The absorption-compression heat pump （ACHP） has been considered as an effective approach to recover and utilize low-grade heat sources. In the present study, the first and second law thermodynamic analyses of the AC...The absorption-compression heat pump （ACHP） has been considered as an effective approach to recover and utilize low-grade heat sources. In the present study, the first and second law thermodynamic analyses of the ACHP with NH3/H20 as working fluid were performed. Thermodynamic properties of each point and heat transfer rate of each component in the cycle under basic operation conditions were calculated from the first law analysis. Following the second law of thermodynamics, the entropy generation of each component and the total entropy generation of the system were obtained. The effect~ of the heating temperature, heat source temperature, and compression ratio on the coefficient of performance （COP） and the total entropy generation （ STot ） of the system were examined. The results show that the increase in COP corresponds to a decrease in STot, and vice versa; besides, for certain operating conditions, an optimum compression ratio in the NH~/H20 ACHP exists.展开更多
Using high pressure and geological condition simulation vessels, we conducted hydrous pyrolysis experiments of kerogen, solid bitumen and liquid hydrocarbons in southern China in order to study the processes of gas ge...Using high pressure and geological condition simulation vessels, we conducted hydrous pyrolysis experiments of kerogen, solid bitumen and liquid hydrocarbons in southern China in order to study the processes of gas generation and derive geo- chemical indicators of gas genesis under approximate pressure and temperature. The results indicate that gas generation productivity of different marine material decreased in the ganic matter （solid bitumen and heavy oil）, and kerogen. order of crude oil （light oil and condensate）, dispersed soluble or- Under identical temperature-pressure regimes, pyrolysates derived from kerogen and dispersed soluble organic matter display drastically different geochemical characteristics. For example, the δ13Cc02-δ13C1 values of gaseous products from dispersed soluble organic matter are greater than 20%o, whereas those from kerogen are less than 20%~. The 813C1 values of pyrolysates from different marine hydrocarbon sources generally increase with pyrolysis temperature, but are always lower than those of the source precursors. The δ13C values of ethane and propane in the pyrolysates also increase with increasing pyrolysis temperature, eventually approaching that of their sources, at peak hydro- carbon generation. At high-over mature stages, the δ13C values of ethane and propane are often greater than those of their sources but close to those of coal gases, and thus become ineffective as gas genetic indicators. Ln（CffC3） can clearly distin- guish kerogen degradation gas from oil cracking gas and Ln（CJC2）-（δ13C1-δ13C2） can be an effective indicator for distinguishing oil cracking gas from dispersed soluble organic matter cracking gas.展开更多
基金National Key Technologies R&D Program of China(No. 2012BABZ︱2B01)National Natural Science Foundation of China(No. 51106161)Innovation Foundation of President of Guangzhou Institute of Energy Conversion,Chinese Academy of Sciences(No. 0907r7)
文摘The absorption-compression heat pump （ACHP） has been considered as an effective approach to recover and utilize low-grade heat sources. In the present study, the first and second law thermodynamic analyses of the ACHP with NH3/H20 as working fluid were performed. Thermodynamic properties of each point and heat transfer rate of each component in the cycle under basic operation conditions were calculated from the first law analysis. Following the second law of thermodynamics, the entropy generation of each component and the total entropy generation of the system were obtained. The effect~ of the heating temperature, heat source temperature, and compression ratio on the coefficient of performance （COP） and the total entropy generation （ STot ） of the system were examined. The results show that the increase in COP corresponds to a decrease in STot, and vice versa; besides, for certain operating conditions, an optimum compression ratio in the NH~/H20 ACHP exists.
基金supported by Petroleum & Chemical United Fund Project(Grant No. 40739902)
文摘Using high pressure and geological condition simulation vessels, we conducted hydrous pyrolysis experiments of kerogen, solid bitumen and liquid hydrocarbons in southern China in order to study the processes of gas generation and derive geo- chemical indicators of gas genesis under approximate pressure and temperature. The results indicate that gas generation productivity of different marine material decreased in the ganic matter （solid bitumen and heavy oil）, and kerogen. order of crude oil （light oil and condensate）, dispersed soluble or- Under identical temperature-pressure regimes, pyrolysates derived from kerogen and dispersed soluble organic matter display drastically different geochemical characteristics. For example, the δ13Cc02-δ13C1 values of gaseous products from dispersed soluble organic matter are greater than 20%o, whereas those from kerogen are less than 20%~. The 813C1 values of pyrolysates from different marine hydrocarbon sources generally increase with pyrolysis temperature, but are always lower than those of the source precursors. The δ13C values of ethane and propane in the pyrolysates also increase with increasing pyrolysis temperature, eventually approaching that of their sources, at peak hydro- carbon generation. At high-over mature stages, the δ13C values of ethane and propane are often greater than those of their sources but close to those of coal gases, and thus become ineffective as gas genetic indicators. Ln（CffC3） can clearly distin- guish kerogen degradation gas from oil cracking gas and Ln（CJC2）-（δ13C1-δ13C2） can be an effective indicator for distinguishing oil cracking gas from dispersed soluble organic matter cracking gas.
