The thermal stability, phase transformation, surface morphology, pore size distribution and permeation of the defect-free silica-zirconia membrane were investigated by using X-ray diffraction （XRD）, atomic force mic...The thermal stability, phase transformation, surface morphology, pore size distribution and permeation of the defect-free silica-zirconia membrane were investigated by using X-ray diffraction （XRD）, atomic force microscopy （AFM）, gas adsorption analyzer （BET）, and gas permeation apparatus, respectively. Using silica as the stabilizing agent, the defect-free membrane was much more stable than pure zirconia. The crystal transformation of zirconia in the silica-stabilized membrane could be prohibited by the interaction between silica and zireonia. ZrO2 crystals were kept tetragonal below 900℃, the size of which did not change with temperature between 700℃ and 900℃. It was further verified by the AFM observation, pore size analysis and permeation study. This thermal stability makes the silica-zirconia membrane a good choice as the intermediate layer for zeolite and Pd-based membranes.展开更多
In order to explain the oscillation heat transfer dynamics of closed loop oscillation heat pipe (CLOHP) with two liquid slugs,analysis on the forces and heat transfer process of the partial gas-liquid phase system inv...In order to explain the oscillation heat transfer dynamics of closed loop oscillation heat pipe (CLOHP) with two liquid slugs,analysis on the forces and heat transfer process of the partial gas-liquid phase system involving multiple parameters was carried out,and a new type oscillation heat transfer dynamic model of the CLOHP was set up based on conservation laws of mass,momentum and energy.Application results indicate that its oscillation heat transfer dynamics features depend largely on the filling rate,pipe diameter and difference in temperature.Besides,oscillation intensity and transfer performance can be improved to a large extent by increasing the temperature difference properly and enlarging the pipe diameter within a certain range under a certain filling rate.展开更多
基金Supported by the National Natural Science Foundation of China (No.20476076).
文摘The thermal stability, phase transformation, surface morphology, pore size distribution and permeation of the defect-free silica-zirconia membrane were investigated by using X-ray diffraction （XRD）, atomic force microscopy （AFM）, gas adsorption analyzer （BET）, and gas permeation apparatus, respectively. Using silica as the stabilizing agent, the defect-free membrane was much more stable than pure zirconia. The crystal transformation of zirconia in the silica-stabilized membrane could be prohibited by the interaction between silica and zireonia. ZrO2 crystals were kept tetragonal below 900℃, the size of which did not change with temperature between 700℃ and 900℃. It was further verified by the AFM observation, pore size analysis and permeation study. This thermal stability makes the silica-zirconia membrane a good choice as the intermediate layer for zeolite and Pd-based membranes.
基金Project(531107040300)supported by the Fundamental Research Funds for the Central Universities in ChinaProject(51176045)supported by the National Natural Science Foundation of China
文摘In order to explain the oscillation heat transfer dynamics of closed loop oscillation heat pipe (CLOHP) with two liquid slugs,analysis on the forces and heat transfer process of the partial gas-liquid phase system involving multiple parameters was carried out,and a new type oscillation heat transfer dynamic model of the CLOHP was set up based on conservation laws of mass,momentum and energy.Application results indicate that its oscillation heat transfer dynamics features depend largely on the filling rate,pipe diameter and difference in temperature.Besides,oscillation intensity and transfer performance can be improved to a large extent by increasing the temperature difference properly and enlarging the pipe diameter within a certain range under a certain filling rate.
