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炭质吸附剂的孔结构修饰及表征
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作者 翟宇恺 李轶 +1 位作者 王燕 赵秋燕 《应用化工》 CAS CSCD 2008年第9期1035-1038,1042,共5页
用1-丁烯炭沉积法修饰碳分子筛的孔结构。考察了炭沉积的位置、浓度、温度、沉积时间和活性组分对沉积效果的影响。结果表明,当1-丁烯浓度为31.8%,沉积温度为993 K,沉积时间为10 min,炭沉积量合适时,空气变压吸附(PSA)N2浓度可达85.6%;... 用1-丁烯炭沉积法修饰碳分子筛的孔结构。考察了炭沉积的位置、浓度、温度、沉积时间和活性组分对沉积效果的影响。结果表明,当1-丁烯浓度为31.8%,沉积温度为993 K,沉积时间为10 min,炭沉积量合适时,空气变压吸附(PSA)N2浓度可达85.6%;对浸Ni(Ni载持量5%)样,炭沉积主要发生在接近外表面的中孔和大孔中,不容易导致孔的堵塞,Ni的加入起到了提高炭沉积选择性的作用,(PSA)N2浓度可达91.0%。FT-IR、XRD、in-situTG/DTA测试表明,经炭沉积修饰后的碳分子筛具有微孔分布独特的骨架网络结构。 展开更多
关键词 热炭沉积 催化沉积 空气变压吸附(PAS)N2浓度 孔结构修饰
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Microstructures and formation mechanism of headstand pyrocarbon cones developed by electromagnetic-field-assisted CVD 被引量:3
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作者 涂川俊 黄启忠 +2 位作者 张明瑜 赵新奇 陈江华 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2012年第10期2569-2577,共9页
Novel headstand pyrocarbon cones (HPCs) with hollow structure were developed on the surfaces of pyrocarbon layers of the carbon/carbon (C/C) composites at 650-750 °C by the electromagnetic-field-assisted chem... Novel headstand pyrocarbon cones (HPCs) with hollow structure were developed on the surfaces of pyrocarbon layers of the carbon/carbon (C/C) composites at 650-750 °C by the electromagnetic-field-assisted chemical vapor deposition in the absence of catalysts. The fine microstructures of the HPCs were characterized by high-resolution transmission electron microscopy. The results show that the textural features of the HPCs directly transfer from turbostratic structure in roots to a well-ordered high texture in stems. And the degree of high texture ordering decreases gradually from the stem to the tail of the HPCs. The formation mechanism of the HPCs was inferred as the comprehensive effect of polarization induction on electromagnetic fields and particle-filler property under disruptive discharge. 展开更多
关键词 headstand pyrocarbon cones chemical vapor deposition electromagnetic-field-assisted method fine microstructure formation mechanism
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