热腐条件下矩形板式天然橡胶支座剪压性能研究

为研究热腐条件下公路桥梁板式天然橡胶支座剪压性能,设计将一批天然橡胶支座置于恒温鼓风干燥箱中,控制一定的温度与湿度,分别进行20d、40d、60d、80d和100d的处理,模拟我国西北地区高温干燥环境对天然橡胶支座的影响,对处理后的试件进行剪压试验,并对其外观尺寸、极限承载力、极限抗剪强度、水平等效刚度及抗剪弹性模量等指标进行对比分析。试验表明热腐处理时间越长,试件出现局部破坏的现象越明显,变形越大,越容易发生脆性破坏,极限抗剪强度、抗剪弹性模量等指标下降的越快。通过对试验结果的对比分析,运用最小二乘法建立极限抗剪强度及抗剪弹性模量的衰减模型基本符合指数函数规律。

Effect of heat treatment on stress corrosion cracking, fracture toughness and strength of 7085 aluminum alloy

The influences of heat treatment on stress corrosion cracking （SCC）, fracture toughness and strength of 7085 aluminum alloy were investigated by slow strain rate testing, Kahn tear testing combined with scanning electron microscopy （SEM） and transmission electron microscopy （TEM）. The results show that the fracture toughness of T74 overaging is increased by 22.9% at the expense of 13.6% strength, and retrogression and reaging （RRA） enhances fracture toughness 14.2% without reducing the strength compared with T6 temper. The fracture toughness of dual-retrogression and reaging （DRRA） is equivalent to that of T74 with an increased strength of 14.6%. The SCC resistance increases in the order： T6〈RRA〈DRRA≈T74. The differences of fracture toughness and SCC were explained on the basis of the role of matrix precipitates and grain boundary orecioitates.

Influence of thermomechanical treatments on localized corrosion susceptibility and propagation mechanism of AA2099 Al-Li alloy

In order to manifest the influence of specific microstructural component on the development of severe localized corrosion in an AA2099 aluminum-lithium alloy, the corrosion behavior of the alloy subjected to solution heat treatment, cold working and artificial ageing was investigated. Immersion testing and potentiodynamic polarization were employed to introduce localized corrosion; scanning electron microscopy and transmission electron microscopy were used to characterize the alloy microstructure and corrosion morphology. It was found that the susceptibility of the alloy to severe localized corrosion was sensitive to thermomechanical treatments. Additionally, the state of alloying elements influenced the mechanism of localized corrosion propagation. Specifically, the alloy in T8 conditions showed higher susceptibility to severe localized corrosion than that in other conditions. During potentiodynamic polarization, the alloy in solution heat-treated and T3 conditions displayed crystallographic corrosion morphology while the alloy in T6 and T8 conditions exhibited selective attack of grain interiors and grain boundaries in local regions.

Heat-treated wood and its development in Europe

Efficient use of timber is a vital concern problem, especially in these regions where the forestry coverage ratio is decreasing. Studies on physical modification of wood have been taken more attention due to the increasing attentions on environmental protection. Thermal modification is emphasized and developed quickly in developing countries, especially in European countries. A large number of researches have been conducted and some industrial production plants have been built. This paper reviewed the history of heat treatment, exemplifies the industrial developments in several European countries, summarized the basic principle of heat treatment and describes the environmental characteristics. The properties of heat-treated wood and its usage are also summed up.

Effect of standard heat treatment on microstructure and properties of borided Inconel 718

Boronizing was applied to Inconel 718. In order to obtain the optimal combination of strength and ductility, the borided Inconel 718 was subjected to standard heat treatment. This consists of solution treatment and then a two-step aging treatment. The borided layer is composed of the compound layer and the boron diffusion zone. Because of the superior hardness of borides, the borided Inconel 718 exhibits a significant reduction in its wear rate and relatively low coefficient of friction （COF） compared with the unborided Inconel 718. The standard heat treatment efficiently promotes the diffusion of boron into the interior of the material and the generation of new borides （Fe2B, CrB）. The borided layer with standard heat treatment shows much better wear resistance due to the thicker borided layer （313.76 μm）.

Facile hydrothermal synthesis of TiO_2-Ca P nano-films on Ti6Al4V alloy

Ti6Al4V alloy was subjected to hydrothermal treatment in the concentrated Ca3(PO4)2, Ca HPO4 and Ca(H2PO4)2 solutions for bioactive surface modification. The treated samples are covered by films composed of nano-particles with the size of 60-240 nm. Such film can also be grown on the strut surface of a Ti6Al4 V scaffold prepared by electron beam melting(EBM) technology. XPS analysis indicates that Ti element on the surface presents as TiO2, and Ca and P elements are in the form of calcium phosphate. XRD and Raman analyses show that the surface layer is composed of anatase TiO2 and hydroxyapatite. Potentiodynamic polarization test in a Ca-free Hank's balanced solution demonstrates that the treated sample has markedly improved corrosion resistance compared with the polished sample. The present work provides a bioactive surface modification method that is easily-operated, low-temperature, less corrosion, and applicable to porous Ti6Al4 V alloy for biomedical applications.

Structure and properties of FeCoNiCrCu_(0.5)Al_x high-entropy alloy

Effects of Al content and heat treatment on the structure,hardness and electrochemical properties of FeCoNiCrCu0.5Alx high-entropy alloys were investigated.The phase structure of as-cast alloys evolves from FCC phase to BCC phase with the increase of Al content.The stable phase of FeCoNiCrCu0.5Alx high-entropy alloys will transform from FCC phase to FCC＋BCC duplex phases when x value increases from 0.5 to 1.5.The hardness of BCC phase is higher than that of FCC phase,and the corrosion resistance of BCC phase is better than FCC phase in chlorine ion and acid medium.High hardness and good corrosion resistance can be obtained in as-cast FeCoNiCrCu0.5Al1.0 alloy.

Stress corrosion cracking behaviour of 7xxx aluminum alloys: A literature review

Stress corrosion cracking （SCC） is degradation of mechanical properties under the combined action of stress and corrosive environment of the susceptible material. Out of eight series of aluminium alloys, 2xxx, 5xxx and 7xxx aluminium alloys are susceptible to SCC. Among them, 7xxx series aluminium alloys have specific application in aerospace, military and structural industries due to superior mechanical properties. In these high strength 7xxx aluminium alloys, SCC plays a vital factor of consideration, as these failures are catastrophic during the service. The understanding of SCC behaviour possesses critical challenge for this alloy. The main aim of this review paper is to understand the effect of constituent alloying elements on the response of microstructural variation in various heat-treated conditions on SCC behavior. Further, review was made for improving the SCC resistance using thermomechanical treatments and by surface modifications of 7xxx alloys. Apart from a brief review on SCC of 7xxx alloys, this paper presents the effect of stress and pre-strain, effect of constituent alloying elements in the alloy, and the effect of environments on SCC behaviour. In addition, the SCC behaviours of weldments, 7xxx metal matrix composites and also laser surface modifications were also reviewed.

Corrosion behaviour of thixoformed and heat-treated ZA27 alloys in NaCl solution

The influence of corrosion on the microstructure of thixoformed and heat-treated ZA27 alloys was investigated. The microstructure of ZA27 alloy was affected by heat treatment. The process of electrochemical corrosion occurs in both ZA27 alloys through the area of r/phase. According to the results of immersion test and electrochemical measurements, the corrosion rate of the thixoformed ZA27 alloy is at least 50% lower than that of the thixoformed and thermally processed alloy. This indicates the unfavourable influence of applied heat treatment （T4 regime） on the corrosion resistance of the thixoformed ZA27 alloy.

Effects of T6 heat treatment on mechanical, abrasive and erosive-corrosive wear properties of eutectic Al-Si alloy

The abrasive and erosive-corrosive properties of eutectic Al-Si （LM6） alloy were studied. Microstructural features of the alloy were altered by controlling the T6 heat treatment parameter, and their influence on hardness, strength and elongation, and response of the samples in erosion-corrosion and abrasion conditions were studied. Characteristics of the Al-Si alloy samples were compared with those of Al conventionally used in agricultural machineries. Fabrication of a typical component using the Al-Si alloy was also explored in order to understand the feasibility of using the alloy system for the envisaged applications. The study suggests the response of the samples in different conditions to be greatly influenced by parameters like chemical composition, microstructural features and applied load, traversal distance and test environment. The performance of even the as cast Al-Si alloy is far superior to that of the conventional Al samples, while the T6 heat treated Al-Si alloy shows improved performance. Accordingly, the as-cast as well as T6 heat treated Al-Si alloy has potential for applications in agriculture as a replacement for the conventionally used Al.

Influence of heat treatment on corrosion behavior of hot rolled Mg5Gd alloys

The influence of heat treatment on the corrosion behavior of rolled Mg5 Gd alloys in 3.5 wt.% Na Cl solution saturated with Mg(OH)2 was characterized by immersion test, electrochemical test, scanning electrochemical microscopy(SECM) and corrosion morphology analysis in order to improve the corrosion resistance of Mg alloys. The results showed that solution treatment reduced the corrosion rate of the Mg5 Gd significantly, resulting in relatively uniform corrosion and shallow corrosion cavities due to the dissolution of Cd-containing particles. The following aging process could further decrease the corrosion rate. Precipitation of nano-sized Cd-containing particles did not cause apparent micro-galvanic corrosion, which could be attributed to the formation of a protective corrosion product film fully covering the particles.

Correlation between microstructure and corrosion and cavitation erosion behaviors of nickel aluminum bronze

The microstructure,corrosion and cavitation erosion(CE)behaviors of the as-cast and four different heat treated nickel aluminum bronzes(NABs)in 3.5 wt.%NaCl solution were investigated.The results show that after annealing,β′transformed into the eutectoid microstructure,and moreκIV precipitated fromα.Less eutectoid microstructure and moreβ′were obtained after normalizing.The quenched NAB mainly consisted ofαandβ′phases,and fine,acicularαandκphases precipitated insideβ′after subsequent aging.The largest proportion of the eutectoid microstructure,which underwent severe selective phase corrosion,was responsible for the lowest corrosion resistance of the annealed NAB.The quenched NAB possessed the most protective film and hence the highest corrosion resistance.The mechanical attack was primarily responsible for the CE damage for the as-cast,annealed and normarlized NABs.The quenched and quenched+aged NABs exhibited superior CE resistance because of the high hardness.The CE−corrosion synergy dominantly caused CE degradation,and it was largely attributed to corrosion-enhanced-CE.

Intergranular Corrosion of AISI 304 Heat Treated at 800℃ Varying Range Times

Austenitic stainless steels, when exposed to welding conditions or aging for length of service, it＇s observed the formation of numerous deleterious phases, such as several kinds of carbides type MC, M6C, M7C3, M23C6, and intermetallic secondary phases （sigma, chi, laves）, which cause the process of intergranular corrosion. The aim of this work was verifying the formation of the types of carbides and/or intermetallic phases existing in the stainless AISI 304 at 800 ℃, varying the timing of heat treatment between 30, 360 and 1,440 min. The optical microscopy analysis revealed the predominant formation of the carbide type M23C6. The results of DL-EPR （double loop electrochemical potentiokinetic reactivation） tests showed a gradual increase in the precipitation of this carbide with the increase of treatment time. The potentiodynamic polarization showed that the precipitation of this carbide reduce the formation of the Cr2O3 passive layer, suggesting that the precipitate carbide to be predominantly of the Cr23C6 type.

Effects of microstructure and texture after thermomechanical treatments on corrosion behavior of AISI 321 pipeline austenitic stainless steel

In the present study,the effects of microstructure,grain size,and texture after thermomechanical processing on the corrosion behavior of AISI 321 austenitic stainless steel(ASS)were studied.The as-received,coarse-grained steel((35±3)μm)was subjected to 20%,50%and 90%thickness reduction through cold rolling at liquid nitrogen temperature,followed by annealing at 750,950 and 1050℃for 15 min.Recrystallization occurred after annealing at 750℃,and with the increasing of annealing temperature to 950℃and 1050℃,secondary recrystallization(abnormal grain growth)and grain growth were observed.The results showed that,after 20%thickness reduction,corrosion resistance increased significantly(21.1 kΩ·cm^(2))compared with the as-received condition(3.9 kΩ·cm^(2))due to the enhancement ofγ-fiber and the creation ofΣ3 boundaries.In contrast,the corrosion resistance decreased with the increasing of thickness reduction to 90%during rolling,but still depicted higher corrosion resistance compared with the as-received specimen.After annealing the 90%cold rolled(CR)specimens at 750 and 950℃,the corrosion resistance increased in comparison with the as-received sample as a result of the more uniform microstructure,appearance of Goss and brass texture components,and grain refinement.However,significant grain growth((112±76)μm)followed by a non-uniform structure was observed after annealing at 1050℃and resulted in the lowest corrosion resistance(1.3 kΩ·cm^(2)).

Intergranular Corrosion of UNS S31803 Heat Treated at 800 ℃ Varying Range Times

The aim of this work is evaluate the intergranular corrosion on UNS S31803 steel, with heat treatments at 800 ℃, varying treatment times of 30 mins, 360 mins and 1,440 mins. The results confirm the formation of o phases and secondary austenite （γ2）. For the analysis of the influence of o and γ2 phases, metallographic analysis were conducted through optical microscopy, potentiokinetic reactivation electrochemical techniques and potentiodynamic polarization in NaCI 3.5% solution. Microstructural analysis has shown a formation of γ2 and o phase in heat treatment, due to diffusion of chromium and molybdenum from δ phase to y phase, precipitating on δ/γ and δ/δ interfaces. The DL-EPR （Double loop electrochemical potentiokinetic reactivation） results have shown an increase of the DOS （degree of sensitization） for long periods of time on heat treatment. The results of potentiodynamic polarization showed a reduction of the corrosion and pitting potentials, followed by an increase of the current density when the UNS S31830 steel is heat treated during long periods of time.

Effects of laser heat treatment on salt spray corrosion of 1Cr5Mo heat resistant steel welding joints

The surface of 1Cr5 Mo heat-resistant steel welding joint was processed with CO2 laser, and the corrosion behaviors before and after laser heat treatment(LHT) were investigated in the salt spray corrosion environments. The microstructures, phases, residual stresses and retained austenite content of 1Cr5 Mo steel welding joint before and after LHT were analyzed with optical microscope and X-ray diffraction, respectively. The cracking morphologies and chemical compositions of corrosion products after salt spray corrosion were analyzed with field emission scanning electron microscopy(FESEM) and energy disperse spectroscopy(EDS), respectively, the polarization curves were measured on a PS-268 A type electrochemical workstation, and the mechanism of corrosion resistance by LHT was investigated as well. The results show that the passive film of original sample is destroyed owing to the corrosive media penetrating into the subsurface, resulting in the redox reaction. The content of residual austenite in the surface and the self-corrosion potential are increased by LHT, which is contributed to improving the capability of salt spray corrosion resistance.

Effects of heat treatment on corrosion behaviors of Mg-3Zn magnesium alloy

The effects of two kinds of heat treatments T4(solution treatment) and T6(aging treatment) on the corrosion behaviors of Mg-3Zn magnesium alloy were studied by electrochemical measurements and scanning electron microscopy(SEM) .It is found that zinc element enriches along grain boundaries to exhibit a network microstructure for both T4-and T6-treated alloy.For T6 treatment,larger MgZn particles form mainly on grain boundary and fine MgZn particles precipitate on matrix.Compared with cast alloy,T4 treatment could decrease the amounts of MgZn particles,and decrease the zinc content of zinc-rich net-segregation.Electrochemical measurements show that T4 treatment increases the corrosion resistance while T6 treatment decreases the corrosion resistance of Mn-3Zn alloy.

Effects of Postharvest Hot Water and Hot Air Treatments on Storage Decay and Quality Traits of Kumquat （Fortunella japonica Lour. Swingle, cv. Ovale） Fruit

Heat treatments such as hot-water dipping （HWD）, hot water rinsing and brushing （HWRB）, and hot air treatment （HAT） have been applied on a wide range of horticultural crops to control postharvest decay and to maintain quality characteristics. In this study we compared the influence of hot-water dipping （HWD） for 2 rain at 50℃and hot air treatment （HAT） at 37 ℃ for 30 hours, on postharvest performance of kumquat （Fortunellajaponica Lour. Swingle, cv. Ovale） fruit. Decay development, transpiration rate （fruit weight loss）, external appearance, and nutritive （sugars and organic acids） and functional properties （ascorbic acid, total phenolic compounds, and total antioxidant activity） were evaluated over 21 days＇ simulated shelf-life at 17 ℃. Untreated fruits were used as control. There was no visible damage to the fruit following HWD or HAT and after storage. However, while HWD and control fruit maintained their fresh appearance during the first 14 days of storage and were rated as fairly fresh after the 21 days, HAT fruits had lost their gloss and no longer appeared fresh. HWD did not affect fruit weight loss while HAT induced significant weight loss with respect to control. HAT did not significantly affect decay incidence after 14 days＇ storage but effectively reduced decay after 21 days＇. HWD notably reduced decay development after 14 and 21 days of storage and proved significantly more effective than HAT. Neither HWD nor HAT significantly affected the nutritive and functional properties of fruit. Thus, present results indicate that while HWD can be applied on kumquats to control postharvest decay without impairing the quality traits, HAT conditions （treatment time and temperature） should be optimized, due to adverse effects to fruit quality.

Biocompatibility and bone regeneration of PEO/Mg-Al LDH-coated pure Mg:an in vitro and in vivo study

Forming a stable anti-corrosion surface layer on magnesium(Mg)and its alloys has become a major challenge in developing a desirable degradable medical implant in bone.In this study,a porous MgO layer was first formed on Mg by plasma electrolytic oxidation(PEO),and then a Mg-Al layered double hydroxide(LDH)layer was prepared to seal the porous structure of the PEO layer(LDH-2h and LDH-12h)via hydrothermal treatment.The bilayer structure composite coating,which can effectively resist the penetration of surrounding media,is similar to plain Chinese tiles.The in vitro results revealed that compared with other coatings,the LDH-12h composite coating can reduce the release of Mg ions and induce a milder change in pH when immersed in phosphate-buffered saline(PBS).In vitro rat bone marrow stem cell(rBMSC)culture suggested that the LDH-12h composite coating is favorable for cell activity,proliferation and could improve the osteogenic activity of rBMSCs.A subcutaneous implantation test revealed that the as-prepared sample showed enhanced corrosion resistance and histocompatibility in vivo,especially in the LDH-12h group.Moreover,LDH-12h had the lowest rate of degradation and the closest combination with the new bone after being inserted into a rat femur for 12 weeks with no major organ dysfunction.In summary,the asprepared PEO/Mg-Al LDH composite coating is able to improve the corrosion resistance and biocompatibility of Mg and to enhance osteogenic activity in vivo,suggesting its promising prospects for orthopedic applications.