The present seal form is restricted by itself, so pilot study in new-style seal-filling hydrogel by choosing acrylamide as absorb-water performance monomer with binary solution hybrid method was carried out. The feasi...The present seal form is restricted by itself, so pilot study in new-style seal-filling hydrogel by choosing acrylamide as absorb-water performance monomer with binary solution hybrid method was carried out. The feasibility of using new-style seal-filling hydrogel to build hermetic wall rapidly was indicated from results. Gelling time of seal-filling hydrogel was influenced by gelling temperature, initiator concentration and accelerator content. Gelling time decreased by 1/3~1/2 times as gelling temperature increased by each 10℃. Gelling time was proportional to 1/2 power of initiator concentration, and was linear of accelerator content with one power. Addition, deformation rate of seal-filling hydrogel depended on monomer content, cross linking agent concentration, accelerator content. And staggered change of elastic modulus was come forth, its demar cation points generally appeared at the value of 50% of vertical deformation.展开更多
基金Supported by National Natural Science Foundation(50474019)Specific Science Research Plan in Education of Shaanxi Province of China(05Jk257)
文摘The present seal form is restricted by itself, so pilot study in new-style seal-filling hydrogel by choosing acrylamide as absorb-water performance monomer with binary solution hybrid method was carried out. The feasibility of using new-style seal-filling hydrogel to build hermetic wall rapidly was indicated from results. Gelling time of seal-filling hydrogel was influenced by gelling temperature, initiator concentration and accelerator content. Gelling time decreased by 1/3~1/2 times as gelling temperature increased by each 10℃. Gelling time was proportional to 1/2 power of initiator concentration, and was linear of accelerator content with one power. Addition, deformation rate of seal-filling hydrogel depended on monomer content, cross linking agent concentration, accelerator content. And staggered change of elastic modulus was come forth, its demar cation points generally appeared at the value of 50% of vertical deformation.