We have developed a process model to simulate the behavior of an industrial-scale pressurized Lurgi fixed-bed coal gasifier using Aspen Plus and General Algebraic Modeling System(GAMS). Reaction characteristics in the...We have developed a process model to simulate the behavior of an industrial-scale pressurized Lurgi fixed-bed coal gasifier using Aspen Plus and General Algebraic Modeling System(GAMS). Reaction characteristics in the fixed-bed gasifier comprising four sequential reaction zones—drying, pyrolysis, combustion and gasification are respectively modeled. A non-linear programming(NLP) model is developed for the pyrolysis zone to estimate the products composition which includes char, coal gases and distillable liquids. A four-stage model with restricted equilibrium temperature is used to study the thermodynamic equilibrium characteristics and calculate the composition of syngas in the combustion and gasification zones. The thermodynamic analysis shows that the exergetic efficiency of the fixed-bed gasifier is mainly determined by the oxygen/coal ratio. The exergetic efficiency of the process will reach an optimum value of 78.3% when the oxygen/coal and steam/coal mass ratios are 0.14 and 0.80, respectively.展开更多
The non-isothermal kinetics of CdO nanoparticles prepared from CdCO3 precursor using thermal decomposition method was investigated. A model-fitting Malek approach and a model-free advanced isoconversional method of Vy...The non-isothermal kinetics of CdO nanoparticles prepared from CdCO3 precursor using thermal decomposition method was investigated. A model-fitting Malek approach and a model-free advanced isoconversional method of Vyazovkin were applied to the analysis of the DSC and TGA data. The results showed that CdO nanoparticles prepared from CdCO3 followed an autocatalytic reaction. Sestak–Berggren model could favorably describe the studied reaction process. Moreover, the apparent activation energy of CdCO3 decomposition was calculated to be (119.19±9.97) kJ/mol and the explicit rate equation form of CdCO3 decomposition was established.展开更多
Based on theory of variable-mass system thermodynamics, the dynamic mathematic models of each component of the horizontal steam-launch system were established, and by the numerical simulation of the system launching p...Based on theory of variable-mass system thermodynamics, the dynamic mathematic models of each component of the horizontal steam-launch system were established, and by the numerical simulation of the system launching process, the thermodynamics and kinetics characteristics of the system with three valves of different flow characteristics were got. The simulation results show that the values of the peak-to-average ratios of dimensionless acceleration with the equal percentage valve, the linear valve and the quick opening valve are 1.355, 1.614 and 1.722, respectively, and the final values of the dimensionless velocities are 0.843, 0.957 and 1.0, respectively. In conclusion, the value of the dimensionless velocity with the equal percentage valve doesn't reach the set value of 0.90 when the dimensionless displacement is 0.82, while the system with the linear valve can meet the launching requirement, as well as the fluctuation range of dimensionless acceleration is less than that of the quick opening valve. Therefore, the system with the linear valve has the best performance among the three kinds of valves.展开更多
In order to study the major performance indicators of the twin-rotor piston engine(TRPE), Matlab/simulink was used to simulate the mathematical models of its thermodynamic processes. With consideration of the characte...In order to study the major performance indicators of the twin-rotor piston engine(TRPE), Matlab/simulink was used to simulate the mathematical models of its thermodynamic processes. With consideration of the characteristics of the working processes in the TRPE, corresponding differential equations were established and then simplified by period features of the TRPE. Finally, the major boundary conditions were figured out. The changing trends of mass, pressure and temperature of working fuel in the working chamber during a complete engine cycle were presented. The simulation results are consistent with the trends of an actual working cycle in the TRPE, which indicates that the method of simulation is feasible. As the pressure in the working chamber is calculated, all the performance parameters of the TRPE can be obtained. The major performance indicators, such as the indicated mean effective pressure, power to weight ratio and the volume power, are also acquired. Compared with three different types of conventional engines, the TRPE has a bigger utilization ratio of cylinder volume, a higher power to weight ratio and a more compact structure. This indicates that TRPE is superior to conventional engines.展开更多
This study presents a novel design for a spiral finned crystallizer which is the primary element of progressive freeze concentration(PFC) system, which simplifies the setup of the conventional system. After the crysta...This study presents a novel design for a spiral finned crystallizer which is the primary element of progressive freeze concentration(PFC) system, which simplifies the setup of the conventional system. After the crystallizer has been designed, the research experiments have been conducted and evaluated through a thorough analysis of its performance by developing a mathematical model that can be used to predict the productivity of ice crystal at a range of coolant temperature. The model is developed based on the basic heat transfer equation, and by considering the solution's and the coolant's convective heat transfer coefficient(h) under the forced flow condition.The model's accuracy is verified by making comparison between the ice crystal mass' experimental value and the values predicted by the model. Consequently, the study found that the model helps in enhancing the PFC system.展开更多
We start from a realistic half space then use to develop a mathematical asymptotic model for thermal imaging, which we analysis well suited for the design of reconstruction algorithms. We seek to reconstruct thermal a...We start from a realistic half space then use to develop a mathematical asymptotic model for thermal imaging, which we analysis well suited for the design of reconstruction algorithms. We seek to reconstruct thermal anomalies only through their rough features. With this way our proposed algorithms are stable against measurement noise and geometry perturbations. Based on rigorous asymptotic estimates, we first obtain an approximation for the temperature profile which we then use to design noniterative detection algorithms. We show on numerical simulations evidence that they are accurate and robust. Moreover, we provide a mathematical model for ultrasonic temperature imaging, which is an important technique in cancerous tissue ablation therapy.展开更多
The heat generation model and three-dimensional computational fluid dynamics model for lithium ion cells were established with boundary conditions defined.In order to provide a better insight about the behaviors of hi...The heat generation model and three-dimensional computational fluid dynamics model for lithium ion cells were established with boundary conditions defined.In order to provide a better insight about the behaviors of high-power lithium ion cells under realistic discharge conditions,the temperature difference of the cells and an active thermal management system with a pure air-cooling mode were analyzed and predicted with the factors affecting the unevenness of temperature field discussed.The results show a significant effect of the cooling flow rate on the temperature rise of the cells for all discharge rates.Average surface temperatures are relatively uniform at lower discharge rate that makes it easier to control the temperature of the pack.Cell temperatures are expected to rise significantly toward the end of discharge and they show non-uniformity at higher discharge rates.Adequate air flow rate of active cooling is required at high discharge rate and high ambient temperature for practical pack thermal management system.展开更多
The automated energy generating complex allows obtaining heat energy from waste coal-water slurry fuel (WCF) that is a mixture of fine coal particles from coal enrichment wastes with water. The mixture is blown into...The automated energy generating complex allows obtaining heat energy from waste coal-water slurry fuel (WCF) that is a mixture of fine coal particles from coal enrichment wastes with water. The mixture is blown into the swirl chamber under the pressure through the special sprayers. The received heat energy is used in different ways. One of the important issues is to estimate the heat losses through the walls of this chamber. In this paper we solved the boundary problem of mathematical physics to estimate the temperature fields in the walls of the swirl chamber. The obtained solution allows us to estimate the heat losses through the waUs of the swid chamber. The task of the mathematical physics has been solved by a numerical finite-difference method. The method for solving this prob- lem can be used in the calculation of temperature fields and evaluation of heat losses in other thermal power units.展开更多
This paper investigates the heat transfer characteristics of a thermoelectric generator. The influence of heat dissipation intensity to the sub-thermal resistances distribution is experimentally studied. Based on the ...This paper investigates the heat transfer characteristics of a thermoelectric generator. The influence of heat dissipation intensity to the sub-thermal resistances distribution is experimentally studied. Based on the thermal network analysis and finite time thermodynamics, an analytical model including all thermal resistances (in both thermocouples and external heat exchangers) is developed to predict the performance of the generator. The results show that the computed values of output power agree well with the experimental values. The heat transfer enhancement on the generator cold side greatly reduces the cold side temperature and thermal resistance, and obviously improves the output power. Compare with air natural convection cooling, the main thermal resistance changes from the resistance between the fins and the ambient to the thermal contact resistances between the generator and the heat sink at the conditions of forced convection and water cooling. This study may be guide the optimization of generator structure.展开更多
During subduction processes, slabs continuously have heat exchange with the ambient mantle, including both conduction and advection effects. The evolution of slab thermal structure is one of the dominant factors in co...During subduction processes, slabs continuously have heat exchange with the ambient mantle, including both conduction and advection effects. The evolution of slab thermal structure is one of the dominant factors in controlling physical and chemical property changes in subduction zones. It also affects our understanding of many key geological processes, such as mineral dehydration, rock partial melting, arc volcanism, and seismic activities in subduction zones. There are mainly two ways for studying thermal structure of subduction zones with geodynamic models: analytical model and numerical model. Analytical model provides insights into the most dominant controlling physical parameters on the thermal structure, such as slab age, velocity and dip angle, shear stress and thermal conductivity, etc. Numerical model can further deal with more complicated environments, such as viscosity change in the mantle wedge, coupling process between slabs and the ambient mantle, and incorporation of petrology and mineralogy. When applying geodynamic modeling results to specific subduction zones on the Earth, there are many factors which may complicate the process, therefore it is difficult to precisely constrain the thermal structure of subduction zones. With the development of new quantitative methods in geophysics and geochemistry, we may obtain more observational constraints for thermal structure of subduction zones, thus providing more reasonable explanations for geological processes related to subduction zones.展开更多
In this paper,the behavior of a salt-gradient solar pond with the square cross-section has been studied experimentally and numerically.A small-scale solar pond were designed and built to provide quantitative data.A tw...In this paper,the behavior of a salt-gradient solar pond with the square cross-section has been studied experimentally and numerically.A small-scale solar pond were designed and built to provide quantitative data.A two-dimensional,transient heat and mass transfer model has been solved numerically by using finite-control-volume method.In this study,all the thermo-physical properties are variable as the function of temperature and salt concentration.Numerical results as obtained for the experimental pond have been satisfactorily compared and validated against measured data.Furthermore,the wall shading effect has been elaborated to improve the agreement between two sets of results.The temperature of the storage zone is predicted well by the model.It also can be observed that the initial concentration profile is preserved with time.The stability of the pond in time has been investigated in order to distinguish the critical zones.Finally,the application of an energy analysis gives an efficiency of about 12%for the pond.展开更多
When subjected to voltage,the dielectric elastomer membrane reduces its thickness and expands its area under the resulting compressive force.This characteristic enables the dielectric elastomer actuators of different ...When subjected to voltage,the dielectric elastomer membrane reduces its thickness and expands its area under the resulting compressive force.This characteristic enables the dielectric elastomer actuators of different structures to be designed and fabricated.By employing the thermodynamic theory and research method proposed by Suo et al.,an equilibrium equation of folded dielectric elastomer actuator with two generalized coordinates is established.The governing equations of failure models involving electromechanical instability,zero electric field,electrical breakdown,loss of tension,and rupture by stretch are also derived.The allowable areas of folded dielectric elastomer actuators are described.These results could provide a powerful guidance to the design and performance evaluation of the dielectric elastomer actuators.展开更多
A modified theoretical model is proposed to predict the grain boundary segregation of impurity atoms during high temperature plastic deformation. The model is based on the supersaturated vacancy-impurity complex creat...A modified theoretical model is proposed to predict the grain boundary segregation of impurity atoms during high temperature plastic deformation. The model is based on the supersaturated vacancy-impurity complex created by plastic deformation and involves quasi-thermodynamics and kinetics. Model predictions are made for phosphorus grain boundary segregation during plastic deformation in ferrite steel. The results reveal that phosphorus segregates at grain boundaries during plastic deformation. At a given temperature, under a certain strain rate the segregation increases with increasing deformation amount until reaching a steady value, and at the same deformation amount it increases with increasing strain rate. The predicted results are compared with the available experimental values, indicating that there is a reasonable agreement between the theoretical predictions and the experimental observations.展开更多
基金Supported by the National Basic Research Program of China(2012CB720500)the National Natural Science Foundation of China(U1162121)
文摘We have developed a process model to simulate the behavior of an industrial-scale pressurized Lurgi fixed-bed coal gasifier using Aspen Plus and General Algebraic Modeling System(GAMS). Reaction characteristics in the fixed-bed gasifier comprising four sequential reaction zones—drying, pyrolysis, combustion and gasification are respectively modeled. A non-linear programming(NLP) model is developed for the pyrolysis zone to estimate the products composition which includes char, coal gases and distillable liquids. A four-stage model with restricted equilibrium temperature is used to study the thermodynamic equilibrium characteristics and calculate the composition of syngas in the combustion and gasification zones. The thermodynamic analysis shows that the exergetic efficiency of the fixed-bed gasifier is mainly determined by the oxygen/coal ratio. The exergetic efficiency of the process will reach an optimum value of 78.3% when the oxygen/coal and steam/coal mass ratios are 0.14 and 0.80, respectively.
文摘The non-isothermal kinetics of CdO nanoparticles prepared from CdCO3 precursor using thermal decomposition method was investigated. A model-fitting Malek approach and a model-free advanced isoconversional method of Vyazovkin were applied to the analysis of the DSC and TGA data. The results showed that CdO nanoparticles prepared from CdCO3 followed an autocatalytic reaction. Sestak–Berggren model could favorably describe the studied reaction process. Moreover, the apparent activation energy of CdCO3 decomposition was calculated to be (119.19±9.97) kJ/mol and the explicit rate equation form of CdCO3 decomposition was established.
基金Project(20080431380)supported by the National Postdoctoral Science Foundation,China
文摘Based on theory of variable-mass system thermodynamics, the dynamic mathematic models of each component of the horizontal steam-launch system were established, and by the numerical simulation of the system launching process, the thermodynamics and kinetics characteristics of the system with three valves of different flow characteristics were got. The simulation results show that the values of the peak-to-average ratios of dimensionless acceleration with the equal percentage valve, the linear valve and the quick opening valve are 1.355, 1.614 and 1.722, respectively, and the final values of the dimensionless velocities are 0.843, 0.957 and 1.0, respectively. In conclusion, the value of the dimensionless velocity with the equal percentage valve doesn't reach the set value of 0.90 when the dimensionless displacement is 0.82, while the system with the linear valve can meet the launching requirement, as well as the fluctuation range of dimensionless acceleration is less than that of the quick opening valve. Therefore, the system with the linear valve has the best performance among the three kinds of valves.
基金Project(7131109)supported by the National Defense Pre-research Foundation of ChinaProject(51175500)supported by the National Natural Science Foundation of China
文摘In order to study the major performance indicators of the twin-rotor piston engine(TRPE), Matlab/simulink was used to simulate the mathematical models of its thermodynamic processes. With consideration of the characteristics of the working processes in the TRPE, corresponding differential equations were established and then simplified by period features of the TRPE. Finally, the major boundary conditions were figured out. The changing trends of mass, pressure and temperature of working fuel in the working chamber during a complete engine cycle were presented. The simulation results are consistent with the trends of an actual working cycle in the TRPE, which indicates that the method of simulation is feasible. As the pressure in the working chamber is calculated, all the performance parameters of the TRPE can be obtained. The major performance indicators, such as the indicated mean effective pressure, power to weight ratio and the volume power, are also acquired. Compared with three different types of conventional engines, the TRPE has a bigger utilization ratio of cylinder volume, a higher power to weight ratio and a more compact structure. This indicates that TRPE is superior to conventional engines.
基金the financial support through Research University Grant and Fundamental Research Grant Scheme(Vot nos.04H46 and 4F224)Chemical Engineering Department,Universiti Teknologi PETRONAS for its support
文摘This study presents a novel design for a spiral finned crystallizer which is the primary element of progressive freeze concentration(PFC) system, which simplifies the setup of the conventional system. After the crystallizer has been designed, the research experiments have been conducted and evaluated through a thorough analysis of its performance by developing a mathematical model that can be used to predict the productivity of ice crystal at a range of coolant temperature. The model is developed based on the basic heat transfer equation, and by considering the solution's and the coolant's convective heat transfer coefficient(h) under the forced flow condition.The model's accuracy is verified by making comparison between the ice crystal mass' experimental value and the values predicted by the model. Consequently, the study found that the model helps in enhancing the PFC system.
基金supported by the ANR project EchoScan(AN-06-Blan-0089)the NSF grant DMS 0707421.
文摘We start from a realistic half space then use to develop a mathematical asymptotic model for thermal imaging, which we analysis well suited for the design of reconstruction algorithms. We seek to reconstruct thermal anomalies only through their rough features. With this way our proposed algorithms are stable against measurement noise and geometry perturbations. Based on rigorous asymptotic estimates, we first obtain an approximation for the temperature profile which we then use to design noniterative detection algorithms. We show on numerical simulations evidence that they are accurate and robust. Moreover, we provide a mathematical model for ultrasonic temperature imaging, which is an important technique in cancerous tissue ablation therapy.
基金supported by the National Natural Science Foundation of China(No.50976011)the Fundamental Research Funds for the Central Universities(No.2009JBM090)
文摘The heat generation model and three-dimensional computational fluid dynamics model for lithium ion cells were established with boundary conditions defined.In order to provide a better insight about the behaviors of high-power lithium ion cells under realistic discharge conditions,the temperature difference of the cells and an active thermal management system with a pure air-cooling mode were analyzed and predicted with the factors affecting the unevenness of temperature field discussed.The results show a significant effect of the cooling flow rate on the temperature rise of the cells for all discharge rates.Average surface temperatures are relatively uniform at lower discharge rate that makes it easier to control the temperature of the pack.Cell temperatures are expected to rise significantly toward the end of discharge and they show non-uniformity at higher discharge rates.Adequate air flow rate of active cooling is required at high discharge rate and high ambient temperature for practical pack thermal management system.
基金the project No.2010-218-02-174 by the Governmental Order of the Russian Federation of April 9,2010 No.218'On measures of federal support of cooperation between higher educational institutions and enterprises which realize complex projects of hi-tech production development
文摘The automated energy generating complex allows obtaining heat energy from waste coal-water slurry fuel (WCF) that is a mixture of fine coal particles from coal enrichment wastes with water. The mixture is blown into the swirl chamber under the pressure through the special sprayers. The received heat energy is used in different ways. One of the important issues is to estimate the heat losses through the walls of this chamber. In this paper we solved the boundary problem of mathematical physics to estimate the temperature fields in the walls of the swirl chamber. The obtained solution allows us to estimate the heat losses through the waUs of the swid chamber. The task of the mathematical physics has been solved by a numerical finite-difference method. The method for solving this prob- lem can be used in the calculation of temperature fields and evaluation of heat losses in other thermal power units.
基金supported by The Major Technology Special Program of Guangdong Province(Grant No.2008A080302002 and 2010A080405003)
文摘This paper investigates the heat transfer characteristics of a thermoelectric generator. The influence of heat dissipation intensity to the sub-thermal resistances distribution is experimentally studied. Based on the thermal network analysis and finite time thermodynamics, an analytical model including all thermal resistances (in both thermocouples and external heat exchangers) is developed to predict the performance of the generator. The results show that the computed values of output power agree well with the experimental values. The heat transfer enhancement on the generator cold side greatly reduces the cold side temperature and thermal resistance, and obviously improves the output power. Compare with air natural convection cooling, the main thermal resistance changes from the resistance between the fins and the ambient to the thermal contact resistances between the generator and the heat sink at the conditions of forced convection and water cooling. This study may be guide the optimization of generator structure.
基金supported by the National Basic Research Program of China(Grant No.2015CB856106)
文摘During subduction processes, slabs continuously have heat exchange with the ambient mantle, including both conduction and advection effects. The evolution of slab thermal structure is one of the dominant factors in controlling physical and chemical property changes in subduction zones. It also affects our understanding of many key geological processes, such as mineral dehydration, rock partial melting, arc volcanism, and seismic activities in subduction zones. There are mainly two ways for studying thermal structure of subduction zones with geodynamic models: analytical model and numerical model. Analytical model provides insights into the most dominant controlling physical parameters on the thermal structure, such as slab age, velocity and dip angle, shear stress and thermal conductivity, etc. Numerical model can further deal with more complicated environments, such as viscosity change in the mantle wedge, coupling process between slabs and the ambient mantle, and incorporation of petrology and mineralogy. When applying geodynamic modeling results to specific subduction zones on the Earth, there are many factors which may complicate the process, therefore it is difficult to precisely constrain the thermal structure of subduction zones. With the development of new quantitative methods in geophysics and geochemistry, we may obtain more observational constraints for thermal structure of subduction zones, thus providing more reasonable explanations for geological processes related to subduction zones.
文摘In this paper,the behavior of a salt-gradient solar pond with the square cross-section has been studied experimentally and numerically.A small-scale solar pond were designed and built to provide quantitative data.A two-dimensional,transient heat and mass transfer model has been solved numerically by using finite-control-volume method.In this study,all the thermo-physical properties are variable as the function of temperature and salt concentration.Numerical results as obtained for the experimental pond have been satisfactorily compared and validated against measured data.Furthermore,the wall shading effect has been elaborated to improve the agreement between two sets of results.The temperature of the storage zone is predicted well by the model.It also can be observed that the initial concentration profile is preserved with time.The stability of the pond in time has been investigated in order to distinguish the critical zones.Finally,the application of an energy analysis gives an efficiency of about 12%for the pond.
基金supported by the National Natural Science Foundation of China(Grant Nos.11225211,11272106,11102052)China Postdoctoral Science Foundation(Grant No.2012M520032)+1 种基金Heilongjiang Postdoctoral Fund(Grant No.LBH-Z12091)the Fundamental Research Funds for the Central Universities(Grant No.HIT.NSRIF.2013030)
文摘When subjected to voltage,the dielectric elastomer membrane reduces its thickness and expands its area under the resulting compressive force.This characteristic enables the dielectric elastomer actuators of different structures to be designed and fabricated.By employing the thermodynamic theory and research method proposed by Suo et al.,an equilibrium equation of folded dielectric elastomer actuator with two generalized coordinates is established.The governing equations of failure models involving electromechanical instability,zero electric field,electrical breakdown,loss of tension,and rupture by stretch are also derived.The allowable areas of folded dielectric elastomer actuators are described.These results could provide a powerful guidance to the design and performance evaluation of the dielectric elastomer actuators.
基金supported by the National Natural Science Foundation of China (Grant No. 50671033)the Department of Science and Technology of Shenzhen (Grant No. SY200806260037A)
文摘A modified theoretical model is proposed to predict the grain boundary segregation of impurity atoms during high temperature plastic deformation. The model is based on the supersaturated vacancy-impurity complex created by plastic deformation and involves quasi-thermodynamics and kinetics. Model predictions are made for phosphorus grain boundary segregation during plastic deformation in ferrite steel. The results reveal that phosphorus segregates at grain boundaries during plastic deformation. At a given temperature, under a certain strain rate the segregation increases with increasing deformation amount until reaching a steady value, and at the same deformation amount it increases with increasing strain rate. The predicted results are compared with the available experimental values, indicating that there is a reasonable agreement between the theoretical predictions and the experimental observations.