Infrared window in hypersonic missile usually suffers complex aerodynamic force/heat during high-speed flight.A finite element method was adopted to simulate the thermal and stress response of microscale functional fi...Infrared window in hypersonic missile usually suffers complex aerodynamic force/heat during high-speed flight.A finite element method was adopted to simulate the thermal and stress response of microscale functional film for infrared window under different aerodynamic heats/forces conditions.Temperature and stress distribution were obtained with different heat fluxes.There is almost constant stress distribution along the film thickness except a sudden decrease near the substrate.The maximum stresses are located at the points which are 0.3 mm away from the edges.Different film materials result in different stress values.The temperature and stress in ZrN are larger than those in Y2O3.Besides the numerical simulation,an oxygen propane flame jet impingement test was performed to investigate thermal shock failure of the infrared window.Some place of the window surface has spots damage and some place has line crack damage after thermal shock.展开更多
A modified MK model combined with ductile fracture criterion(DFC-MK model) is proposed to compute the forming limit diagrams(FLDs) of 5A06-O aluminum alloy sheet at different temperatures.The material constant(C...A modified MK model combined with ductile fracture criterion(DFC-MK model) is proposed to compute the forming limit diagrams(FLDs) of 5A06-O aluminum alloy sheet at different temperatures.The material constant(C) of ductile fracture criterion and initial thickness imperfection parameter(f0) at various temperatures are determined by using a new computing method based on wide sheet bending test.The FLDs at 20 and 200 °C are calculated through the DFC-MK model.The DFC-MK model,which includes the influence of through-thickness normal stress,is written into the subroutine VUMAT embedded in Abaqus/ Explicit.The cylindrical cup hydroforming tests are carried out to verify the model.The results show that compared with experimental observations,the predicted FLDs based on DFC-MK model are more accurate than the conventional MK model;the errors between the simulations and experiments in warm hydroforming are 8.23% at 20 °C and 9.24% at 200 °C,which verify the effectiveness of the proposed model.展开更多
To study the influence of roll casting process parameters on temperature and thermal-stress fields for the AZ31 magnesium alloy sheets,three-dimensional geometric and 3D finite element models for roll casting were est...To study the influence of roll casting process parameters on temperature and thermal-stress fields for the AZ31 magnesium alloy sheets,three-dimensional geometric and 3D finite element models for roll casting were established based on the symmetry of roll casting by ANSYS software.Meshing method and smart-sizing algorithm were used to divide finite element mesh in ANSYS software.A series of researches on the temperature and stress distributions during solidification process with different process parameters were done by 3D finite element method.The temperatures of both the liquid-solid two-phase zone and liquid phase zone were elevated with increasing pouring temperature.With the heat transfer coefficient increasing,the two-phase region for liquid-solid becomes smaller.With the pouring temperature increasing and the increase of casting speed,the length of two-phase zone rises.The optimized of process parameters(casting speed 2 m/min,pouring temperature 640 ℃ and heat transfer coefficient 15 kW/(m2·℃) with the water pouring at roller exit was used to produce magnesium alloy AZ31 sheet,and equiaxed grains with the average grain size of 50 μm were achieved after roll casting.The simulation results give better understanding of the temperature variation in phase transformation zone and the formation mechanism of hot cracks in plates during roll casting and help to design the optimized process parameters of roll casting for Mg alloy.展开更多
The bending problem of a functionally graded anisotropic cantilever beam subjected to thermal and uniformly dis-tributed load is investigated,with material parameters being arbitrary functions of the thickness coordin...The bending problem of a functionally graded anisotropic cantilever beam subjected to thermal and uniformly dis-tributed load is investigated,with material parameters being arbitrary functions of the thickness coordinate. The heat conduction problem is treated as a 1D problem through the thickness. Based on the elementary formulations for plane stress problem,the stress function is assumed to be in the form of polynomial of the longitudinal coordinate variable,from which the stresses can be derived. The stress function is then determined completely with the compatibility equation and boundary conditions. A practical example is presented to show the application of the method.展开更多
Thermal analysis and thermal diagnose are important for small power connector especially in electronic devices since their structure is usually compact. In this paper thermal behavior of small power connector was inve...Thermal analysis and thermal diagnose are important for small power connector especially in electronic devices since their structure is usually compact. In this paper thermal behavior of small power connector was investigated. It was found that the contact resistance increased due to the Joule beating, and that increased contact resistance produced more Joule heating; this mutual action causes the connector to lose efficiency. The thermal distribution in the connector was analyzed using finite element method (FEM). The failure mechanism is discussed. It provides basis for improving the structure. The conclusion was verified by experimental results.展开更多
When species in the solution undergo multiple chemical reactions, the solution may be treated as a solution of all species actually present or as a hypothetical solution composed of elemental species. Based on the fu...When species in the solution undergo multiple chemical reactions, the solution may be treated as a solution of all species actually present or as a hypothetical solution composed of elemental species. Based on the fundamental thermodynamic principle, the relationships of mole numbers, molar fractions, thermodynamic properties, partial molar properties, potential and fugacity between the hypothetical solution of elemental species and the equilibrated solution of actual species were derived. The hypothetical elemental solution provides a way of reducing the dimensionality of problem, simplifying the analysis and visualizing the phase behavior.展开更多
In this study,the effect of influencing parameters on the stress distribution around a polygonal cutout within a laminated composite under uniform heat flux was analytically examined.The analytical method was develope...In this study,the effect of influencing parameters on the stress distribution around a polygonal cutout within a laminated composite under uniform heat flux was analytically examined.The analytical method was developed based on the classical laminated plate theory and two-dimensional thermo-elastic method.A mapping function was employed to extend the solution of a perforated symmetric laminate with a circular cutout to the solution of polygonal cutouts.The effect of significant parameters such as the cutout angular position,bluntness and aspect ratio,the heat flux angle and the laminate stacking sequence in symmetric composite laminate containing triangular,square and pentagonal cutouts was studied.The Neumann boundary condition was used at the edges of the thermally insulated polygonal cutout.The laminate was made of graphite/epoxy(AS/3501) material with two different stacking sequences of [30/45]sand[30/0/-30]_(s).The analytical solutions were well validated against finite element results.展开更多
A chemical process may involve multiple adiabatic electronic states, and non-adiabatic couplings play an important role in the reaction mechanism. In this work, the effect of non-adiabatic couplings in the H+MgH;→Mg;...A chemical process may involve multiple adiabatic electronic states, and non-adiabatic couplings play an important role in the reaction mechanism. In this work, the effect of non-adiabatic couplings in the H+MgH;→Mg;+H;reaction are studied using the time-dependent wave packet method and trajectory surface hopping method. The calculated results show that the reaction follows a direct abstraction process when the non-adiabatic couplings are neglected. However, when non-adiabatic couplings are included in the calculations, a longlived excited state complex(MgH_(2)+)*can be formed during the reaction. These direct and complex-forming reaction pathways are revealed by trajectory surface hopping calculations.The non-adiabatic couplings induced complex-forming mechanism not only increases the reactivity but also has significant effect on the product vibrational state distribution.展开更多
Based on the construction property of rolled compacted concrete, three-dimensional finite element relocating mesh method was developed in simulating construction process and computing temperature and stress field. Usi...Based on the construction property of rolled compacted concrete, three-dimensional finite element relocating mesh method was developed in simulating construction process and computing temperature and stress field. Using this method, the temperature and the thermal stress fields developed in the RCC gravity dam of the Longtan project with or without a longitudinal joint during construction and operation are calculated so as to simulate the construction process. The computation results show that the value of the thermal stresses developed in the dam even, without any longitudinal joint, could meet the design criteria provided the placement temperature is adequately controlled.展开更多
Finite Element Method is used in this article to analyze the stress of CR superferric magnet.Magnetic force and the stress caused by this force are calculated.The thermal stress and strain of the coil caused by coolin...Finite Element Method is used in this article to analyze the stress of CR superferric magnet.Magnetic force and the stress caused by this force are calculated.The thermal stress and strain of the coil caused by cooling down is also analyzed.The result will be taken as a check for the design of the coil and coilcase,and also as a reference for the optimization of further design and quench protection.展开更多
Water-soluble gelatin-PbS bionanocomposites (BNCs) were synthesized via a facile one-pot chemical reaction method at pH 7.40. The samples were characterized by transmission electron microscopy (TEM), X-ray diffrac...Water-soluble gelatin-PbS bionanocomposites (BNCs) were synthesized via a facile one-pot chemical reaction method at pH 7.40. The samples were characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD), UV-vis absorption spectra (UV-vis), Fourier transform infrared spectra (FT-IR) and circular dichroism (CD). FT-IR data were used to envis- age the binding of PbS particles with oxygen atoms of carbonyl groups of gelatin molecule. The possible integration mechanism between gelatin and PbS was discussed in detail. The effect of Pb2+ and PbS on the conformations of gelatin has also been analyzed by means of UV-vis, CD and FT-IR spectra, resulting in less c^-helix content and more open structures ([3-sheet, r-turn, or expanded). A new formula to calculate the association constant was proposed according to the relationship between the absorbance of gelatin-PbS BNCs and the free concentration of PbS, and apparent association constants K (298/303/308 K: 3.11/2.00/1.60 × 10^6 tool/L) at three different temperatures were calculated based on this formula. Thermodynamic parameters such as AG^θ, △Hθ and △S^θ were also determined. The results of the thermodynamic investigations indicated that the reaction was spontaneous (AG^θ 〈 0), and enthalpy-driven (△H^8 〈 0).展开更多
The properties of dissolution in different solvents,the specific heat capacity and thermal decomposition process under the non-isothermal conditions for energetic triazole ionic salts 1,2,4-triazolium nitrate(1a),1,2,...The properties of dissolution in different solvents,the specific heat capacity and thermal decomposition process under the non-isothermal conditions for energetic triazole ionic salts 1,2,4-triazolium nitrate(1a),1,2,3-triazolium nitrate(1b),3,4,5triamino-1,2,4-triazolium nitrate(2a),3,4,5-triamino-1,2,4-triazolium dinitramide(2b)were precisely measured using a Calvet Microcalorimeter.The thermochemical equation,differential enthalpies of dissolution(△difH m ),standard molar enthalpies of dissolution(△difH m ),apparent activation energy(E),pre-exponential constant(A),kinetic equation,linear relationship of specific heat capacity with temperature over the temperature range from 283 to 353 K,standard molar heat capacity(C p,m)and enthalpy,entropy and Gibbs free energy at 283–353 K,taking 298.15 K as the benchmark for 1a,1b,2a and 2b were obtained with treating experimental data and theoretical calculation method.The kinetic and thermodynamic parameters of thermal decomposition reaction,critical temperature of thermal explosion(Tb),self-accelerating decomposition temperature(TSADT)and adiabatic time-to-explosion(t)of 1a,1b,2a and 2b were calculated.Their heat-resistance abilities were evaluated.Information was obtained on the relation between molecular structures and properties of 1a,1b,2a and 2b.展开更多
The human head is one of the most sensitive parts of human body due to the fact that it contains brain. Any abnormality in the functioning of brain may disturb the entire system. One of the disturbing factors of brain...The human head is one of the most sensitive parts of human body due to the fact that it contains brain. Any abnormality in the functioning of brain may disturb the entire system. One of the disturbing factors of brain is thermal stress. Thus, it is imperative to study the effects of thermal stress on human head at various environmental conditions. For the thermoregulation process, the human head is considered to be a structure of four layers viz.; brain, cerebrospinal fluid (CSF), skull and scalp. A mathematical model has been formulated to estimate the variation of temperature at these layers. The model is based on radial form of bio-heat equation with the appropriate boundary conditions and has been solved by variational finite element method. The rate of metabolic heat gen- eration and thermal conductivity in this study have been assumed to be heterogeneous. The results were compared with the experimental studies for their coincidence and it has been observed theoretically and experimentally that the human head has greater resistance to compete with the thermal stress up to large extent.展开更多
The three-dimensional inverse transient thermoelastic problem for a thin rectangular object is considered within the context of the theory of generalized thermoelasticity. The upper surface of the rectangular object o...The three-dimensional inverse transient thermoelastic problem for a thin rectangular object is considered within the context of the theory of generalized thermoelasticity. The upper surface of the rectangular object occupying the space D: -a〈xSa; -b〈_y〈b; 0〈z〈h; with the known boundary conditions. Laplace and Finite Marchi-Fasulo transform techniques are used to determine the unknown temperature, temperature distribution, displacement and thermal stresses on upper plane surface of a thin rectangular object. The distributions of the considered physical variables are obtained and represented graphically.展开更多
基金Projects (51222205,51372053) supported by the National Natural Science Foundation of ChinaProject (JC201305) supported by Heilongjiang Provincial Science Fund for Distinguished Young Scholars,ChinaProject (20112302110036) supported by Ph.D. Programs Foundation of Ministry of Education of China
文摘Infrared window in hypersonic missile usually suffers complex aerodynamic force/heat during high-speed flight.A finite element method was adopted to simulate the thermal and stress response of microscale functional film for infrared window under different aerodynamic heats/forces conditions.Temperature and stress distribution were obtained with different heat fluxes.There is almost constant stress distribution along the film thickness except a sudden decrease near the substrate.The maximum stresses are located at the points which are 0.3 mm away from the edges.Different film materials result in different stress values.The temperature and stress in ZrN are larger than those in Y2O3.Besides the numerical simulation,an oxygen propane flame jet impingement test was performed to investigate thermal shock failure of the infrared window.Some place of the window surface has spots damage and some place has line crack damage after thermal shock.
基金Project(51175024)supported by the National Natural Science Foundation of China
文摘A modified MK model combined with ductile fracture criterion(DFC-MK model) is proposed to compute the forming limit diagrams(FLDs) of 5A06-O aluminum alloy sheet at different temperatures.The material constant(C) of ductile fracture criterion and initial thickness imperfection parameter(f0) at various temperatures are determined by using a new computing method based on wide sheet bending test.The FLDs at 20 and 200 °C are calculated through the DFC-MK model.The DFC-MK model,which includes the influence of through-thickness normal stress,is written into the subroutine VUMAT embedded in Abaqus/ Explicit.The cylindrical cup hydroforming tests are carried out to verify the model.The results show that compared with experimental observations,the predicted FLDs based on DFC-MK model are more accurate than the conventional MK model;the errors between the simulations and experiments in warm hydroforming are 8.23% at 20 °C and 9.24% at 200 °C,which verify the effectiveness of the proposed model.
基金Project(CSTC 2010BB4301) supported by Natural Science Foundation Project of Chongqing,ChinaProject supported by the Open Fund for Key Laboratory of Manufacture and Test Techniques for Automobile Parts of Ministry of Education Chongqing University of Technology,2003,China
文摘To study the influence of roll casting process parameters on temperature and thermal-stress fields for the AZ31 magnesium alloy sheets,three-dimensional geometric and 3D finite element models for roll casting were established based on the symmetry of roll casting by ANSYS software.Meshing method and smart-sizing algorithm were used to divide finite element mesh in ANSYS software.A series of researches on the temperature and stress distributions during solidification process with different process parameters were done by 3D finite element method.The temperatures of both the liquid-solid two-phase zone and liquid phase zone were elevated with increasing pouring temperature.With the heat transfer coefficient increasing,the two-phase region for liquid-solid becomes smaller.With the pouring temperature increasing and the increase of casting speed,the length of two-phase zone rises.The optimized of process parameters(casting speed 2 m/min,pouring temperature 640 ℃ and heat transfer coefficient 15 kW/(m2·℃) with the water pouring at roller exit was used to produce magnesium alloy AZ31 sheet,and equiaxed grains with the average grain size of 50 μm were achieved after roll casting.The simulation results give better understanding of the temperature variation in phase transformation zone and the formation mechanism of hot cracks in plates during roll casting and help to design the optimized process parameters of roll casting for Mg alloy.
基金Project supported by the National Natural Science Foundation of China (Nos. 10472102 and 1043203)the Foundation of Ningbo University (No. 2005014), China
文摘The bending problem of a functionally graded anisotropic cantilever beam subjected to thermal and uniformly dis-tributed load is investigated,with material parameters being arbitrary functions of the thickness coordinate. The heat conduction problem is treated as a 1D problem through the thickness. Based on the elementary formulations for plane stress problem,the stress function is assumed to be in the form of polynomial of the longitudinal coordinate variable,from which the stresses can be derived. The stress function is then determined completely with the compatibility equation and boundary conditions. A practical example is presented to show the application of the method.
文摘Thermal analysis and thermal diagnose are important for small power connector especially in electronic devices since their structure is usually compact. In this paper thermal behavior of small power connector was investigated. It was found that the contact resistance increased due to the Joule beating, and that increased contact resistance produced more Joule heating; this mutual action causes the connector to lose efficiency. The thermal distribution in the connector was analyzed using finite element method (FEM). The failure mechanism is discussed. It provides basis for improving the structure. The conclusion was verified by experimental results.
基金Supported by the National Natural Science Foundation of China (No. 29976035) and the Natural Science Foundation of Zhejiang and Fujian Province.
文摘When species in the solution undergo multiple chemical reactions, the solution may be treated as a solution of all species actually present or as a hypothetical solution composed of elemental species. Based on the fundamental thermodynamic principle, the relationships of mole numbers, molar fractions, thermodynamic properties, partial molar properties, potential and fugacity between the hypothetical solution of elemental species and the equilibrated solution of actual species were derived. The hypothetical elemental solution provides a way of reducing the dimensionality of problem, simplifying the analysis and visualizing the phase behavior.
文摘In this study,the effect of influencing parameters on the stress distribution around a polygonal cutout within a laminated composite under uniform heat flux was analytically examined.The analytical method was developed based on the classical laminated plate theory and two-dimensional thermo-elastic method.A mapping function was employed to extend the solution of a perforated symmetric laminate with a circular cutout to the solution of polygonal cutouts.The effect of significant parameters such as the cutout angular position,bluntness and aspect ratio,the heat flux angle and the laminate stacking sequence in symmetric composite laminate containing triangular,square and pentagonal cutouts was studied.The Neumann boundary condition was used at the edges of the thermally insulated polygonal cutout.The laminate was made of graphite/epoxy(AS/3501) material with two different stacking sequences of [30/45]sand[30/0/-30]_(s).The analytical solutions were well validated against finite element results.
基金supported by the National Natural Science Foundation of China(No.11774043)。
文摘A chemical process may involve multiple adiabatic electronic states, and non-adiabatic couplings play an important role in the reaction mechanism. In this work, the effect of non-adiabatic couplings in the H+MgH;→Mg;+H;reaction are studied using the time-dependent wave packet method and trajectory surface hopping method. The calculated results show that the reaction follows a direct abstraction process when the non-adiabatic couplings are neglected. However, when non-adiabatic couplings are included in the calculations, a longlived excited state complex(MgH_(2)+)*can be formed during the reaction. These direct and complex-forming reaction pathways are revealed by trajectory surface hopping calculations.The non-adiabatic couplings induced complex-forming mechanism not only increases the reactivity but also has significant effect on the product vibrational state distribution.
文摘Based on the construction property of rolled compacted concrete, three-dimensional finite element relocating mesh method was developed in simulating construction process and computing temperature and stress field. Using this method, the temperature and the thermal stress fields developed in the RCC gravity dam of the Longtan project with or without a longitudinal joint during construction and operation are calculated so as to simulate the construction process. The computation results show that the value of the thermal stresses developed in the dam even, without any longitudinal joint, could meet the design criteria provided the placement temperature is adequately controlled.
文摘Finite Element Method is used in this article to analyze the stress of CR superferric magnet.Magnetic force and the stress caused by this force are calculated.The thermal stress and strain of the coil caused by cooling down is also analyzed.The result will be taken as a check for the design of the coil and coilcase,and also as a reference for the optimization of further design and quench protection.
基金supported by the National Natural Science Foundation of China(21067001)Natural Science Foundation of Guangxi Province(0991083)Innovation Project of Guangxi University for Nationalities(gxun-chx2012091)
文摘Water-soluble gelatin-PbS bionanocomposites (BNCs) were synthesized via a facile one-pot chemical reaction method at pH 7.40. The samples were characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD), UV-vis absorption spectra (UV-vis), Fourier transform infrared spectra (FT-IR) and circular dichroism (CD). FT-IR data were used to envis- age the binding of PbS particles with oxygen atoms of carbonyl groups of gelatin molecule. The possible integration mechanism between gelatin and PbS was discussed in detail. The effect of Pb2+ and PbS on the conformations of gelatin has also been analyzed by means of UV-vis, CD and FT-IR spectra, resulting in less c^-helix content and more open structures ([3-sheet, r-turn, or expanded). A new formula to calculate the association constant was proposed according to the relationship between the absorbance of gelatin-PbS BNCs and the free concentration of PbS, and apparent association constants K (298/303/308 K: 3.11/2.00/1.60 × 10^6 tool/L) at three different temperatures were calculated based on this formula. Thermodynamic parameters such as AG^θ, △Hθ and △S^θ were also determined. The results of the thermodynamic investigations indicated that the reaction was spontaneous (AG^θ 〈 0), and enthalpy-driven (△H^8 〈 0).
基金supported by the National Natural Science Foundation of China (20573098)the Science and Technology Foundation of National Key Lab of Science and Technology on Combustion and Explosion in China (9140C3503030805)
文摘The properties of dissolution in different solvents,the specific heat capacity and thermal decomposition process under the non-isothermal conditions for energetic triazole ionic salts 1,2,4-triazolium nitrate(1a),1,2,3-triazolium nitrate(1b),3,4,5triamino-1,2,4-triazolium nitrate(2a),3,4,5-triamino-1,2,4-triazolium dinitramide(2b)were precisely measured using a Calvet Microcalorimeter.The thermochemical equation,differential enthalpies of dissolution(△difH m ),standard molar enthalpies of dissolution(△difH m ),apparent activation energy(E),pre-exponential constant(A),kinetic equation,linear relationship of specific heat capacity with temperature over the temperature range from 283 to 353 K,standard molar heat capacity(C p,m)and enthalpy,entropy and Gibbs free energy at 283–353 K,taking 298.15 K as the benchmark for 1a,1b,2a and 2b were obtained with treating experimental data and theoretical calculation method.The kinetic and thermodynamic parameters of thermal decomposition reaction,critical temperature of thermal explosion(Tb),self-accelerating decomposition temperature(TSADT)and adiabatic time-to-explosion(t)of 1a,1b,2a and 2b were calculated.Their heat-resistance abilities were evaluated.Information was obtained on the relation between molecular structures and properties of 1a,1b,2a and 2b.
文摘The human head is one of the most sensitive parts of human body due to the fact that it contains brain. Any abnormality in the functioning of brain may disturb the entire system. One of the disturbing factors of brain is thermal stress. Thus, it is imperative to study the effects of thermal stress on human head at various environmental conditions. For the thermoregulation process, the human head is considered to be a structure of four layers viz.; brain, cerebrospinal fluid (CSF), skull and scalp. A mathematical model has been formulated to estimate the variation of temperature at these layers. The model is based on radial form of bio-heat equation with the appropriate boundary conditions and has been solved by variational finite element method. The rate of metabolic heat gen- eration and thermal conductivity in this study have been assumed to be heterogeneous. The results were compared with the experimental studies for their coincidence and it has been observed theoretically and experimentally that the human head has greater resistance to compete with the thermal stress up to large extent.
基金University Grant Commission,New Delhi for providing the partial financial assistance under major research project scheme
文摘The three-dimensional inverse transient thermoelastic problem for a thin rectangular object is considered within the context of the theory of generalized thermoelasticity. The upper surface of the rectangular object occupying the space D: -a〈xSa; -b〈_y〈b; 0〈z〈h; with the known boundary conditions. Laplace and Finite Marchi-Fasulo transform techniques are used to determine the unknown temperature, temperature distribution, displacement and thermal stresses on upper plane surface of a thin rectangular object. The distributions of the considered physical variables are obtained and represented graphically.