浅析镀锡铜线热镀法废锡产生的原因及对策

镀锡线随着近几年生产技术的突破及市场需求量越来越大,目前较多铜企业都新上或增加了镀锡线生产线。在镀锡过程中,废锡的产生一直是个困扰企业生产的问题,本次主要探讨废锡产生的原因及如何通过工艺改进来减少废锡的产生。实践表明,通过工艺的改进能够减少废锡的产生,提高其利用率。

Microthermokinetic study of xanthate adsorption on impurity-doped galena

Six kinds of galena with different impurities were synthesized and the effects of impurities on the floatability of galena were investigated. The thermodynamic and kinetic parameters on the galena surface were measured using microcalorimetry, and the adsorption configuration and energy of butyl xanthate on the surfaces of galena with different impurities were simulated by density functional theory. Flotation experiments showed that Ag and Bi significantly promoted the recovery of galena, while Zn, Sb, Mn, and Cu reduced the recovery of the flotation. Microthermokinetic results indicated that the absolute value of xanthate adsorption heat was directly proportional to the flotation recovery of galena. Adsorption heat and reaction rate coefficients of xanthate on galena containing Ag or Bi were larger than those on pure galena, but smaller on galena containing Cu or Sb. Additionally, the relationship between the heat of unsaturated adsorption of xanthate and the adsorption energy of impurity atom on galena surface was investigated.

Modified MK model combined with ductile fracture criterion and its application in warm hydroforming

A modified MK model combined with ductile fracture criterion（DFC-MK model） is proposed to compute the forming limit diagrams（FLDs） of 5A06-O aluminum alloy sheet at different temperatures.The material constant（C） of ductile fracture criterion and initial thickness imperfection parameter（f0） at various temperatures are determined by using a new computing method based on wide sheet bending test.The FLDs at 20 and 200 °C are calculated through the DFC-MK model.The DFC-MK model,which includes the influence of through-thickness normal stress,is written into the subroutine VUMAT embedded in Abaqus/ Explicit.The cylindrical cup hydroforming tests are carried out to verify the model.The results show that compared with experimental observations,the predicted FLDs based on DFC-MK model are more accurate than the conventional MK model;the errors between the simulations and experiments in warm hydroforming are 8.23% at 20 °C and 9.24% at 200 °C,which verify the effectiveness of the proposed model.

Effects of heat treatment on phase contents and mechanical properties of infiltrated B_4C/2024Al composites

The B4C/2024Al composites were successfully produced by pressureless infiltration method, and the effects of heat treatment on phase content and mechanical properties were investigated by X-ray diffraction （XRD）, scanning electron microscopy （SEM） and mechanical properties testing. The results show that phases of BnC/2024Al composites include B4C, Al, Al3BC, AlB2 and Al2Cu. The phase species remain unchanged; however, the phase content of the composites changes significantly after heat treatment at the temperature of 660, 700, 800 or 900 ℃ for 12, 24 or 36 h. It is found that the heat treatment results in not only considerable enhancement in hardness, but also reduction in bending strength of the composites. Heat treatment at 800 ℃ for 36 h does best to hardness of the composites, while at 700 ℃ for 36 h it is the most beneficial to their comprehensive mechanical properties.

Effects of electrolysis process parameters on alumina dissolution and their optimization

The Box–Behnken design and desirability approach were used to investigate and optimize the process parameters for aluminum reduction cells related to alumina dissolution. The bath temperature, alumina content, current and alumina temperature were chosen as the design parameters. The content of cumulative dissolved alumina(CCDA) and the relative deviation from the target content(RDTC) were adopted as the responses. The interactive influence results show that increasing the bath temperature and alumina temperature, as well as decreasing the alumina content, can increase CCDA. Increasing the bath temperature and lowering the current are beneficial for obtaining a more uniform alumina distribution. The optimal operating parameters were determined to be as follows: bath temperature of 958.8 ℃, alumina content of 2.679 wt.%, current of 300 kA and alumina temperature of 200 ℃.

Investigation on temperature field of unidirectional carbon fiber/epoxy composites during drilling process

The phenomenon of heat accumulation and transportation in the composite materials is a very typical and critical issue during drilling process.In this study,a three-dimensional temperature field prediction model is proposed using finite difference method,based on the partly homogenization hypothesis of material,to predict temperature field in the process of drilling unidirectional carbon fiber/epoxy(C/E)composites.According to the drilling feed motion,drilling process is divided into four stages to study the temperature distributing characteristics.The results show that the temperature distribution predicted by numerical study has a good agreement with the experimental results.The temperature increases with increasing the drilling depth,and the burn phenomena is observed due to the heat accumulation,especially at the drill exit.Due to the fiber orientation,an elliptical shape of the temperature field along the direction is found for both numerical and experimental studies of C/E composites drilling process.

Effects of solution treatment on mechanical properties and microstructures of Al-Li-Cu-Mg-Ag alloy

Mechanical properties and microstructures of Al-Li-Cu-Mg-Ag alloy after solution treatments were investigated by means of optical microscopy （OM）, tensile test, hardness measurement and electrical conductivity test, differential scanning calorimetric （DSC）, energy dispersive X-ray （EDX）, scanning electron microscopy （SEM） and transition electron microscopy （TEM）, respectively The results show that both tensile strength and hardness increase first and then decrease with temperature at constant holding time of 30 min with maximum strength and hardness appearing at 520 ℃. Tensile strength, hardness and elongation of samples treated at 520 ℃ for 30 min are 566 MPa （σb）, 512 MPa （σ0.2）, HB 148 and 8.23% （δ）, respectively. There are certain amount of fine T1 （AI2CuLi） phase dispersing among AI substrates according to TEM images. This may result in mixed fracture morphology with trans-granular and inter-granular delamination cracks observed in SEM images.

Identification and analysis based on genetic algorithm for proton exchange membrane fuel cell stack

The temperature of proton exchange membrane fuel cell stack and the stoichiometric oxygen in cathode have relationship with the performance and life span of fuel cells closely. The thermal coefficients were taken as important factors affecting the temperature distribution of fuel cells and components. According to the experimental analysis, when the stoichiometric oxygen in cathode is greater than or equal to 1.8, the stack voltage loss is the least. A novel genetic algorithm was developed to identify and optimize the variables in dynamic thermal model of proton exchange membrane fuel cell stack, making the outputs of temperature model approximate to the actual temperature, and ensuring that the maximal error is less than 1 ℃. At the same time, the optimum region of stoichiometric oxygen is obtained, which is in the range of 1.8-2.2 and accords with the experimental analysis results. The simulation and experimental results show the effectiveness of the proposed algorithm.

Research of Temperature Tracer Method to Detect Tubular Leakage Passage in Earth-Dam

The location, intensity and scope of concentrated leakage must be determined in order to repair earth-Dam scoured by the leakage. In this paper, firstly, heat tracer theory and distribution laws of temperature in soil body with leakage are discussed. Then temperature tracer model is established according to stable heat conduction theory. In such model, the concentrated seepage passage is simplified into a circular pipe as a boundary condition. The location, scope and flow-velocity of the concentrated leakage are estimated via ichnography of the lowest temperature based on temperature data from detecting wells by quantitative computation and qualitative analysis. In case study, the distribution characteristic of temperature (including temperature data of water in reservoir, drainage pipes and tail pond) can be interpreted by this model. A modified model is also set up, applied for detected data at different cross-sections of the leakage passage, in which the temperature data are rectified according to distances from data locations to calculating section. Finally, the model is solved by numerical iterative method, and the possible error of this theoretical model is discussed. The permeability coefficient in leakage area is identical with that of normal soil in magnitude after anti-seepage repairing accomplished, which indicates this model is effective.

Synthesis of Large-scale Multistream Heat Exchanger Networks Based on Stream Pseudo Temperature

Effective temperature level of stream, namely stream pseudo temperature, is determined by its actual temperature and heat transfer temperature difference contribution value. Heat transfer temperature difference con-tribution value of a stream depends on its heat transfer film coefficient, cost per unit heat transfer area, actual tem-perature, and so on. In the determination of the suitable heat transfer temperature difference contribution values of the stream, the total annual cost of multistream heat exchanger network (MSHEN) is regarded as an objective func-tion, and genetic/simulated annealing algorithm (GA/SA) is adopted for optimizing the heat transfer temperature difference contribution values of the stream. The stream pseudo temperatures are subsequently obtained. On the ba-sis of stream pseudo temperature, optimized MSHEN can be attained by the temperature-enthalpy (T-H) diagram method. This approach is characterized with fewer decision variables and higher feasibility of solutions. The calcu-lation efficiency of GA/SA can be remarkably enhanced by this approach and more probability is shown in search-ing the global optimum solution. Hence this approach is presented for solving industrial-sized MSHEN which is difficult to deal by traditional algorithm. Moreover, in the optimization of stream heat transfer temperature differ-ence contribution values, the effects of the stream temperature, the heat transfer film coefficient, and the construc-tion material of heat exchangers are considered, therefore this approach can be used to optimize and design heat exchanger network (HEN) with unequal heat transfer film coefficients and different of construction materials. The performance of the proposed approach has been demonstrated with three examples and the obtained solutions are compared with those available in literatures. The results show that the large-scale MSHEN synthesis problems can be solved to obtain good solutions with the modest computational effort.

In Situ Measurement of the Undisturbed Ground Temperature for Ground Source Heat Pump System

The undisturbed ground temperatures are important for design of the ground heat exchangers in ground source heat pump （GSHP） systems. In this paper, the undisturbed ground temperatures measured in two different methods are presented. The investigation was carried out in two cases. The temperature measured with the direct method is assumed to give the correct undisturbed ground temperature profile. The temperature measured with indirect method overestimates the undisturbed ground temperature by 2.1℃ and 1.7~C. This difference is mainly caused by the circulation pump and ambient air to the fluid. Therefore, the results that are decreased about 2℃ as compared with the indirect measured are recommended to estimate the undisturbed ground temperature in situ measuring. A smaller pump or deeper borehole or mild weather would result in a more correct temperature. Because the undisturbed ground temperature is affected by many factors. Whether or not these conclusions are correct to other areas, this would need further investigation.

Thermal Equilibrium Reached by Interaction Between Two Identical Systems

In this work we show that tending to thermal equilibrium in one system, at least in certain cases, is associated with the coherent dynamical evolution of this system in interaction with another identical system. The temperature varying effect with time is manifestly shown in our analyses.

Calculation and experimental study on heating temperature field of super-high strength aluminum alloy thick plate

Stepped heating treatment has been applied to aluminum alloy thick plate to improve the mechanical performance and corrosion resistance.Accurate temperature control of the plate is the difficulty in engineering application.The heating process,the calculation of surface heat transfer coefficient and the accurate temperature control method were studied based on measured heating temperature for the large-size thick plate.The results show that,the temperature difference between the surface and center of the thick plate is small.Based on the temperature uniformity,the surface heat transfer coefficient was calculated,and it is constant below300°C,but grows greatly over300°C.Consequently,a lumped parameter method(LPM)was developed to predict the plate temperature.A stepped solution treatment was designed by using LPM,and verified by finite element method(FEM)and experiments.Temperature curves calculated by LPM and FEM agree well with the experimental data,and the LPM is more convenient in engineering application.

Algorithm of heating temperature for Chongqing's winter greenhouses

Internal temperature is crucial to plant growth in the greenhouse. We investigated the patterns of constructing and managing greenhouses in Chongqing, and developed an algorithm of heating temperature for closed winter plastic greenhouses under the conditions of no man-made illumination, no ventilation and hot wind machine as the heating equipment, which are the most adopted pattern of greenhouses in Chongqing area. The algorithm includes two functions of temperature outside the greenhouse, which calculate the values of the warming estimation coefficient (WEC) and the gap between temperatures inside and outside the greenhouse with the measured data of outside temperature, and then give the value of internal temperature; the heat rating of heating facilities required by a greenhouse can be determined by this algorithm with given values of floor area and internal temperature, measured outside temperature and calculated WEC. Verification of the algorithm demonstrates a desirable accuracy of estimation. Algorithms of computing heating temperature for greenhouses of different constructing and managing patterns and in different geographic conditions can also be derived in a similar way. This research presents a paradigm for developing a feasible method to fit out greenhouses with appropriate heating facilities, aiming at energy efficient and cost efficient production.

Oxidative heat release intensity in coal at low temperatures measured by the hot-wire method

Directly measuring the oxidative heat release intensity at low temperatures is difficult at present.We developed a new method based on heat conduction theory that directly measures heat release intensity of loose coal at low temperatures.Using this method, we calculated the oxidative heat release intensity of differently sized loose coals by comparing the temperature rise of the coal in nitrogen or an air environment.The results show that oxidation heat release intensity of Shenhua coal sized 0～15 mm is 0.001～0.03 W/m3 at 30～90 °C and increases with increasing temperature.The heat release intensity at a given temperature is larger for smaller sized coal.The temperature effect on heat release intensity is muted as the coal size increases.At lower temperature the change in heat release intensity as a function of size becomes smaller.These results show that the test system is usable for practical applications and is easy to operate and is capable of measuring mass samples.

An improvement to the simulation of phase-change heat-transfer during soil freezing and thawing

A new variable time step method,which is called the backwards calculating time step method,is presented in this paper.It allows numerical simulation of soil freezing and thawing while avoiding "phase change missing and overflowing".A sensitive heat capacity model is introduced through which the calculation errors are analyzed.Then the equation using the self-adjusted time step is presented and solved using finite differences.Through this equation,the time needed for a space cell to reach the phase change point temperature is calculated.Using this time allows the time step to be adjusted so that errors caused by "phase change missing and overflowing" are successfully eliminated.Above all,the obvious features of this method are an accelerated rate for adjusting the time step and simplifing the computations.An actual example proves that this method can accurately calculate the temperature fields during soil freezing and thawing.It is an improvement over traditional methods and can be widely used on complicated multi-dimensional phase change problems.

Numerical simulation and model of control-efficiency of thermal crown of work rolls in cold rolling

Aiming at accuracy control of the thermal crown of work rolls in cold rolling,new parameters such as regulation domain and control-efficiency factors were proposed and a numerical analysis model of the thermal crown of work rolls was established using finite difference method to study roll's thermal deformation.Based on simulation results,the influences of control-efficiency factors on thermal crown are presented and the thermal crown of work rolls is analyzed after taking sub-cooling of sprinkling beam into consideration.It has been found that the control-efficiency factor of any position on the roll's surface is linear function of the temperature and the control ability of water temperature is stronger than other control parameters.In addition,the verification of the model has been carried out based on the producing technology data in some factories and the numerical simulation results coincide well with the experimental data.Therefore,this work has important value for on-line control of roll's crown in cold rolling.

Isothermal and nonisothermal crystallization kinetics of bio-sourced nylon 69

Bio-sourced nylon 69,one of promising engineering plastics,has a great potential in developing sustainable technology and various commercial applications.Isothermal and nonisothermal crystallization kinetics of nylon 69 is a base to optimize the process conditions and establish the structure–property correlations for nylon 69,and it is also highly bene ficial for successful applications of nylon products in industry.Isothermal and nonisothermal crystallization kinetics has been investigated by differential scanning calorimetry for nylon 69,bio-sourced even–odd nylon.The isothermal crystallization kinetics has been analyzed by the Avrami equation,the calculated Avrami exponent at various crystallization temperatures falls into the range of 2.28 and 2.86.In addition,the Avrami equation modi fied by Jeziorny and the equation suggested by Mo have been adopted to study the nonisothermal crystallization.The activation energies for isothermal and nonisothermal crystallization have also been determined.The study demonstrates that the crystallization model of nylon 69 might be a twodimensional(circular)growth at both isothermal and nonisothermal crystallization conditions.Furthermore,the value of the crystallization rate parameter(K)decreases signi ficantly but the crystallization half-time(t1/2)increases with the increase of the isothermal crystallization temperature.To nonisothermal crystallization,the crystallization rate increases as the cooling rate increases according to the analysis of Jeziorny's theory.The results of Mo's theory suggest that a faster cooling rate is required to reach a higher relative degree of crystallinity in a unit of time,and crystallization rate decreases when the relative degree of crystallinity increases at nonisothermal crystallization conditions.

Factors controlling the latent and sensible heat FLuxes over Erhai Lake under different atmospheric surface layer stability conditions

The stratification of the atmospheric surface layer(ASL)plays an important role in regulating the water vapor and heat exchange across the lake–air interface.Based on one year of data measured by the eddy covariance technique over Erhai Lake in 2015,the ASL stability(ζ)was divided into six ranges,including unstable(-1ζ<-0:1),weakly unstable(-0:1ζ<-0:01),near-neutral1(-0:01ζ<0),near-neutral2(0ζ<0:01),weakly stable(0:01ζ<0:1),and stable(0:1ζ<1).The characteristics of ASL stability conditions and factors controlling the latent(LE)and sensible heat(H)fluxes under different stability conditions were analyzed in this study.The stability conditions of Erhai Lake have noticeably seasonal and diurnal variation,with the nearneutral and(weakly)stable stratification usually occurring before July,with frequencies of 51.7%and 23.3%,respectively,but most of the(weakly)unstable stratification was observed after July,with a frequency of 59.8%.Large evaporation occurred even in stable atmospheric conditions,due to the coupled effects of the relatively larger lake–air vapor pressure difference and wind speed.The relative controls of LE and H by different atmospheric variables are largely dependent on the stability conditions.In stable and unstable ranges,LE is closely correlated with the vapor pressure difference,whereas in weakly unstable to weakly stable ranges,it is primarily controlled by wind speed.H is related to wind speed and the lake–air temperature difference under stable conditions,but shows no obvious relationship under unstable conditions.

Computational Characterization of Nanosystems

Nanosystems play an important role in many applications.Due to their complexity,it is challenging to accurately characterize their structure and properties.An important means to reach such a goal is computational simulation,which is grounded on ab initio electronic structure calculations.Low scaling and accurate electronic-structure algorithms have been developed in recent years.Especially,the efficiency of hybrid density functional calculations for periodic systems has been significantly improved.With electronic structure information,simulation methods can be developed to directly obtain experimentally comparable data.For example,scanning tunneling microscopy images can be effectively simulated with advanced algorithms.When the system we are interested in is strongly coupled to environment,such as the Kondo effect,solving the hierarchical equations of motion turns out to be an effective way of computational characterization.Furthermore,the first principles simulation on the excited state dynamics rapidly emerges in recent years,and nonadiabatic molecular dynamics method plays an important role.For nanosystem involved chemical processes,such as graphene growth,multiscale simulation methods should be developed to characterize their atomic details.In this review,we review some recent progresses in methodology development for computational characterization of nanosystems.Advanced algorithms and software are essential for us to better understand of the nanoworld.