The technology that waste activated carbon after extracting gold is regenerated with steam under microwave heating was studied. The influence of the activation temperature, activation duration and steam flow rate on i...The technology that waste activated carbon after extracting gold is regenerated with steam under microwave heating was studied. The influence of the activation temperature, activation duration and steam flow rate on iodine adsorption value and regeneration yield of activated carbon was investigated. The response surface methodology (RSM) technique was utilized to optimize the process conditions. The optimum conditions for the preparation of activated carbon are identified to be activation temperature of 831 ℃, activation duration of 40 min and steam flow rate of 2.67 mL/min. The optimum conditions result in an activated carbon with an iodine number of 1048 mg/g and a yield of 40%, and the BET surface area evaluated using nitrogen adsorption isotherm is 1493 m2/g, with total pore volume of 1.242 cm3/g. And the pore structure of activated carbon regenerated is mainly composed of micropores and a small amount of mesopores.展开更多
Bio-sourced nylon 69,one of promising engineering plastics,has a great potential in developing sustainable technology and various commercial applications.Isothermal and nonisothermal crystallization kinetics of nylon ...Bio-sourced nylon 69,one of promising engineering plastics,has a great potential in developing sustainable technology and various commercial applications.Isothermal and nonisothermal crystallization kinetics of nylon 69 is a base to optimize the process conditions and establish the structure–property correlations for nylon 69,and it is also highly bene ficial for successful applications of nylon products in industry.Isothermal and nonisothermal crystallization kinetics has been investigated by differential scanning calorimetry for nylon 69,bio-sourced even–odd nylon.The isothermal crystallization kinetics has been analyzed by the Avrami equation,the calculated Avrami exponent at various crystallization temperatures falls into the range of 2.28 and 2.86.In addition,the Avrami equation modi fied by Jeziorny and the equation suggested by Mo have been adopted to study the nonisothermal crystallization.The activation energies for isothermal and nonisothermal crystallization have also been determined.The study demonstrates that the crystallization model of nylon 69 might be a twodimensional(circular)growth at both isothermal and nonisothermal crystallization conditions.Furthermore,the value of the crystallization rate parameter(K)decreases signi ficantly but the crystallization half-time(t1/2)increases with the increase of the isothermal crystallization temperature.To nonisothermal crystallization,the crystallization rate increases as the cooling rate increases according to the analysis of Jeziorny's theory.The results of Mo's theory suggest that a faster cooling rate is required to reach a higher relative degree of crystallinity in a unit of time,and crystallization rate decreases when the relative degree of crystallinity increases at nonisothermal crystallization conditions.展开更多
Starch ofavocado seeds can be used as an alternative source of starch because it contains 80.1% starch. Natural starch can be made into a modified starch, for example dextrin. Dextrin can be made by using acid or enzy...Starch ofavocado seeds can be used as an alternative source of starch because it contains 80.1% starch. Natural starch can be made into a modified starch, for example dextrin. Dextrin can be made by using acid or enzyme hydrolysis. The purposes of this research were determine the concentration of hydrochloric acid (HCl), the temperature and heating timein the optimum process of hydrolysis of starch into dextrin and to determine the quality of the resulting product dextrin terms of Indonesian National Standard 01-2593-1992. The methode was used in this research is hydrolisis with hydrochloric acid (HCl). The results processing into starch avocado seed yield is 23.15%. HCl concentration, temperature and heating time significantly affect the value of dextrose equivalent (DE), viscosity and part soluble in cold water. There is interaction between HCl concentration, temperature and heating time on the value of DE, viscosity and part soluble in cold water. Optimum conditions of process was obtained at a concentration of 0.15 N HCl, 30 minutes heating time and heating temperature of 90 ℃. Dextrose equivalent (DE) value is 19.61%. The value of solubility in cold water is 90.19%. Viscosity value is 1.61 ° E. Dextrin is not accordance with the standards of quality parameters Indonesian National Standard 01-2593-1992. Dextrin produced should be applied to non-food industry.展开更多
基金Project(2013AA064003)supported by the National High Technology Research and Development Program of ChinaProject(2012HB008)supported by Young and Middle-aged Academic Technology Leader Backup Talent Cultivation Program in Yunnan Province,China
文摘The technology that waste activated carbon after extracting gold is regenerated with steam under microwave heating was studied. The influence of the activation temperature, activation duration and steam flow rate on iodine adsorption value and regeneration yield of activated carbon was investigated. The response surface methodology (RSM) technique was utilized to optimize the process conditions. The optimum conditions for the preparation of activated carbon are identified to be activation temperature of 831 ℃, activation duration of 40 min and steam flow rate of 2.67 mL/min. The optimum conditions result in an activated carbon with an iodine number of 1048 mg/g and a yield of 40%, and the BET surface area evaluated using nitrogen adsorption isotherm is 1493 m2/g, with total pore volume of 1.242 cm3/g. And the pore structure of activated carbon regenerated is mainly composed of micropores and a small amount of mesopores.
基金Supported by the Natural Science Foundation of Zhejiang Province(LY15B060006)the National Natural Science Foundation of China(21104066)the Zhejiang Province Public Technology Research and Industrial Grant(2012C21078)
文摘Bio-sourced nylon 69,one of promising engineering plastics,has a great potential in developing sustainable technology and various commercial applications.Isothermal and nonisothermal crystallization kinetics of nylon 69 is a base to optimize the process conditions and establish the structure–property correlations for nylon 69,and it is also highly bene ficial for successful applications of nylon products in industry.Isothermal and nonisothermal crystallization kinetics has been investigated by differential scanning calorimetry for nylon 69,bio-sourced even–odd nylon.The isothermal crystallization kinetics has been analyzed by the Avrami equation,the calculated Avrami exponent at various crystallization temperatures falls into the range of 2.28 and 2.86.In addition,the Avrami equation modi fied by Jeziorny and the equation suggested by Mo have been adopted to study the nonisothermal crystallization.The activation energies for isothermal and nonisothermal crystallization have also been determined.The study demonstrates that the crystallization model of nylon 69 might be a twodimensional(circular)growth at both isothermal and nonisothermal crystallization conditions.Furthermore,the value of the crystallization rate parameter(K)decreases signi ficantly but the crystallization half-time(t1/2)increases with the increase of the isothermal crystallization temperature.To nonisothermal crystallization,the crystallization rate increases as the cooling rate increases according to the analysis of Jeziorny's theory.The results of Mo's theory suggest that a faster cooling rate is required to reach a higher relative degree of crystallinity in a unit of time,and crystallization rate decreases when the relative degree of crystallinity increases at nonisothermal crystallization conditions.
文摘Starch ofavocado seeds can be used as an alternative source of starch because it contains 80.1% starch. Natural starch can be made into a modified starch, for example dextrin. Dextrin can be made by using acid or enzyme hydrolysis. The purposes of this research were determine the concentration of hydrochloric acid (HCl), the temperature and heating timein the optimum process of hydrolysis of starch into dextrin and to determine the quality of the resulting product dextrin terms of Indonesian National Standard 01-2593-1992. The methode was used in this research is hydrolisis with hydrochloric acid (HCl). The results processing into starch avocado seed yield is 23.15%. HCl concentration, temperature and heating time significantly affect the value of dextrose equivalent (DE), viscosity and part soluble in cold water. There is interaction between HCl concentration, temperature and heating time on the value of DE, viscosity and part soluble in cold water. Optimum conditions of process was obtained at a concentration of 0.15 N HCl, 30 minutes heating time and heating temperature of 90 ℃. Dextrose equivalent (DE) value is 19.61%. The value of solubility in cold water is 90.19%. Viscosity value is 1.61 ° E. Dextrin is not accordance with the standards of quality parameters Indonesian National Standard 01-2593-1992. Dextrin produced should be applied to non-food industry.