工装材料和厚度对复合材料热成型性能的影响

随着复合材料在航空航天、汽车制造等领域的广泛应用,热成型工艺的研究显得尤为重要m工装材料的选择及其厚度对复合材料的热成型性能具有重要影响。基于此,文章简要分析了复合材料在航空中的应用现状,并对两种常见材质工装——Invar钢和Q235钢进行了系统的研究,重点分析了它们在不同厚度条件下的固化曲线及温度响应特性。研究发现,由于Invar 钢优异的热稳定性和较低的热导率,其内部温度响应矫形面的滞后现象更加显著,并且不同的热量传递方式对工装性能及复合材料成型质量也会有一定的影响。

Influence of process parameters on properties of AA6082 in hot forming process

The influences of process parameters on mechanical properties of AA6082in the hot forming and cold-die quenching(HFQ)process were analysed experimentally.Transmission electron microscopy was used to observe the precipitate distribution and to thus clarify strengthening mechanism.A new model was established to describe the strengthening of AA6082by HFQ process in this novel forming technique.The material constants in the model were determined using a genetic algorithm tool.This strengthening model for AA6082can precisely describe the relationship between the strengths of formed workpieces and process parameters.The predicted results agree well with the experimental ones.The Pearson correlation coefficient,average absolute relative error,and root-mean-square error between the calculated and experimental hardness values are0.99402,2.0054%,and2.045,respectively.The model is further developed into an FE code ABAQUS via VUMAT to predict the mechanical property variation of a hot-stamped cup in various ageing conditions.

Degradation behaviors,thermostability and mechanical properties of poly(ethylene terephthalate)/polylactic acid blends

It is difficult for polyethylene terephthalate （PET） to degrade,which caused severe pollution.In this work,polylactic acid （PLA） was introduced to improve the degradation of PET.PET/PLA was synthesized by extrusion blending.The thermal,crystalline and mechanical properties of blends were investigated with TGA,DSC,WAXD and universal testing machine.The degradation of the blends in soil,acid and alkaline buffer solutions was assessed,respectively.It was found that the introduction of a little PLA promoted crystallization of PET during injection molding process.The starting decomposition temperature lowered from 412.1 ℃ of pure PET to 330.4 ℃ at 50% PLA content,tensile and bending strength of blends gradually decreased with the PLA content increasing,while the degradation rate improved.Alkaline environment was most beneficial for blends to degrade.The degradation mechanism was discussed.

Experimental Research of Automotive Needlepunched Carpets at Thermoforming Temperatures

Tensile properties with different thermoforming conditions and deformation mechanism at thermoforming temperatures of automotive needlepunched carpets made up of three layers of different materials were reported.Investigations on the tensile properties were performed as a function of thermoforming temperature,extensile speed and fiber orientation based on an orthogonal experiment design.The experimental results show that the automotive carpets are rate-dependent anisotropic one and very sensitive to the forming temperature.The tensile properties are strongly depended on the forming temperature when compared with the extensile speed and the fiber orientation.Experiments only varying with the temperature were performed because of the dominative effect of the temperature.Different deformation performances were observed with different temperatures.Deformation mechanisms at the thermoforming temperatures were presented to explain the nonlinear trend of the ultimate elongation with the temperatures based on the combination of the experimental observations and the corresponding polymer theories.

Optimization of the thermoelectric properties of poly(nickel-ethylenetetrathiolate) synthesized via potentiostatic deposition

The coordination polymer poly（nickel-ethylenetetrathiolate） （poly（Ni-ett））, formed by nickel（Ⅱ） and 1,1,2,2-ethenetetrathiolate （ett）, is the most promising N-type organic thermoelectric material ever reported; it is synthesized via potentiostatic deposition, and the effect of different applied potentials on the optimal performance of the polymers is investigated. The optimal thermoelectric property ofpoly（Ni-ett） synthesized at 0.6 V is remarkably greater than that of the polymers synthesized at 1 and 1.6 V, exhibiting a maximum power factor of up to 131.6μW/mK2 at 360 K. Furthermore, the structure-property correlation ofpoly（Ni-ett） is also extensively investigated. X-ray diffraction （XRD） and X-ray photoelectron spectroscopy （XPS） analyses revealed that the larger size of crystalline domains and the higher oxidation state of poly（Ni-ett） synthesized at 0.6 V possibly results in the higher bulk mobility and carrier concentration in the polymer chains, respectively, accounting for the enhanced power factor.