Abstract Using visual experimental apparatus, one system (T40, 1×10^-3 mol/L, nonadded with coal) and another system (T40, 2×10^-3 mol/L, added with coal) were experimented with for three times and two t...Abstract Using visual experimental apparatus, one system (T40, 1×10^-3 mol/L, nonadded with coal) and another system (T40, 2×10^-3 mol/L, added with coal) were experimented with for three times and two times, respectively. Five groups of P-T experimental parameters were obtained using the data logger system and analyzed combined with the video information of the experiments. Major conclustions show that the induction time is shortened by 10-20 times in the experimental system containing residual pentahedral ring structures; "memory effect" can accelerate the dynamic progress and improve the thermodynamic conditions of gas hydrate formation.展开更多
The present work is concerned with determining the viscosity,diffusion,thermal diffusion factor and thermal conductivity of five equimolar binary gas mixtures including:CF4-He,CF4-Ne,CF4-Ar,CF4-Kr,CF4-Xe from the prin...The present work is concerned with determining the viscosity,diffusion,thermal diffusion factor and thermal conductivity of five equimolar binary gas mixtures including:CF4-He,CF4-Ne,CF4-Ar,CF4-Kr,CF4-Xe from the principle of corresponding states of viscosity by the inversion technique.The Lennard-Jones (12-6) model potential is used as the initial model potential.The calculated interaction potential energies obtained from the inversion procedure is employed to reproduce the viscosities,diffusions,thermal diffusion factors,and thermal conductivities.The accuracies of the calculated viscosity and diffusion coefficients were 1% and 4%,respectively.展开更多
文摘Abstract Using visual experimental apparatus, one system (T40, 1×10^-3 mol/L, nonadded with coal) and another system (T40, 2×10^-3 mol/L, added with coal) were experimented with for three times and two times, respectively. Five groups of P-T experimental parameters were obtained using the data logger system and analyzed combined with the video information of the experiments. Major conclustions show that the induction time is shortened by 10-20 times in the experimental system containing residual pentahedral ring structures; "memory effect" can accelerate the dynamic progress and improve the thermodynamic conditions of gas hydrate formation.
基金Research Committees of Shiraz University and Shiraz University of Technology for supporting this project and making computer facilities available
文摘The present work is concerned with determining the viscosity,diffusion,thermal diffusion factor and thermal conductivity of five equimolar binary gas mixtures including:CF4-He,CF4-Ne,CF4-Ar,CF4-Kr,CF4-Xe from the principle of corresponding states of viscosity by the inversion technique.The Lennard-Jones (12-6) model potential is used as the initial model potential.The calculated interaction potential energies obtained from the inversion procedure is employed to reproduce the viscosities,diffusions,thermal diffusion factors,and thermal conductivities.The accuracies of the calculated viscosity and diffusion coefficients were 1% and 4%,respectively.