V-4Cr-4Ti is the leading candidate vanadium alloy for fusion applications as structural material of first wall and blanket. Due to the interaction between Ti and interstitial solutes of C, N, and O, precipitation occu...V-4Cr-4Ti is the leading candidate vanadium alloy for fusion applications as structural material of first wall and blanket. Due to the interaction between Ti and interstitial solutes of C, N, and O, precipitation occurs at elevated temperature. The behavior has been studied in the past few years by short time annealing and results showed that it may greatly affect its mechanical properties Ti-CON type precipitates, appearing at- 700℃ in the solid-solution annealed alloy in high number density and small size, strengthen the alloy significantly and reduce its ductility. As the ductility reduction is in an acceptable level, the strengthening might be utilized for a light and strong vanadium alloy structure. Before a conclusion, uncertainty of its thermal stability should be studied during the high temperature serves. Besides, seldom has been studied for the effect of long time aging on precipitation behavior and tensile properties of the alloy.展开更多
The coordination polymer poly（nickel-ethylenetetrathiolate） （poly（Ni-ett））, formed by nickel（Ⅱ） and 1,1,2,2-ethenetetrathiolate （ett）, is the most promising N-type organic thermoelectric material ever repor...The coordination polymer poly（nickel-ethylenetetrathiolate） （poly（Ni-ett））, formed by nickel（Ⅱ） and 1,1,2,2-ethenetetrathiolate （ett）, is the most promising N-type organic thermoelectric material ever reported; it is synthesized via potentiostatic deposition, and the effect of different applied potentials on the optimal performance of the polymers is investigated. The optimal thermoelectric property ofpoly（Ni-ett） synthesized at 0.6 V is remarkably greater than that of the polymers synthesized at 1 and 1.6 V, exhibiting a maximum power factor of up to 131.6μW/mK2 at 360 K. Furthermore, the structure-property correlation ofpoly（Ni-ett） is also extensively investigated. X-ray diffraction （XRD） and X-ray photoelectron spectroscopy （XPS） analyses revealed that the larger size of crystalline domains and the higher oxidation state of poly（Ni-ett） synthesized at 0.6 V possibly results in the higher bulk mobility and carrier concentration in the polymer chains, respectively, accounting for the enhanced power factor.展开更多
文摘V-4Cr-4Ti is the leading candidate vanadium alloy for fusion applications as structural material of first wall and blanket. Due to the interaction between Ti and interstitial solutes of C, N, and O, precipitation occurs at elevated temperature. The behavior has been studied in the past few years by short time annealing and results showed that it may greatly affect its mechanical properties Ti-CON type precipitates, appearing at- 700℃ in the solid-solution annealed alloy in high number density and small size, strengthen the alloy significantly and reduce its ductility. As the ductility reduction is in an acceptable level, the strengthening might be utilized for a light and strong vanadium alloy structure. Before a conclusion, uncertainty of its thermal stability should be studied during the high temperature serves. Besides, seldom has been studied for the effect of long time aging on precipitation behavior and tensile properties of the alloy.
基金supported by the National Basic Research Program of China (2013CB632506)the Strategic Priority Research Program of the Chinese Academy of Sciences (XDB12000000)+1 种基金Key Project of National Natural Science Foundation of China (51336009)National Natural Science Foundation of China (21290191, 21333011)
文摘The coordination polymer poly（nickel-ethylenetetrathiolate） （poly（Ni-ett））, formed by nickel（Ⅱ） and 1,1,2,2-ethenetetrathiolate （ett）, is the most promising N-type organic thermoelectric material ever reported; it is synthesized via potentiostatic deposition, and the effect of different applied potentials on the optimal performance of the polymers is investigated. The optimal thermoelectric property ofpoly（Ni-ett） synthesized at 0.6 V is remarkably greater than that of the polymers synthesized at 1 and 1.6 V, exhibiting a maximum power factor of up to 131.6μW/mK2 at 360 K. Furthermore, the structure-property correlation ofpoly（Ni-ett） is also extensively investigated. X-ray diffraction （XRD） and X-ray photoelectron spectroscopy （XPS） analyses revealed that the larger size of crystalline domains and the higher oxidation state of poly（Ni-ett） synthesized at 0.6 V possibly results in the higher bulk mobility and carrier concentration in the polymer chains, respectively, accounting for the enhanced power factor.
