低碱度钢渣的余热处理工艺——块状钢渣综合热闷处理…

采用热激，蒸煮，水浸及加入外加剂等措施，充分利用钢渣余热和钢渣的复杂结构，对钢渣进行裂化，碎化，粉化处理是目前钢渣处理与利用的新方法－块状钢渣综合热闷处理，文中介绍该方法的数据原理，处理步骤，设备及处理后的效益。

硬齿面齿轮精密热滚挤工艺及轮齿变形的研究

以广泛应用于汽车行业及精密机床上的20CrMo渗碳齿轮为例,介绍了一种将热处理、精滚以及淬火等工序组合成单一在线加工工艺的精滚形变热处理工艺方法,并建立了滚挤过程中轮齿的双面啮合受力模型,推导出完整的轮齿变形计算公式.

转炉钢渣不同处理工艺对钢渣性能的影响研究

本文以宝钢转炉钢渣的处理为例,分析转炉渣滚筒法处理工艺、转炉渣热泼处理工艺不同钢渣处理工艺及其技术特点。对不同处理工艺处理的钢渣密度、易磨性、游离氧化钙含量、金属铁含量、化学组成、钢渣活性指数性能的分析。根据钢渣的主要性质、利用途径、利用条件和发展方向,比较各种工艺的优缺点,比较两种转炉钢渣处理的最佳工艺,以期为钢铁企业选择合理的钢渣处理工艺提供一定的指导。

生物质热解产物的应用分析

将生物质资源通过干馏热解工艺处理后,可生成生物质木炭、木醋液、木焦油和木燃气。生物质木炭和木燃气是两种清洁的可再生能源,木醋液和木焦油是两种天然的农用化学品替代物,四种基础产物在许多行业均具有广泛的用途。

Effects of T9I6 thermo-mechanical process on microstructure, mechanical properties and ballistic resistance of 2519A aluminum alloy

The effects of T916 thermo-mechanical process on microstructures, mechanical properties and ballistic resistance of 2519A aluminum alloy were investigated by optical microscopy （OM）, transmission electron microscopy （TEM）, tensile tests and ballistic resistance test. After T916 treatment, the yield strength, tensile strength and elongation rate of 2519A aluminum alloy reach 501 MPa, 540 MPa and 14%, respectively. And the ballistic limit velocity of 2519A-T916 alloy （30 mm in thickness） is 715 rn/s. The microstructure varies near the sidewalls of crater. The interrupted ageing contributes to these excellent properties of the alloy. During T916 process, the precipitation of Guinier Preston （GP） zone is finer and denser during the interrupted ageing, thus resulting in well precipitated strengthening phase.

Thermal Treatment for Decreasing the Acidity of Crude Oil

Highly acidic crude oil is thermally soaked to investigate how the temperature and time involved affect the removal of organic acid in feedstock. Experimental results indicate that thermal treatment is an effective approach to decreasing acidity and the acid removal rate reaches 80%. Temperature is one of the main factors that determine the acid removal reaction. When the temperature ranges from 420oC to 440oC, the acid removal rate increases with the rise of the reaction temperature, but the increase slows down gradually. At the reaction temperature below 440oC, the long reaction time favors the acid removal. The cracking and polymerization of hydrocarbon molecules take place so that the properties of the crude oil change at the same time when the highly acidic crude is thermally treated.

Effect of heat treatment on microstructures and mechanical properties of high vacuum die casting Mg-8Gd-3Y-0.4Zr magnesium alloy

The microstructure, the content of compounds, mechanical properties and fracture behavior of high vacuum die casting Mg-8Gd-3Y-0.4Zr alloy （mass fraction, %） under T4 condition and T6 condition were investigated. The microstructure for the as-cast Mg-8Gd-3Y-0.4Zr alloy mainly consists ofα-Mg and eutectic Mg24（Gd,Y）5 compound. After solution treatment, the eutectic compounds dissolve massively into the Mg matrix. The main composition of solution-treated alloys is supersaturated α-Mg and cuboid-shaped phase. The T4 heat treated samples have increasing cuboidal particles with the increase of heat treatment temperature, which turn out good mechanical properties. The optimum T4 heat treatment for high vacuum die cast Mg-8Gd-3Y-0.4Zr alloy is 475 ℃, 2 h according to microstructure results. The optimum ultimate strength and elongation of solution-treated Mg-8Gd-3Y-0.4Zr alloy are 222.1 MPa and 15.4%, respectively. The tensile fracture mode of the as-cast, and T6 heat treated alloys is transgranular quasi-cleavage fracture.

Effect of heat treatment on microstructure and dimensional stability of ZL114A aluminum alloy

The effects of heat treatment process on microstrucature, micro-yield strength and dynamic dimensional stability of ZL114A aluminum alloy were investigated by optical microscopy （OM）, transmission electron microscopy （TEM）, tensile testing and thermal cycling on-line measuring method. Fine dispersed eutectic Si phases are observed, and long strip eutectic Si and massive primary Si phases decrease in ZL114A alloy after high-temperature and long-time solution treatment, which result in the increase of micro-plastic deformation resistance. With the increasing of aging temperature, aging precipitation behaviour of ZLll4A alloy transforms from precipitation of GP zone and fl＇ phases simultaneously at lower temperature to precipitation of stable Mg2Si phases at higher temperature. Because coherent strengthening is the main strengthen mechanism for micro-plastic deformation, precipitation of stable Mg2Si phases is unfavorable to the improvement of micro-plastic deformation resistance. Micro-yield strength cannot characterize dimensional stability comprehensively, and dynamic dimensional stability under alternative temperature should also be tested cooperatively for better evaluation of dimensional stability.

Comparison of up ladder type and terraced type normalizing heat treatments of heavy cylinder

Because of the mixed grain and coarse grain structure, the long heat treatment cycle and large energy conservation in the heavy cylinder heat treatment process, the up ladder type and terraced type normalizing heat treatment of heavy cylinder after rolling were put forward. The microstructure and mechanical properties of 2.25Cr1Mo0.25 V steel after the up ladder type normalizing, terraced type normalizing and isothermal type normalizing were studied. Experimental results show that： 1） For the grain refinement, the twice terraced type normalizing is better than the up ladder type and isothermal type normalizing, and the average grain size is 18 μm; 2） The yield strength, tensile strength and-30℃ charpy impact energy after twice terraced type normalizing are 681 MPa, 768 MPa and 181 J, respectively, and the mechanical properties are better than those of the up ladder type and isothermal type normalizing; 3） Compared with the isothermal type normalizing, the holding time of terraced type normalizing can be shortened by 30%, which greatly reduces the energy consumption.

COMPARING STUDY OF BLENDING PREHEATING MODIFIED COAL COKING AND STAMPING COKING FOR DONGSHEN COAL

The compaison of the properties of coke of three coking methods is introduced. The mechanical properties and high temperature reactivity of coke bleding preheating modified Dongshen coal are improved obviously than those of normal coke, and achieve or exceed that of stamping coke. This method shows more ability of expending coking coal resources.

Effects of Nucleating Agents on Crystallization of Arc-Molten Slag from Incinerator Fly Ash

Glass-ceramics obtained from the electric arc furnace molten slag of incinerator fly ash was produced by applying nucleation and crystallization through heat treatment process. The effects of nucleating agent （TiO2 and Cr2O3） on the crystallization kinetics and heat treatment schedule of the slag were investigated. The results show that the nucleating agents changed the crystallization phase and morphology of the obtained glass-ceramics. The optimum heat treatment schedule of the glass with TiO2 was determined as nucleation at 952 K for 1.5 h and crystal growth at 1 258 K for 1.5 h, while those values with Cr203 were estimated at 971 K for 2 h and at 1 238 K for 2 h. TiO2 acting as nucleating agent could decrease the activation energy of the slag and shorten the total thermal treatment time in comparison with Cr2O3. The glass-ceramics obtained under the optimum heat treatment condition was environmentfriendly and had remarkable physical/mechanical properties and chemical durability.

Facile Synthesis of 3D Porous Flower-like ZnO Micro/nanostructure Films and Their Photocatalytic Performance

3D porous flower-like ZnO micro/nanostructure films grown on Ti substrates are synthesized via a very facile electrodeposition technique followed by heat treatment process. The ZnO architecture is assembled with ultra thin sheets, which consist of numbers of nanoparticles and pores, and the size of the nanoparticles can be controlled by adjusting the electrodepo- sition time or calcination temperature. It is worth noting that this synthetic method can provide an effective route for other porous metal oxide nanostructure films. Moreover, the photocatalytic performance shows the porous ZnO is an ideal photocatalyst.

Microstructure ＆ texture evolution and magnetic properties of high magnetic-induction 6.5% Si electrical steel thin sheet fabricated by a specially designed rolling route

Electrical steel sheets with 6.5%(mas fraction) Si with good shapes and superior magnetic inductions were successfully produced by a specially designed processing route including ingot casting, hot rolling and warm rolling both with interpass thermal treatment, and final annealing. The sheets were of 0.2 mm and 0.3 mm thick over 140 mm width. A detailed study of the microstructural and textural evolutions from the hot rolling to annealing was carried out by optical microscopy, X-ray diffraction and electron backscattered diffraction. The hot rolled sheet characterized by near-equiaxed grains was dominated by the mixture of <001>//ND fiber(λ-fiber), <110>//RD fiber(α-fiber) and <111>//ND fiber(γ-fiber) textures owing to the partial recrystallization and strain induced boundary migration(SIBM) during the hot rolling interpass thermal treatment. The static recovery and SIBM during the warm rolling interpass thermal treatment result in large and elongated warm rolling grains. The warm rolling texture is dominated by obvious λ, Goss and strong γ-fiber textures. The application of the interpass thermal treatment during hot and warm rolling significantly enhances the impact of SIBM during annealing, which is responsible for the formation of the moderate λ-fiber, some near-λ fiber texture components and the obviously weakened γ-fiber texture in the annealed sheet, leading to a higher magnetic induction compared to the commercially produced 6.5% Si steel by chemical vapor deposition(CVD).

Influence of the Main Technological Variables of Cyclical Mechanic-Thermal Processing on the Strain Hardening of Steel Parts

The main objective of the present work was to determine the influence of the most important technological variables of CMTP （cyclical mechanic-thermal processing） on the strain hardening in the surface layers of steel parts. For this, it was designed a full factorial plan at two levels of five independent variables that include the whole processing in two and three cycles, the cold-forming degree and force during the plastic deformation （burnishing）, and the temperature and time at the given temperature during the aging. Each cycle is composed of plastic deformation at room temperature plus aging. As dependent variables, the degree and penetration depth of strain hardening were evaluated. Based on the appropriately used set of experimental data, it had been fitted an exponential model for each dependent variables and also a two-degree polynomial fitting of in-depth evolution of microhardness profile was obtained. The amount of cycles and the cold-forming degree are the technological variables of CMTP that influence the most on strain hardening, although other variables also are significant. The microhardness profile highlights that during the CMTP, the strain hardening decreases from the outer bound to the transition zone of the surface layers, where it disappears.

Effect of Different Sizes of α Phase on Tensile Properties of Metastable β Titanium Alloy Ti-5.5Cr-5Al-4Mo-3Nb-2Zr

To study the relationship between the microstructure and tensile properties of the novel metastable β titanium alloy Ti-5.5Cr-5Al-4Mo-3Nb-2Zr,a heat treatment process of ABFCA(solid solution in α+βregion with subsequent furnace cooling followed by aging treatment finally)was designed,by which α phases of different sizes can be precipitated in the β matrix.The results show that the microstructure obtained by this heat treatment process is composed of primary α(α_(p))phase,submicro rod-like α(α_(r))phase and secondary α(α_(s))phase.The alloy with multi-scale α phase has an excellent balance between strength and ductility.The elongation is about 18.3% at the ultimate tensile strength of 1125.4 MPa.The relationship between the strength of the alloy and the α phase was established.The strength of the alloy is proportional to the power of‒1/2 of the average spacing and width of α phase.The α_(s) phase with a smaller size and phase spacing can greatly improve the strength of the alloy by hindering dislocation slip.The transmission electron microscope analysis shows that there is a large amount of dislocation accumulation at the α/β interfaces,and many deformation twins are found in the α_(p) phase after tensile deformation.When the dislocation slip is hindered,twins occur at the stress concentration location,and twins can initiate some dislocations that are difficult to slip.Meanwhile,the plastic strain is distributed uniformly among the α_(p),α_(r),α_(s) phases and β matrix,thereby enhancing the ductility of the alloy.

A novel microstructural design and heat treatment technique based on gradient control of carbon partitioning between austenite and martensite for high strength steels

Based on gradient control of carbon partitioning between martensite and austenite during heat treatment of steels,a stepping-quenching-partitioning(S-Q-P) process is developed for high strength steels.The S-Q-P process involves several quenching processes at progressively lower temperatures between martensite-start(Ms) and martensite-finish(Mf) temperatures,each followed by a partitioning treatment at either the initial quenching temperature or above that temperature.A novel microstructure is designed based on the S-Q-P process.Sizes and distributions of retained austenite and high-carbon martensite surrounded by martensite laths can be manipulated by the partitioning duration and temperature,and quenching temperature of the S-Q-P process.Alloying element Si is employed in the S-Q-P steel to suppress formation of carbides and create suitable amount of retained austenite.A steel of 0.39C-1.22Mn-1.12Si-0.23Cr(wt.%) treated by the S-Q-P process is endowed with some special microstructural characteristics:some strips of retained austenite located at edges of martensite blocks with high density of dislocations and between martensite laths,some small blocks of twinned martensites distributed among bundles of the low-carbon martensite lath.The mechanical properties of the medium carbon steel after the S-Q-P process can reach ultimate tensile strength(Rm) of 1240 MPa,total elongation(EI) of 25%,and product of strength and ductility(PSD) of 31.2 GPa% that are much more improved than those after the conventional quenching-tempering(Q-T) and currently prevailing quenching-partitioning(Q-P) treatments.The PSD of the tested steel after the S-Q-P process increases by 67% and 32% as compared with those after the Q-T and Q-P processes,respectively.

Preparation and properties of solution-processed zinc tin oxide films from a new organic precursor

Transparent,smooth and dense zinc tin oxide (ZTO) thin films have been successfully produced by using a new precursor solution,zinc acetate and tin(II) 2-ethylhexanoate mixed with 2-ethanolamine in methoxyethanol.The ZTO films have been prepared by spin-coating,followed by thermal treatment in oxygen atmosphere.The morphology,composition,crystallinity and band gap energy (Eg) of the ZTO thin films have been characterized by Atomic Force Microscopy (AFM),Atomic Emission Spectrometry (AES),X-ray Diffraction (XRD) and UV-vis spectrophotometry.The conductivity of ZTO is about 9.8×10-9 S/cm,as estimated from the current-voltage (I-V) curve.The effect of the thermal treatment process on the morphology of ZTO thin films is also discussed.

One-pot synthesis of Li_3VO_4@C nanofibers by electrospinning with enhanced electrochemical performance for lithium-ion batteries

Electrospinning is firstly used to one-pot synthesis of Li3VO4@C nanofibers in a large scale. Although with the presence of organic sources in synthesis process, the pure phase Li3VO4 with superior nanofibrous morphology is still successfully obtained through adjusting different heat treatment processes and different vanadium sources. The prepared Li3VO4@C nanofibers exhibit a unique structure in which nanosized Li3VO4 particles are uniformly embedded in amorphous carbon matrix. Compared with LiBVO4/C powder, Li3VO4@C nanofibers display enhanced reversible capacity of 451 mAhg^-1 at 40mAg^-1 with an increased initial coulombic efficiency of 82.3%, and the capacity can remain at 394 mAh g ^-1 after 100 cycles. This superior electrochemical performance can be attributed to its unique structure which ensures a high reactivity by nanosized Li3VO4, more stable electrode/electrolyte interface by carbon encapsulation, improved electronic conductivity and buffered volume changes by flexible carbon matrix. The electrospinning technology provides an effective method to obtain high performance Li3VO4 as a promising anode material for lithium-ion batteries.

Wrinkle-free graphene with spatially uniform electrical properties grown on hot-pressed copper

The chemical vapor deposition （CVD） of graphene on Cu substrates enables the fabrication of large-area monolayer graphene on desired substrates. However, during the transfer of the synthesized graphene, topographic defects are unavoidably formed along the Cu grain boundaries, degrading the electrical properties of graphene and increasing the device-to-device variability. Here, we introduce a method of hot-pressing as a surface pre-treatment to improve the thermal stability of Cu thin film for the suppression of grain boundary grooving. The flattened Cu thin film maintains its smooth surface even after the subsequent high temperature CVD process necessary for graphene growth, and the formation of graphene without wrinkles is realized. Graphene field effect transistors （FETs） fabricated using the graphene synthesized on hot-pressed Cu thin film exhibit superior field effect mobility and significantly reduced device-to-device variation.