProject(2010MS046) supported by the Independent Fund of Huazhong University of Science and Technology,China
文摘To investigate the effects of pressure on the hot isostatic pressing(HIP) process of a stainless steel powder,density distribution and deformation of the powder at four different applied pressure levels were predicted and compared by using finite element method(FEM).Constitutive relations of porous compacts during HIP process were derived based on the yield criterion of porous metal materials.Thermo-mechanical coupling calculations were carried out by the MSC.Marc.Densification mechanisms were studied through evolutions of relative density,equivalent plastic strain and equivalent viscoplastic strain rate for compacts.The simulation results were also compared with experimental data.The results show that the densification rate and final density of compacts increase dramatically with the increase in the applied pressure level when it is below 100 MPa during HIP process,and the creep for compacts evolves into steady stage with the improvement of density.
文摘Pore structure of C/C (Carbon-Carbon) composite after several stages of pitch impregnation under the high pressure and heat treatment was investigated by means of low temperature nitrogen adsorption and the standard contact porosimetry. Total pore volume, pore size distribution and specific surface area were calculated for samples of composite after several successive stages of treatment. The radius of pores presented in the material changes from 1 nm to 90 tam. Total pore volume and specific surface area both decrease after successive stages of pitch impregnation under the pressure, whereas heat treatment up to 1,750 ℃ and 2,000 ℃ leads to creation of some porous space and pore volume expansion. The bulk porosity of C/C composite comes down from 33.7% to 13.7% after the serial stages of treatment and the specific surface area is reduced by half compared to the initial material.
文摘Consider the systemwhich can be used to model the adiabatic gas flow through porous media. Here v is specific volume, u denotes velocity, s stands for entropy, p denotes pressure with pv <0 for v >0. It is proved that the solutions of (1) tend to those of the following nonlinear parabolic equation time-asymptotically:
基金the MST Grant #1999075107 and the Innovation funds of AMSS, CAS of China.
文摘The initial boundary value problems (IBVP) for the system of compressible adiabatic flow through porous media and the IBVP for its corresponding reduced system through Darcy’ laws on [0, 1] x [0, +] are considered respectively. The global existence of smooth solutions to the IBVP problems for two systems are proved, and their large-time behavior is analyzed. The time-asymptotic equivalence of these two systems are investigated, the decay rate of the difference of solutions between these two systems are shown to be determined explicitly by the initial perturbations and boundary effects. It is found that the oscillation of the specific volume can be cancelled by that of entropy, i.e., the oscillation of the specific volume and entropy is not required to be small.
基金supported by the National Basic Research Program of China (Grant No. 2009CB219507)
文摘Gas hydrate decomposition in sediments involves complicated multiphase flow and heat and mass transfer processes because of heat absorption by solid hydrates. Factors affecting gas hydrate decomposition in sediments include sediment type, mineral composition, pore size distribution, particle size, pore water composition, hydrate saturation distribution, initial formation pressure and temperature and cement characteristics. In this paper, experimental simulations of gas hydrate decomposition are carried out on an artificial core to investigate the effects of initial pressure and temperature, particle size and pore size. The experiments show that the characteristics of gas hydrate decomposition in sediments differ completely from those in a pure water system. The decomposition rate of hydrate sediments increases with the initial pressure increasing and decreasing temperatures. Furthermore, the decomposition rate of hydrate sediments decreases with decreasing particle size and increasing pore size.