一种热能参数自动检测系统的构建

本文介绍了一种以 PC 机为主机,以单片机及其外围电路为分机,以 CAN 总线通信接口适配卡连接主机和分机的热能参数自动检测系统,给出了硬、软件结构。实际运行结果表明:系统具有测量参数多、可靠性高、智能功能强等特点。

一种热力参数自动测试系统

介绍以PC为主机、单片机为分机、基于CAN总线的热能自动测试系统。以温度、压力、流量为基本观测量 ,利用水蒸气热力学状态参数数学模型计算出全部热能参数 。

Prediction of mechanical properties of A357 alloy using artificial neural network

The workpieces of A357 alloy were routinely heat treated to the T6 state in order to gain an adequate mechanical property.The mechanical properties of these workpieces depend mainly on solid-solution temperature,solid-solution time,artificial aging temperature and artificial aging time.An artificial neural network（ANN） model with a back-propagation（BP） algorithm was used to predict mechanical properties of A357 alloy,and the effects of heat treatment processes on mechanical behavior of this alloy were studied.The results show that this BP model is able to predict the mechanical properties with a high accuracy.This model was used to reflect the influence of heat treatments on the mechanical properties of A357 alloy.Isograms of ultimate tensile strength and elongation were drawn in the same picture,which are very helpful to understand the relationship among aging parameters,ultimate tensile strength and elongation.

New Li-ion Battery Evaluation Research Based on Thermal Property and Heat Generation Behavior of Battery

We do a new Li-ion battery evaluation research on the effects of cell resistance and polariza- tion on the energy loss in batteries based on thermal property and heat generation behavior of battery. Series of 18650 cells with different capacities and electrode materials are evalu- ated by measuring input and output energy which change with charge-discharge time and current. Based on the results of these tests, we build a model of energy loss in cells＇ charge- discharge process, which include Joule heat and polarization heat impact factors. It was reported that Joule heat was caused by cell resistance, which included De-resistance and reaction resistance, and reaction resistance could not be easily obtained through routine test method. Using this new method, we can get the total resistance R and the polarization parameter U. The relationship between R, η, and temperature is also investigated in order to build a general model for series of different Li-ion batteries, and the research can be used in the performance evaluation, state of charge prediction and the measuring of consistency of the batteries.

Influences of hot stamping parameters on mechanical properties and microstructure of 30MnB5 and 22MnB5 quenched in flat die

The influences of hot stamping parameters such as heating temperature,soaking time,deformation temperature and cooling medium on the phase transformation,microstructure and mechanical properties of 30MnB5 and 22MnB5 are investigated and analyzed in this work.The quenching experiment,tensile testing,hardness measurement and microstructure observation were conducted to obtain the mechanical and microstructural data.The results indicate that 30MnB5 possesses a higher tensile strength but a lower elongation than 22MnB5,if hot stamped at the same process parameter.The tensile strength and hardness of the hot stamped specimens decrease under inappropriate heating conditions for two reasons,insufficient austenitization or coarse austenite grains.The austenitic forming rate of 30MnB5 is higher than that of 22MnB5,because more cementite leads to higher nucleation rate and diffusion coefficient of carbon atom.More amount of fine martensite forms under the higher deformation temperature or the quicker cooling rate.

Density Functional Theory Study of Selectivity of Crown Ethers to Li^+ in Spent Lithium-Ion Batteries Leaching Solutions

It is a challenge to recover lithium from the leaching solution of spent lithium-ion batteries,and crown ethers are potential extractants due to their selectivity to alkali metal ions.The theoretical calculations for the selectivity of crown ethers with different structures to Li ions in aqueous solutions were carried out based on the density functional theory.The calculated results of geometries,binding energies,and thermodynamic parameters show that 15C5 has the strongest selectivity to Li ions in the three crown ethers of 12C4,15C5,and 18C6.B15C5 has a smaller binding energy but more negative free energy than 15C5 when combined with Li^+,leading to that the lithium ions in aqueous solutions will combine with B15C5 rather than 15C5.The exchange reactions between B15C5 and hydrated Li^+,Co^2+,and Ni^2+were analyzed and the results show that B15C5 is more likely to capture Li^+from the hydrated ions in an aqueous solution containing Li^+,Co^2+,and Ni^2+.This study indicates that it is feasible to extract Li ions selectively using B15C5 as an extractant from the leaching solution of spent lithium-ion batteries.

Hydration process of rice husk ash cement paste and its corrosion resistance of embedded steel bar

Thermogravimetric analysis and electrical resistivity were used to determine the hydration process of cement paste with rice husk ash(RHA)(0−15%)and water-cement ratio of 0.4 in this work.X-ray diffraction(XRD)method and scanning electron microscopy(SEM)were used to survey crystal composition and microstructures of specimens cured for 3 h,1 d,7 d and 28 d.Finally,electrical parameters(electrical resistance and AC impedance spectroscopy)of steel bars reinforced cement paste were investigated to study the effect of RHA on the corrosion resistance.Results showed that RHA could affect the cement hydration by hydration promotion and pozzolanic effect.The evaluation function for electrical resistivity and curing ages fitted well with linear increasing function.The addition of RHA higher than 5%demonstrated a decreasing role in the electrical resistivity of cement paste at earlier curing ages(3−7 d).Meanwhile,when at later curing ages(7−28 d)the result was the opposite.Moreover,RHA demonstrated positive effects on corrosion resistance of steel bars in cement paste.

Adsorption and desorption properties of D318 resin for Cr(Ⅵ)

The adsorption capability of D318 resin for Cr（Ⅵ） was investigated by chemistry analysis. Experimental results show that D318 resin has the best adsorption ability for Cr（Ⅵ） at pH=3.16 in HAc-NaAc medium. The statically saturated adsorption capacity of the resin is 265.4 mg/g. The thermodynamic adsorption parameters, enthalpy change AH and free energy change AG298 of the adsorption reaction are 4.81 and -5.16 kJ/mol, respectively. The apparent activation energy Ea is 22.4 kJ/mol. The adsorption behavior obeys the Freundlich isotherm. The molar coordination ratio of the functional group of resin to Cr（Ⅵ） is 3：2. Cr（Ⅵ） adsorbed on D318 resin can be eluted by 5%NaOH-5%NaCl quantitatively.

Effect of working parameters on performance characteristics of hydrostatic turntable by using FSI-thermal model

Effects of working parameters on performance characteristics of hydrostatic turntable are researched by applying the fluid-structure-thermal coupled model.Fluid-structure interaction(FSI)technique and computational fluid dynamics(CFD)method are both employed by this new model,and thermal effects are also considered.Hydrostatic turntable systems with a series of oil supply pressures,various oil recess depth and several surface roughness parameters are studied.Performance parameters,such as turntable displacement,system flow rate,temperature rise of lubrication,stiffness and damping coefficients,are derived from different working parameters(rotational speed of turntable and exerted external load)of the hydrostatic turntable.Numerical results obtained from this FSI-thermal model are presented and discussed,and theoretical predictions are in good agreement with the experimental data.Therefore,this developed model is a very useful tool for studying hydrostatic turntables.The calculation results show that in order to obtain better performance,a rational selection of the design parameters is essential.

INVESTIGATION OF THE INTERACTIONS BETWEEN WATER AND MODIFIED SILICA GEL BY IGC AND TPD

In this work, the thermodynamic parameters for the adsorption of water vapor on untreated silica gel and silica gel treated with hygroscopic salts and silane coupling agent were determined by lnverse Gas Chromatography （IGC） in the infinite dilution region. The desorption activation energies of the water vapor on virgin and modified silica gels were estimated by using the Temperature Programmed Desorption （TPD） technique. The interactions between the water and the virgin and modified silica gels were discussed. Results showed that the thermodynamic parameters and desorption activation energy of water vapour on the silica gels increase with decreasing pore size and increasing the surface hydrophilic properties. The desorption activation energy of virgin and modified silica gels was found to increase with increasing the thermodynamic parameters. The larger the adsorption parameters and the desorption activation energy were, the interactions between water and virgin and modified silica gels were.

Country-level meteorological parameters for building energy efficiency in China

Accurate basic data are necessary to support performance-based design for achieving carbon peak and carbon neutral targets in the building sector.Meteorological parameters are the prerequisites of building thermal engineering design,heating ventilation and air conditioning design,and energy consumption simulations.Focusing on the key issues such as low spatial coverage and the lack of daily or higher time resolution data,daily and hourly models of the surface meteorological data and solar radiation were established and evaluated.Surface meteorological data and solar radiation data were generated for 1019 cities and towns in China from 1988 to 2017.The data were carefully compared,and the accuracy was proved to be high.All the meteorological parameters can be assessed in the building sector via a sharing platform.Then,country-level meteorological parameters were developed for energy-efficient building assessment in China,based on actual meteorological data in the present study.This set of meteorological parameters may facilitate engineering applications as well as allowing the updating and expansion of relevant building energy efficiency standards.The study was supported by the National Science and Technology Major Project of China during the 13th Five-Year Plan Period,named Fundamental parameters on building energy efficiency in China,comprising of 15 top-ranking universities and institutions in China.

Experimental investigation of effect of refrigerant gases,compressor lubricant and operating conditions on performance of a heat pump

In the field of heat pumps,there are a number of parameters that affect the performance and efficiency of the apparatus,which have been the subject of studies by individual researchers in the literature.This study describes an experimental method in order to investigate the effects of some significant parameters on heat pump performance.In this regard,a laboratory heat pump setup has been utilized to operate in different working conditions for achieving an appropriate estimation to find out effects of mentioned parameters such as refrigerant type and charge amount,compressor oil viscosity,compressor cooling fan,secondary fluids temperature and flow rate.Different refrigerants have been selected and used as circulating fluid in the installed heat pump.Although this work has been devoted to a detailed attempt to recognize the effects of various parameters on the coefficient of performance(COP) value,an appropriate method has been carried out to survey the obtained results by using economic analysis.It was revealed that one of the main parameters is refrigerant charge amount which has a notable effect on COP.The temperature of the heat source was also tested and the performance of the system increased by more than 11% by employing mentioned modifications and various operating conditions.In addition,by selecting a low viscosity compressor oil,the system performance increased by 18%.This improvement is more than 6% for the case that cooling fan is installed to cool the compressor element.

Investigate the Parameters Effect on Thermogravimetry Analysis （TGA） Performance for SOx Additive in FCC Units

Although the FCC process has been used for more than halfa century, new and important developments continue to be made in several areas. Some of these new developments are a direct response to environmental regulation. Sulfur oxides （SOx-SO2＋SO3） emitted from fluid catalytic cracking units （FCCU） are one of the most hazardous atmospheric pollutants, which may cause serious environmental problems such as the formation of acid rain and the destruction of the ozone layer. Thus, great attention has been focused on the SOx removal from FCC in last few years. The present papers will focus on the spinel material studies include three samples they were prepared by acidic method, solid solution MgAl2O4, solid solution with cerium10%Ce/MgAl2O4, iron mixed spinel with cerium 10%Ce/MgAl2-xFeO4.MgO and two samples solid solution with cerium introduce by vanadium as second co-catalyst prepared by basic method, 1% V/10%Ce/MgAl2O4.MgO were tested in TGA for oxidation half cycle to study some parameters effect on performance of SOx additives in TGA under condition similar to those of FCC units. Thermogravimetry analysis experiments have been used to demonstrate the pick-up and release of sulfur oxides in the development of additives for SOx control in the FCCU.

A New Alpha-function for the Peng-Robinson Equation of State： Application to Natural Gas

Cubic equations of state(EOSs) are simple and easy at calculation. One way of improving the accuracy of a cubic EOS is through the modification of temperature-dependent energy parameter by using alpha-function.The industrial applications of natural gas are very wide and as a result, prediction of thermodynamic properties and phase behavior of natural gas is an important part of design for such processes. In this work we develop a newα-function for the Peng-Robinson(PR) EOS with the parameters optimized especially for natural gas components.The parameters are generalized as a linear function of acentric factor. The results are compared to the predictions from original PR EOS and other α-functions in literature. It is shown that the new α-function presents a good accuracy with the average deviation of 1.42% for natural gas components.

Glass formation for iron-based alloys by combining kinetic and thermodynamic parameters

The glass formation was intensively studied for Fe-based alloys. Parameters defining kinetics and thermodynamic behavior of crystallization were calculated using calorimetric measurements and physical properties of constituent elements. It is found that the critical cooling rate Rc estimated by combining kinetic and thermodynamic parameters highly correlates with measured Rc found in literatures with correlation coefficient R2=0.944, and alloy compositions with high melting enthalpy AHm can easily form glass even without high undercooling and high value of the ,β-parameter of Tumbull＇s theory, revealing that the glass formation in this group of alloys is mostly controlled by growth limitation. This combination of kinetic and thermodynamic parameters can be used to determine alloy composition with good glass forming ability in Fe-based alloys just using physical properties of alloying elements and calorimetric measurements.

Optimizing Geothermal Energy Resource

Unlike other types of renewable energy resources, geothermal energy provides a stable source of energy as it can be exploited regardless of meteorological conditions. Using organic cycle, geothermal energy can be utilized for power generation. In such systems, the heat is exchanged between the surrounding rock mass and transport fluid. Consequently, the temperature of extracted geofluid from the well decreases with the time in accordance with the working parameters. Those parameters includeenergy extraction rate, temperature difference between inlet and outlet of the well, and the thermal conductivity of the ground. Current work, aims to develop a reliable computer model to specify the optimal working parameters so that the geofluid temperature will not reach a low value that is not acceptable for electricity generation, and the energy availability of geothermal resource is maximized. In the current study the ground thermal properties, the geothermal gradient and well dimensions are based on realistic data in Qatar and neighboring countries. The proposed model was developed for different heat extraction rate, different ground thermal properties, and for varied temperature difference between inlet and outlet of the well. Simulation shows that selecting the optimal working parameters can increase the availability of geothermal resource significantly.

Study on the Influence of Structural Parameters of Multi-channel Cylinder Dryer on Heat Transfer Performance

An approach to design multi-channel cylinder dryer was proposed. The heat transfer performance and flow characteristic under various structural parameters were analyzed. First, an experiment was designed and set up to measure the condensing heat transfer coefficient and the pressure drop in order to ,~erify the applicability of the Cavallini＇s correlation. Then, the relationship among the count of channels, aspect ratio, spacing ratio, width, height and hydraulic diameter of a channel was given. Finally, the correlation of condensing heat transfer and the homogeneous model was introduced in order to observe the heat transfer performance and flow characteristic of the multi-channel cylinder dryer affected by different structures. The study reveals that the structural parameters including count of channels, aspect ratio, spacing ratio of a channel dramatically influence the condensation heat transfer coefficient and frictional resistance of the steam. Based on the selected paper machine, it is suggested that the overall performance of the multi-channel cylinder dryer is best if the count of channels is 150-200, the aspect ratio is 1 ： 3 and the spacing ratio is 1 ： 1-1 ： 3.

Constructal entransy dissipation rate minimization for umbrella-shaped assembly of cylindrical fins

Umbrella-shaped assembly of cylindrical fins is optimized by adopting analytical method and taking dimensionless mean thermal resistance (MTR) as performance index. The optimal construct of umbrella-shaped assembly is obtained. The results show that the heat conductance performance of the assembly becomes ever worse with ever greater number of elemental cylindrical fins,the umbrella-shaped assembly reduces to cylindrical fin in some values of design parameters,and the diameters’ dependence on design parameters is weak for the optimized assembly. An equivalent thermal resistance defined based on entransy dissipation rate (EDR) reflects an average heat transfer effect of the assembly. The constructal design corresponding to the minimum EDR (or MTR) should be adopted for designing an assembly of fins in engineering at the limit safe condition.

Influence of heating parameters on properties of the Al-Si coating applied to hot stamping

The Al-Si coating of ultra-high strength steel has been applied to hot stamping more and more widely, owing to solving the problem of oxidation and decarburization. However, the evolution of Al-Si coating during the heating process was rarely studied in the previous study. The tests about the influence of heating parameters, such as heating temperature, heating rates and dwell time, on properties of the Al-Si coating were carried out on the Gleeble-3500 thermal simulator. The properties of the Al-Si coating, for instance, volume fraction of FeAl intermetallics, α-Fe layer as well as porosity and 3D surface topography, were explored in the study. Results showed that more and more Kirkendall voids and cracks appeared in the Al-Si coating when the heating temperature exceeded 600°C. The heating rates almost had no influence on properties of the Al-Si coating when the temperature was equal to or lower than 500°C. The volume fraction of FeAl intermetallics in the coating with dwell time from 3 s to 8 min at 930°C was0, 6.19%, 17.03% and 20.65%, separately. The volume fraction of the α-Fe layer in the coating changed from zero to 31.52%with the prolonged dwell time. The porosity of the coating ranged from 0.51% to 4.98% with the extension of dwell time. The unsmooth degree of the surface of the coating rose gradually with the increasing of heating rates and the extension of dwell time.The 3D surface topography of the coating was determined by the comprehensive effect of atoms diffusion, new formed phases,surface tension and the degree of oxidation of the coating surface. Experiments indicated that rapid heating was not suitable for the coating when the temperature exceeded 500°C. Experiments also demonstrated that enough dwell time was essential to obtain the superior properties of the coating.

Thermodynamic analysis for a chemically recuperated scramjet

Endothermic hydrocarbon fuel is regarded as an optimal fuel for a scramjet with regenerative cooling,which provides extra cooling through endothermic chemical conversion to avoid the severly limited cooling capacity when conventional fuels are adopted for cooling.Although endothermic cooling is proposed from the view point that the heat sink of a conventional fuel is insufficient,the heat-absorbing through endothermic chemical reaction is actually a chemical recuperation process because the wasted heat dissipated from the engine thermal structure is recovered through the endothermic chemical reaction.Therefore,the working process of a scramjet with endothermic hydrocarbon fuel cooling is a chemical recuperative cycle.To analyze the chemical recuperative cycle of a chemically recuperated scramjet engine,we defined physical and chemical recuperation effectivenesses and heating value increment rate,and derived engine performance parameters with chemical recuperation.The heat value benefits from both physical and chemical recuperations,and it increases with the increase in recuperation effectiveness.The scramjet performance parameters also increase with the increase in chemical recuperation effectiveness.The increase in chemical recuperation effectiveness improves both the performances of the fuel cooling system and the combustion system.The results of analysis prove that the existence of a chemical recuperation process greatly improves the performance of the whole scramjet.