A series of caprolactam ionic liquids(ILs) containing incorporated halide anions were synthesized.Their physical properties,such as melting points,heats of fusion and heat capacities,were measured by differential scan...A series of caprolactam ionic liquids(ILs) containing incorporated halide anions were synthesized.Their physical properties,such as melting points,heats of fusion and heat capacities,were measured by differential scanning calorimeter(DSC).The results indicate that these ionic liquids exhibit proper melting points,high value of heats of fusion,and satisfying heat capacities which are suitable for thermal energy storage applications.展开更多
The paper is devoted to new, experimentally registered thermo physical problems of high temperature applied external and internal aerodynamics which is defined first of all by intensive interaction of the gaseous medi...The paper is devoted to new, experimentally registered thermo physical problems of high temperature applied external and internal aerodynamics which is defined first of all by intensive interaction of the gaseous media and thermal radiation. The first report section analyses basic complexities of designing high temperature air breathing engines related to origin of so-called "unexpected" heat of working process. The next parts of the report consider physical, chemical and plasma features of aerodynamics of reentry space blunt bodies and meteors with specified account of thermal radiation influence. Our solutions are based on the classical Dark Matter-Energy simulation. We present special experimental data for Dark Matter pressure registration on the earth conditions.展开更多
In this paper,the behavior of a salt-gradient solar pond with the square cross-section has been studied experimentally and numerically.A small-scale solar pond were designed and built to provide quantitative data.A tw...In this paper,the behavior of a salt-gradient solar pond with the square cross-section has been studied experimentally and numerically.A small-scale solar pond were designed and built to provide quantitative data.A two-dimensional,transient heat and mass transfer model has been solved numerically by using finite-control-volume method.In this study,all the thermo-physical properties are variable as the function of temperature and salt concentration.Numerical results as obtained for the experimental pond have been satisfactorily compared and validated against measured data.Furthermore,the wall shading effect has been elaborated to improve the agreement between two sets of results.The temperature of the storage zone is predicted well by the model.It also can be observed that the initial concentration profile is preserved with time.The stability of the pond in time has been investigated in order to distinguish the critical zones.Finally,the application of an energy analysis gives an efficiency of about 12%for the pond.展开更多
In this paper, considering the different elastic properties in the attached head and the free head, we propose a physical model, in which the free head undergoes a diffusive search in an entropic spring potential form...In this paper, considering the different elastic properties in the attached head and the free head, we propose a physical model, in which the free head undergoes a diffusive search in an entropic spring potential formed by undocking the neck linker, and there are asymmetric conformational changes in the attached head formed by docking the neck linker to support the load force and bias the diffusive search to the forward direction. By performing the thermodynamic analysis, we obtain the free energy difference between forward and backward binding sites. And using the Fokker-Planck equation with two absorbing boundaries, we obtain the dependence of the ratio of forward to backward steps on the backward force. Also, within the Michaelis-Menten model, we investigate the dependence of the velocity-load relationship on the effective length of the junction between the two heads. The results show that our model can provide a physical understanding for the processive movement of kinesin.展开更多
Direct extrapolation of the strong interaction between quarks in pure perturbative calculation has a problem of thermodynamic inconsistency. A new term determined by thermodynamic consistency requirement could resolve...Direct extrapolation of the strong interaction between quarks in pure perturbative calculation has a problem of thermodynamic inconsistency. A new term determined by thermodynamic consistency requirement could resolve it. This new term plays an important role at lower density in describing the equation of state of quark matter, while it is negligible at high density. Accordingly, the density behavior of the sotmd velocity becomes more reasonable, and the maximum mass of quark stars can be as large as two times the solar mass.展开更多
First-principles calculations,which are based on the plane-wave pseudopotential approach to density functional perturbation theory within the local density approximation,have been performed to investigate the structur...First-principles calculations,which are based on the plane-wave pseudopotential approach to density functional perturbation theory within the local density approximation,have been performed to investigate the structural,lattice dynamical and thermodynamic properties of zinc blende(B3) structure magnesium chalcogenides:MgS,MgSe and MgTe.The results of ground state parameters and phonon dispersion are compared and agree well with the experimental data available and other calculations.We obtain the change of Born effective charge and LO-TO splitting under hydrostatic pressure.Finally,by the calculations of phonon frequencies,some thermodynamic properties such as the entropy,heat capacity,internal energy,and free energy are also successfully obtained.展开更多
基金Supported by the National Natural Science Foundation of China (21176010, 20706005).
文摘A series of caprolactam ionic liquids(ILs) containing incorporated halide anions were synthesized.Their physical properties,such as melting points,heats of fusion and heat capacities,were measured by differential scanning calorimeter(DSC).The results indicate that these ionic liquids exhibit proper melting points,high value of heats of fusion,and satisfying heat capacities which are suitable for thermal energy storage applications.
文摘The paper is devoted to new, experimentally registered thermo physical problems of high temperature applied external and internal aerodynamics which is defined first of all by intensive interaction of the gaseous media and thermal radiation. The first report section analyses basic complexities of designing high temperature air breathing engines related to origin of so-called "unexpected" heat of working process. The next parts of the report consider physical, chemical and plasma features of aerodynamics of reentry space blunt bodies and meteors with specified account of thermal radiation influence. Our solutions are based on the classical Dark Matter-Energy simulation. We present special experimental data for Dark Matter pressure registration on the earth conditions.
文摘In this paper,the behavior of a salt-gradient solar pond with the square cross-section has been studied experimentally and numerically.A small-scale solar pond were designed and built to provide quantitative data.A two-dimensional,transient heat and mass transfer model has been solved numerically by using finite-control-volume method.In this study,all the thermo-physical properties are variable as the function of temperature and salt concentration.Numerical results as obtained for the experimental pond have been satisfactorily compared and validated against measured data.Furthermore,the wall shading effect has been elaborated to improve the agreement between two sets of results.The temperature of the storage zone is predicted well by the model.It also can be observed that the initial concentration profile is preserved with time.The stability of the pond in time has been investigated in order to distinguish the critical zones.Finally,the application of an energy analysis gives an efficiency of about 12%for the pond.
文摘In this paper, considering the different elastic properties in the attached head and the free head, we propose a physical model, in which the free head undergoes a diffusive search in an entropic spring potential formed by undocking the neck linker, and there are asymmetric conformational changes in the attached head formed by docking the neck linker to support the load force and bias the diffusive search to the forward direction. By performing the thermodynamic analysis, we obtain the free energy difference between forward and backward binding sites. And using the Fokker-Planck equation with two absorbing boundaries, we obtain the dependence of the ratio of forward to backward steps on the backward force. Also, within the Michaelis-Menten model, we investigate the dependence of the velocity-load relationship on the effective length of the junction between the two heads. The results show that our model can provide a physical understanding for the processive movement of kinesin.
基金supported by the National Natural Science Foundation of China(Grant Nos.11135011 and 11475110)the Key Project from Chinese Academy of Sciences(Grant No.KJCX3-SYW-N2)
文摘Direct extrapolation of the strong interaction between quarks in pure perturbative calculation has a problem of thermodynamic inconsistency. A new term determined by thermodynamic consistency requirement could resolve it. This new term plays an important role at lower density in describing the equation of state of quark matter, while it is negligible at high density. Accordingly, the density behavior of the sotmd velocity becomes more reasonable, and the maximum mass of quark stars can be as large as two times the solar mass.
基金Supported by Education Department Foundation of Liaoning Province of China under Grant Nos. 201064145,2010397Education Science Foundation of Liaoning of China under Grant No. 201102166
文摘First-principles calculations,which are based on the plane-wave pseudopotential approach to density functional perturbation theory within the local density approximation,have been performed to investigate the structural,lattice dynamical and thermodynamic properties of zinc blende(B3) structure magnesium chalcogenides:MgS,MgSe and MgTe.The results of ground state parameters and phonon dispersion are compared and agree well with the experimental data available and other calculations.We obtain the change of Born effective charge and LO-TO splitting under hydrostatic pressure.Finally,by the calculations of phonon frequencies,some thermodynamic properties such as the entropy,heat capacity,internal energy,and free energy are also successfully obtained.