In this work, a thermodynamic model is developed for prediction of structure H hydrate formation. The model combines the Peng-Robinson equation of state for the vapor, liquid and aqueous phases with the extended Ng-Ro...In this work, a thermodynamic model is developed for prediction of structure H hydrate formation. The model combines the Peng-Robinson equation of state for the vapor, liquid and aqueous phases with the extended Ng-Robinson hydrate model for gas hydrate formation of all three structures. The parameters of 14 structure- H hydrate formers are determined based on the experimental data of structure-H hydrates in the literature. The expression of fugacity of water in the empty hydrate phase is correlated for calculating structure-H hydrate formation conditions in the absence of free water. The model is tested by predicting hydrate formation conditions of a number of structure-H hydrate forming systems which are in good agreement with the experimental data. The proposed model is also applied to the prediction of hydrate formation conditions for various reservoir fluids such as natural gas and gas condensate.展开更多
The thermal decomposition of abietic acid in air was investigated under non-isothermal condition using thermogravimetric analysis-differential thermal analysis (TGA-DTA) technique with heating rates of 5, 10, 15 and...The thermal decomposition of abietic acid in air was investigated under non-isothermal condition using thermogravimetric analysis-differential thermal analysis (TGA-DTA) technique with heating rates of 5, 10, 15 and 25 K.min-~. The non-isothermal kinetic parameters were obtained via the analysis of the thermogravimetric and differential thermogravimetric (TG-DTG) curves by using Flynn-Wall-Ozawa method and Kissinger method. The thermal decomposition mechanism of abietic acid was studied with four integral methods (Satava-Sestak, MacCallum-Tanner, ordinary integral and Agrawal). The results show that the thermal decomposition mechanism is nu- cleation and growth, and the mechanism function is Avrami-Erofeev equation with n equates 1/2. The activation energy and the pre-exponential factor are 64.04 kJ.mol^-1 and 5.89×10^5 s^-1, respectively.展开更多
The present paper deals with both the steady-state and dynamic simulation of a plate heat exchanger, in counter-flow arrangement. A CFD (computational fluid dynamics) program FLUENT has been used to predict the temp...The present paper deals with both the steady-state and dynamic simulation of a plate heat exchanger, in counter-flow arrangement. A CFD (computational fluid dynamics) program FLUENT has been used to predict the temperature distribution in steady-state conditions in plate heat exchanger as well as fluid temperatures at exit of flow channels in transient condition. The results are presented for the heat exchanger, which is simulated according to the configuration of the plate heat exchanger used in the experiment. The simulated results obtained by the CFD model have been compared with the experimental data from the literature, which shows that the CFD model developed in this study is capable of predicting the steady-state and transient performance of the plate heat exchangers satisfactorily.展开更多
With the improved moving least-squares (IMLS) approximation, an orthogonal function system with a weight function is used as the basis function. The combination of the element-free Galerkin (EFG) method and the IMLS a...With the improved moving least-squares (IMLS) approximation, an orthogonal function system with a weight function is used as the basis function. The combination of the element-free Galerkin (EFG) method and the IMLS approximation leads to the development of the improved element-free Galerkin (IEFG) method. In this paper, the IEFG method is applied to study the partial differential equations that control the heat flow in three-dimensional space. With the IEFG technique, the Galerkin weak form is employed to develop the discretized system equations, and the penalty method is applied to impose the essential boundary conditions. The traditional difference method for two-point boundary value problems is selected for the time discretization. As the transient heat conduction equations and the boundary and initial conditions are time dependent, the scaling parameter, number of nodes and time step length are considered in a convergence study.展开更多
基金Supported by the National Natural Science Foundation of China (No. 20490207, No. 20176028, No. 90210020) and Huo Ying-dong Education Foundation (No. 81064)
文摘In this work, a thermodynamic model is developed for prediction of structure H hydrate formation. The model combines the Peng-Robinson equation of state for the vapor, liquid and aqueous phases with the extended Ng-Robinson hydrate model for gas hydrate formation of all three structures. The parameters of 14 structure- H hydrate formers are determined based on the experimental data of structure-H hydrates in the literature. The expression of fugacity of water in the empty hydrate phase is correlated for calculating structure-H hydrate formation conditions in the absence of free water. The model is tested by predicting hydrate formation conditions of a number of structure-H hydrate forming systems which are in good agreement with the experimental data. The proposed model is also applied to the prediction of hydrate formation conditions for various reservoir fluids such as natural gas and gas condensate.
基金Supported by the National'Natural Science Foundation of China (20976031, 31060102), the Natural Science Foundation of Guangxi Autonomous Region (2011GXNSFD018011,0991030, 2010GXNSFA013042), the Science and Technology Program Foundation of Wuzhou City (200901011), the Scientific and Technological Project of Guangxi (1099060-2), the Scientific Research Innovative Foundation of Doctor Candidate (105930901008).
文摘The thermal decomposition of abietic acid in air was investigated under non-isothermal condition using thermogravimetric analysis-differential thermal analysis (TGA-DTA) technique with heating rates of 5, 10, 15 and 25 K.min-~. The non-isothermal kinetic parameters were obtained via the analysis of the thermogravimetric and differential thermogravimetric (TG-DTG) curves by using Flynn-Wall-Ozawa method and Kissinger method. The thermal decomposition mechanism of abietic acid was studied with four integral methods (Satava-Sestak, MacCallum-Tanner, ordinary integral and Agrawal). The results show that the thermal decomposition mechanism is nu- cleation and growth, and the mechanism function is Avrami-Erofeev equation with n equates 1/2. The activation energy and the pre-exponential factor are 64.04 kJ.mol^-1 and 5.89×10^5 s^-1, respectively.
文摘The present paper deals with both the steady-state and dynamic simulation of a plate heat exchanger, in counter-flow arrangement. A CFD (computational fluid dynamics) program FLUENT has been used to predict the temperature distribution in steady-state conditions in plate heat exchanger as well as fluid temperatures at exit of flow channels in transient condition. The results are presented for the heat exchanger, which is simulated according to the configuration of the plate heat exchanger used in the experiment. The simulated results obtained by the CFD model have been compared with the experimental data from the literature, which shows that the CFD model developed in this study is capable of predicting the steady-state and transient performance of the plate heat exchangers satisfactorily.
基金the National Natural Science Foundation of China (Grant No. 11171208)Shanghai Leading Academic Discipline Project (Grant No. S30106)
文摘With the improved moving least-squares (IMLS) approximation, an orthogonal function system with a weight function is used as the basis function. The combination of the element-free Galerkin (EFG) method and the IMLS approximation leads to the development of the improved element-free Galerkin (IEFG) method. In this paper, the IEFG method is applied to study the partial differential equations that control the heat flow in three-dimensional space. With the IEFG technique, the Galerkin weak form is employed to develop the discretized system equations, and the penalty method is applied to impose the essential boundary conditions. The traditional difference method for two-point boundary value problems is selected for the time discretization. As the transient heat conduction equations and the boundary and initial conditions are time dependent, the scaling parameter, number of nodes and time step length are considered in a convergence study.