The electrical heating experiments on oil shale sample from Huadian of Jilin were carried out by the pyrolysis method at three different heating rate 2℃/min, 5 ℃/min and 10 ℃/min in the temperature range of 30℃ -...The electrical heating experiments on oil shale sample from Huadian of Jilin were carried out by the pyrolysis method at three different heating rate 2℃/min, 5 ℃/min and 10 ℃/min in the temperature range of 30℃ -750℃. Heating rate 2 ℃/rain is considered low, while intermediate one covers the range 5 ℃/min and high heating rate is 10℃/min. The controlling parameters studied were the final pyrolysis temperature and the influence of the heating rate as well as type. The heating rate has an important effect on the pyrolysis of oil shale and the amount of residual carbon obtained therefore. It is found that increasing the heating rate and py- rolysis temperature also increases the production of oil and the total weight loss. Higher heating rates resulted in higher rates of accumulation. The rate of oil and water collection passed through the maximum of different heat- ing rates at different pyrolysis temperatures. Heating rate affected density, oil conversion and oil yield.展开更多
A research on the heat transfer performance of kerosene flowing in a vertical upward tube at supercritical pressure is presented.In the experiments,insights are offered on the effects of the factors such as mass flux,...A research on the heat transfer performance of kerosene flowing in a vertical upward tube at supercritical pressure is presented.In the experiments,insights are offered on the effects of the factors such as mass flux,heat flux,and pressure.It is found that increasing mass flux reduces the wall temperature and separates the experimental section into three different parts,while increasing working pressure deteriorates heat transfer.The extended corresponding-state principle can be used for evaluating density and transport properties of kerosene,including its viscosity and thermal conductivity,at different temperatures and pressures under supercritical conditions.For getting the heat capacity,a Soave–Redlich–Kwong(SRK)equation of state is used.The correlation for predicting heat transfer of kerosene at supercritical pressure is established and shows good agreement with the experimental data.展开更多
The heat exchanger network(HEN) synthesis problem based on entransy theory is analyzed. According to the characteristics of entransy representation of thermal potential energy, the entransy dissipation represents the ...The heat exchanger network(HEN) synthesis problem based on entransy theory is analyzed. According to the characteristics of entransy representation of thermal potential energy, the entransy dissipation represents the irreversibility of the heat transfer process, the temperature difference determines the entransy dissipation, and four HEN design steps based on entransy theory are put forward. The present study shows how it is possible to set energy targets based on entransy and achieve them with a network of heat exchangers by an example of heat exchanger network design for four streams. In order to verify the correctness of the heat exchanger networks design method based on entransy theory, the synthesis of the HEN for the diesel hydrogenation unit is studied. Using the heat exchange networks design method based on entransy theory, the HEN obtained is consistent with energy targets. The entransy transfer efficiency of HEN based on entransy theory is 92.29%, higher than the entransy transfer efficiency of the maximum heat recovery network based on pinch technology.展开更多
Cavitation bubble collapse has a great influence on the temperature of hydraulic oil. Herein, cone-type throttle valve experiments are carried out to study the thermodynamic processes of cavitation. First, the process...Cavitation bubble collapse has a great influence on the temperature of hydraulic oil. Herein, cone-type throttle valve experiments are carried out to study the thermodynamic processes of cavitation. First, the processes of growth and collapse are analysed, and the relationships between the hydraulic oil temperature and bubble growth and collapse are deduced. The effect of temperature is then considered on the hydraulic oil viscosity and saturated vapour pressure. Additionally, an improved form of the Rayleigh–Plesset equation is developed. The effect of cavitation on the hydraulic oil temperature is experimentally studied and the effects of cavitation bubble collapse in the hydraulic system are summarised. Using the cone-type throttle valve as an example, a method to suppress cavitation is proposed.展开更多
Based on the energy equation of gas-liquid flow in pipeline,the explicit temperature drop formula for gas-liquid steady state calculation was derived.This formula took into consideration the Joule-Thomson effect,impac...Based on the energy equation of gas-liquid flow in pipeline,the explicit temperature drop formula for gas-liquid steady state calculation was derived.This formula took into consideration the Joule-Thomson effect,impact of terrain undulation and heat transfer with the surroundings along the line.Elimination of temperature iteration loop and integration of the explicit temperature equation,instead of enthalpy energy equation,into the conjugated hydraulic and thermal computation have been found to improve the efficiency of algorithm.Then,the inner wall temperature of gas-liquid flow was calculated by using explicit temperature equation and inner wall convective heat transfer coefficient of mixed flow which can be obtained by liquid convective heat transfer coefficient and gas convective heat transfer coefficient on the basis of liquid holdup.The temperature results of gas-liquid flow and inner wall in the case example presented both agree well with those in professional multiphase computational software OLGA.展开更多
Petroleum coke was thermally treated on a fixed bed reactor in a temperature range of 1173-1673 K. The changes of the elemental composition and crystalline structure of petroleum coke, with heat treatments as well as ...Petroleum coke was thermally treated on a fixed bed reactor in a temperature range of 1173-1673 K. The changes of the elemental composition and crystalline structure of petroleum coke, with heat treatments as well as the gasification reactivity of the heat-treated petroleum cokes were investigated. The results showed that the petroleum coke was carbonized and grapbitized to a higher degree with increasing heating temperature, while the gasification reactivity decreased. The treatment at temperatures of 1173 and 1473 K significantly enlarged the specific surface area and the pore volume of petroleum coke. Both the specific surface area and the pore volume decreased at 1673 K. An empirical normal distribution function model (NDFM) was found to fit the gasification rates of petroleum coke well. The correlation coefficient of petroleum coke by normal distribution function model at different heat treatment temperatures is between 0.93 and 0.95.展开更多
Development of gas turbine oils that can be used in higher temperature conditions remains the greatest technological challenge. Though the maximum operating temperature of conventional lubricating oils is generally se...Development of gas turbine oils that can be used in higher temperature conditions remains the greatest technological challenge. Though the maximum operating temperature of conventional lubricating oils is generally set around 100 ℃, or 140 ℃ for scavenged oils, it is predicted that the future will require oils to function at 200 ℃ or above. To find a clue to developing oils that can be used at higher temperatures, this study attempted to estimate service lives and operating temperature ranges of certain oils, including oils conforming to MIL-PRF-23699, which are deemed promising candidates for high-temperature applications, by analyzing their reaction rates of degradation and degeneration by oxidation. Among a number of methods used in the analyses of reaction rates, this study chose thermo-gravimetry (TG), with which estimations can be made relatively easily.展开更多
The entransy theory, which can be used to optimize the heat transfer network of a solar power tower system (SPTS) and im- prove its energy efficiency, was introduced in this paper. Firstly, the irreversibility of th...The entransy theory, which can be used to optimize the heat transfer network of a solar power tower system (SPTS) and im- prove its energy efficiency, was introduced in this paper. Firstly, the irreversibility of the heat transfer processes in a SPTS was analyzed and the total entransy dissipation equation of a SPTS was derived. Then, two types of optimization problems (reduc- ing the total circulating flow rate or the total heat-exchanging area) of a SPTS were solved with conditional extremum model based on the formulas of total entransy dissipation. Finally, the entransy dissipation-based optimization principle was applied to a simple SPTS without re-heater and a complex SPTS with a re-heater. The results showed that under the chosen calculation conditions the minimum total thermal conductance was 19306.03 W K-~ for a SPTS without re-heater when the total heat ca- pacity rate of heat transfer fluid (HTF) was 3200 W K-1. The minimum total thermal conductance was about 7.9% lower than the value predicted based on the typical outlet temperature of a receiver. This meant that the total heat exchange area or initial investment could be effectively reduced under the prescribed total HTF circulating flow rate. We also studied the variation trends of the two optimized results including minimum total HTF heat capacity rate and minimum total thermal conductance. The minimum total HTF heat capacity rate decreased with the given total thermal conductance, the minimum total thermal conductance decreased first and then increased with the given total HTF heat capacity rate. We also found that for a SPTS with a re-heater, the mixing temperature and the mixing position of HTF had significant effects on the two types of optimization problems.展开更多
The purpose of this study is to understand the factor that influence the heating efficiency of the outward and inward multi-hole gas burner. The flame-hole angle and the distance from flame hole to heating object are ...The purpose of this study is to understand the factor that influence the heating efficiency of the outward and inward multi-hole gas burner. The flame-hole angle and the distance from flame hole to heating object are chosen as the experimental parameters. The measurement of the flame temperature distribution is carried out on each experimental condition. The observation of combustion flame, by the Schlieren method, is done from the purpose to understand the combustion phenomenon on the heating efficiency. LPG (Liquefied petroleum gas) is used for the test fuel gas. The compositions of LPG are propane 97.5vol%, butane 0.2vol% and methane + ethylene 2.3vol%. The optimum ranges of the flame-hole angle and the distance from flame hole to heating object are clarified. The experimental correlation equations for the outward and inward multi-flame-hole gas burner are proposed.展开更多
文摘The electrical heating experiments on oil shale sample from Huadian of Jilin were carried out by the pyrolysis method at three different heating rate 2℃/min, 5 ℃/min and 10 ℃/min in the temperature range of 30℃ -750℃. Heating rate 2 ℃/rain is considered low, while intermediate one covers the range 5 ℃/min and high heating rate is 10℃/min. The controlling parameters studied were the final pyrolysis temperature and the influence of the heating rate as well as type. The heating rate has an important effect on the pyrolysis of oil shale and the amount of residual carbon obtained therefore. It is found that increasing the heating rate and py- rolysis temperature also increases the production of oil and the total weight loss. Higher heating rates resulted in higher rates of accumulation. The rate of oil and water collection passed through the maximum of different heat- ing rates at different pyrolysis temperatures. Heating rate affected density, oil conversion and oil yield.
基金Supported by the National Science Foundation of Zhejiang Province(Z13E060001)the National Natural Science Foundation of China(52176091)+1 种基金the National Science Foundation of Shandong Province(ZR2012EEQ017)the PhD Program Foundation of Ministry of Education of China(20120101110102)
文摘A research on the heat transfer performance of kerosene flowing in a vertical upward tube at supercritical pressure is presented.In the experiments,insights are offered on the effects of the factors such as mass flux,heat flux,and pressure.It is found that increasing mass flux reduces the wall temperature and separates the experimental section into three different parts,while increasing working pressure deteriorates heat transfer.The extended corresponding-state principle can be used for evaluating density and transport properties of kerosene,including its viscosity and thermal conductivity,at different temperatures and pressures under supercritical conditions.For getting the heat capacity,a Soave–Redlich–Kwong(SRK)equation of state is used.The correlation for predicting heat transfer of kerosene at supercritical pressure is established and shows good agreement with the experimental data.
基金Supported the National Natural Science Foundation of China(21406124)
文摘The heat exchanger network(HEN) synthesis problem based on entransy theory is analyzed. According to the characteristics of entransy representation of thermal potential energy, the entransy dissipation represents the irreversibility of the heat transfer process, the temperature difference determines the entransy dissipation, and four HEN design steps based on entransy theory are put forward. The present study shows how it is possible to set energy targets based on entransy and achieve them with a network of heat exchangers by an example of heat exchanger network design for four streams. In order to verify the correctness of the heat exchanger networks design method based on entransy theory, the synthesis of the HEN for the diesel hydrogenation unit is studied. Using the heat exchange networks design method based on entransy theory, the HEN obtained is consistent with energy targets. The entransy transfer efficiency of HEN based on entransy theory is 92.29%, higher than the entransy transfer efficiency of the maximum heat recovery network based on pinch technology.
基金Projects(51505289,51275123)supported by the National Natural Science Foundation of China
文摘Cavitation bubble collapse has a great influence on the temperature of hydraulic oil. Herein, cone-type throttle valve experiments are carried out to study the thermodynamic processes of cavitation. First, the processes of growth and collapse are analysed, and the relationships between the hydraulic oil temperature and bubble growth and collapse are deduced. The effect of temperature is then considered on the hydraulic oil viscosity and saturated vapour pressure. Additionally, an improved form of the Rayleigh–Plesset equation is developed. The effect of cavitation on the hydraulic oil temperature is experimentally studied and the effects of cavitation bubble collapse in the hydraulic system are summarised. Using the cone-type throttle valve as an example, a method to suppress cavitation is proposed.
基金Project(2011ZX05000-026-004) supported by the National Science & Technology Specific Program of ChinaProject(2010D-5006-0604) supported by the China National Petroleum Corporation (CNPC) Innovation FoundationProject(51004167) supported by the National Natural Science Foundation of China
文摘Based on the energy equation of gas-liquid flow in pipeline,the explicit temperature drop formula for gas-liquid steady state calculation was derived.This formula took into consideration the Joule-Thomson effect,impact of terrain undulation and heat transfer with the surroundings along the line.Elimination of temperature iteration loop and integration of the explicit temperature equation,instead of enthalpy energy equation,into the conjugated hydraulic and thermal computation have been found to improve the efficiency of algorithm.Then,the inner wall temperature of gas-liquid flow was calculated by using explicit temperature equation and inner wall convective heat transfer coefficient of mixed flow which can be obtained by liquid convective heat transfer coefficient and gas convective heat transfer coefficient on the basis of liquid holdup.The temperature results of gas-liquid flow and inner wall in the case example presented both agree well with those in professional multiphase computational software OLGA.
文摘Petroleum coke was thermally treated on a fixed bed reactor in a temperature range of 1173-1673 K. The changes of the elemental composition and crystalline structure of petroleum coke, with heat treatments as well as the gasification reactivity of the heat-treated petroleum cokes were investigated. The results showed that the petroleum coke was carbonized and grapbitized to a higher degree with increasing heating temperature, while the gasification reactivity decreased. The treatment at temperatures of 1173 and 1473 K significantly enlarged the specific surface area and the pore volume of petroleum coke. Both the specific surface area and the pore volume decreased at 1673 K. An empirical normal distribution function model (NDFM) was found to fit the gasification rates of petroleum coke well. The correlation coefficient of petroleum coke by normal distribution function model at different heat treatment temperatures is between 0.93 and 0.95.
文摘Development of gas turbine oils that can be used in higher temperature conditions remains the greatest technological challenge. Though the maximum operating temperature of conventional lubricating oils is generally set around 100 ℃, or 140 ℃ for scavenged oils, it is predicted that the future will require oils to function at 200 ℃ or above. To find a clue to developing oils that can be used at higher temperatures, this study attempted to estimate service lives and operating temperature ranges of certain oils, including oils conforming to MIL-PRF-23699, which are deemed promising candidates for high-temperature applications, by analyzing their reaction rates of degradation and degeneration by oxidation. Among a number of methods used in the analyses of reaction rates, this study chose thermo-gravimetry (TG), with which estimations can be made relatively easily.
基金supported by the National Natural Science Foundation of China(Grant No.U1261112)the Research Project of Chinese Ministry of Education(Grant Nos.113055A,20120201130006)
文摘The entransy theory, which can be used to optimize the heat transfer network of a solar power tower system (SPTS) and im- prove its energy efficiency, was introduced in this paper. Firstly, the irreversibility of the heat transfer processes in a SPTS was analyzed and the total entransy dissipation equation of a SPTS was derived. Then, two types of optimization problems (reduc- ing the total circulating flow rate or the total heat-exchanging area) of a SPTS were solved with conditional extremum model based on the formulas of total entransy dissipation. Finally, the entransy dissipation-based optimization principle was applied to a simple SPTS without re-heater and a complex SPTS with a re-heater. The results showed that under the chosen calculation conditions the minimum total thermal conductance was 19306.03 W K-~ for a SPTS without re-heater when the total heat ca- pacity rate of heat transfer fluid (HTF) was 3200 W K-1. The minimum total thermal conductance was about 7.9% lower than the value predicted based on the typical outlet temperature of a receiver. This meant that the total heat exchange area or initial investment could be effectively reduced under the prescribed total HTF circulating flow rate. We also studied the variation trends of the two optimized results including minimum total HTF heat capacity rate and minimum total thermal conductance. The minimum total HTF heat capacity rate decreased with the given total thermal conductance, the minimum total thermal conductance decreased first and then increased with the given total HTF heat capacity rate. We also found that for a SPTS with a re-heater, the mixing temperature and the mixing position of HTF had significant effects on the two types of optimization problems.
文摘The purpose of this study is to understand the factor that influence the heating efficiency of the outward and inward multi-hole gas burner. The flame-hole angle and the distance from flame hole to heating object are chosen as the experimental parameters. The measurement of the flame temperature distribution is carried out on each experimental condition. The observation of combustion flame, by the Schlieren method, is done from the purpose to understand the combustion phenomenon on the heating efficiency. LPG (Liquefied petroleum gas) is used for the test fuel gas. The compositions of LPG are propane 97.5vol%, butane 0.2vol% and methane + ethylene 2.3vol%. The optimum ranges of the flame-hole angle and the distance from flame hole to heating object are clarified. The experimental correlation equations for the outward and inward multi-flame-hole gas burner are proposed.