原木跌水结构对河流潜流带温度场的影响

为探究原木跌水结构对河流潜流带温度场的影响,应用有限元软件COMSOL Multiphysics构建了地表水地下水二维耦合模型,分析原木跌水结构的高度、间距及数量等参数变化对河流潜流带温度场的影响规律。结果表明:河道中原木跌水结构的添加会改变潜流带局部的压力分布,增加原木高度、间距和数量都会使河床压力最大值增大;随着原木跌水结构高度增加,原木下方区域温度受地表水水温的影响范围扩大;随着原木跌水结构间距和数量的增加,潜流带热缓冲作用增强。原木跌水结构设置参数的变化将不同程度影响潜流带温度场的变化和热缓冲作用,引起潜流带内部的热异质性,从而增加底栖生物和水生生境的多样性。

Electronic Structures and Thermoelectric Properties of Two-Dimensional MoS2/MoSe2 Heterostructures

Thermoelectric properties of bulk and bilayer two-dimensional （2D） MoS2/MoSe2 het- erostructures are investigated using density functional theory in conjunction with semi- classical Boltzmann transport theory. It is predicted that the bulk 2D heterostructures could considerably enhance the thermoelectric properties as compared with the bulk MoSe2. The enhancement originates from the reduction in the band gap and the presence of interlayer van der Waals interactions. We therefore propose the 2D MoS2/MoSe2 heterostructures as a possible candidate material for thermoelectric applications.

Subthermionic field-effect transistors with sub-5 nm gate lengths based on van der Waals ferroelectric heterostructures

Overcoming the sub-5 nm gate length limit and decreasing the power dissipation are two main objects in the electronics research field. Besides advanced engineering techniques, considering new material systems may be helpful. Here, we demonstrate two-dimensional(2D) subthermionic field-effect transistors(FETs) with sub-5 nm gate lengths based on ferroelectric(FE) van der Waals heterostructures(vdWHs).The FE vd WHs are composed of graphene, MoS2, and CuInP2S6 acting as 2D contacts, channels, and ferroelectric dielectric layers, respectively. We first show that the as-fabricated long-channel device exhibits nearly hysteresis-free subthermionic switching over three orders of magnitude of drain current at room temperature. Further, we fabricate short-channel subthermionic FETs using metallic carbon nanotubes as effective gate terminals. A typical device shows subthermionic switching over five-to-six orders of magnitude of drain current with a minimum subthreshold swing of 6.1 mV/dec at room temperature. Our results indicate that 2D materials system is promising for advanced highly-integrated energy-efficient electronic devices.

Linking the spatiotemporal variation of litterfall to standing vegetation biomass in Brazilian savannas

Aims Litterfall at a global scale is affected by climate,edaphic features and vegetation structure,with litter production increasing from grasslands to forests following the rise in standing biomass.However,at landscape scales,the same relationship between litter production and vegetation structure has rarely been studied and comparisons of litterfall patterns between adjacent,structurally distinct communities are lacking.Here,we use a standardized methodology to describe the structural differences among four savanna physiognomies and analyze their relationship with changes in litterfall across the Cerrado.Methods We evaluated the woody vegetation structure and composition in 48 sites,equally distributed across four physiognomies and monitored the monthly litter production from April 2014 to March 2015.Important Findings Results showed that the density,basal area,cylindrical volume and aboveground biomass of woody vegetation differ among physiognomies,increasing consistently from cerrado ralo,cerrado típico,cerrado denso and cerradão.Indeed,we found a strong and positive relationship between aboveground biomass and annual litter production,with litter yield increasing from 0.9 to 8.4 Mg ha^(−1)across different physiognomies,following the increment in vegetation structure.Monthly production was seasonal and similar among vegetation types,increasing during the dry season.Leaves comprised the dominant fraction(approx.85%)and litterfall seasonality primarily resulted from the concentration of leaf shedding during dry months.However,the temporal pattern of litterfall throughout the year showed a gradual reduction in the seasonality from open to closed vegetation types,likely following the decrease of deciduous species abundance in the plant community.Our results showed that changes in vegetation structure may affect spatial and temporal litterfall patterns in different physiognomies,which co-occur across the Cerrado landscape,with potential implications for the overall functioning of this ecosystem.Moreover,these findings highlight the use of standardized methods as essential to correctly compare litterfall patterns among different environments.

Boosting photocatalytic hydrogen production by creating isotype heterojunctions and single-atom active sites in highly-crystallized carbon nitride

Carbon nitride-based photocatalysts hold an enormous potential in producing hydrogen.A strategy to simultaneously create isotype heterojunctions and active sites in highly-crystallized carbon nitride is anticipated to significantly boost the photocatalytic activity,but is yet to be realized.Herein,we find that cobalt salt added in the ionothermal synthesis can promote the phase transition of heptazine-based crystalline carbon nitride(CCN)to triazine-based poly(triazine imide)(PTI),rendering the creation of singleatom cobalt coordinated isotype CCN/PTI heterojunction.Co-CCN/PTI exhibits an appreciable apparent quantum yield of 20.88%at 425 nm for photocatalytic hydrogen production with a rate achieving3538μmol h^(-1)g^(-1)(λ>420 nm),which is 4.8 times that of CCN and 27.6 times that of PTI.The high photocatalytic activity is attributed to the Type II isotype highly-crystallized CCN/PTI heterojunction for promoting charge carrier migration,and the single-atom Co sites for accelerating surface oxidation reaction.

Homogenization for Periodic Heterogeneous Materials with Arbitrary Position-Dependent Material Properties

We present a rigorous homogenization approach for elcient computation of a class of physical problems in a one-dimensional periodic heterogeneous material. This material is represented by a spatially periodic array of unit cells with a length of More specifically, the method is applied to the diffusion, heat conduction, and wave propagation problems. Heterogeneous materials can have arbitrary position-dependent continuous or discontinuous materials properties （for example heat conductivity） within the unit cell. The final effective model includes both effective properties at the leading order and high-order contributions due to the microscopic heterogeneity. A dimensionless heterogeneity parameter ~ is defined to represent high-order contributions, shown to be in the range of [-1/12, 0], and has a universal expression for all three problems. Both effective properties and heterogeneity parameter 13 are independent oft, the microscopic scale of heterogeneity. The homogenized solution describing macroscopic variations can be obtained from the effective model. Solution with sub-unit-cell accuracy can be constructed based on the homogenized solution and its spatial derivatives. The paper represents a general approach to obtain the effective model for arbitrary periodic heterogeneous materials with position-dependent properties.