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苹果酸二薄荷酯的制备及其热裂解性质 被引量:17
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作者 朱海军 刘志华 +3 位作者 任卓英 古昆 缪明明 李斌 《精细化工》 EI CAS CSCD 北大核心 2004年第8期586-588,616,共4页
以薄荷醇和苹果酸为原料,对甲苯磺酸为催化剂,采用熔融酯化法制备苹果酸二薄荷酯。优化的反应条件为:催化剂用量w(对甲苯磺酸)=1 5%,原料配比n(薄荷醇)/n(苹果酸)=2 4,反应时间5h,反应温度120℃,苹果酸二薄荷酯收率达61 5%。产物经IR、M... 以薄荷醇和苹果酸为原料,对甲苯磺酸为催化剂,采用熔融酯化法制备苹果酸二薄荷酯。优化的反应条件为:催化剂用量w(对甲苯磺酸)=1 5%,原料配比n(薄荷醇)/n(苹果酸)=2 4,反应时间5h,反应温度120℃,苹果酸二薄荷酯收率达61 5%。产物经IR、MS和1HNMR进行了结构表征,并在300、600和900℃对其热裂解性质进行了研究。 展开更多
关键词 苹果酸二薄荷酯 制备 热裂解性质 薄荷醇 苹果酸 对甲苯磺酸 催化剂 熔融酯化法
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Investigation of heat sink of endothermic hydrocarbon fuels 被引量:1
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作者 郭永胜 林瑞森 《Journal of Zhejiang University-Science A(Applied Physics & Engineering)》 SCIE EI CAS CSCD 2005年第7期632-635,共4页
Endothermic hydrocarbon fuels are advanced coolants for high-temperature structures of spacecraft. No data of tested-cooling-ability of endothermic fuels have been broadly discussed in literature. In this work a high-... Endothermic hydrocarbon fuels are advanced coolants for high-temperature structures of spacecraft. No data of tested-cooling-ability of endothermic fuels have been broadly discussed in literature. In this work a high-temperature flow calorimeter was designed, and the cooling capacity of six different hydrocarbon fuels were measured. Experimental results showed that these hydrocarbon fuels have capacity for cooling high-temperature structures, and that the cooling capacity of fuel N-1 can reach 3.15 M J/kg, which can nearly satisfy the requirement of thermal management for a Mach 3 cruise aircraft, whose heat sink requirement is about 3.5 M J/kg. The endothermic velocity of hydrocarbon fuels was also measured by the calorimeter. 展开更多
关键词 Endothermic hydrocarbon fuels Heat sink. Thermal management Cooling capacity
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