本文由氧化石墨烯通过水热法制备直接获得石墨烯。采用热重-差热分析方法检测了石墨烯受热过程中的质量变化和氧化温度。利用热分析-质谱联用技术在400-650°C温度区间得到了水和二氧化碳正离子质谱峰,这说明石墨烯氧化过程中的质...本文由氧化石墨烯通过水热法制备直接获得石墨烯。采用热重-差热分析方法检测了石墨烯受热过程中的质量变化和氧化温度。利用热分析-质谱联用技术在400-650°C温度区间得到了水和二氧化碳正离子质谱峰,这说明石墨烯氧化过程中的质量损失是由羟基水和二氧化碳脱除造成的。同时,还采用非等温热分析动力学方法,利用5、10、15°C?min^(-1)三种不同升温速率获得了石墨烯材料在空气气氛下的热分析动力学参数。通过Kissinger方法计算出石墨烯氧化过程中的活化能(Ea)和指前因子的对数(lg(A/s-1))分别为155.11 k J?mol^(-1)和6.90。利用Ozawa-Flynn-Wall(FWO)方法还建立了活化能和指前因子与反应转化率之间的关系。基于以上研究结果,本工作将对石墨烯在热界面、导热和先进复合材料等领域的应用提供参考价值。展开更多
The pyrolysis characteristics of PVC were systematically investigated using a Netzschne TG thermo-balance coupled to a quadrupole mass spectrometer. The pyrolysis conditions were 0.1 MPa of Ar, a heating rate of 10 ℃...The pyrolysis characteristics of PVC were systematically investigated using a Netzschne TG thermo-balance coupled to a quadrupole mass spectrometer. The pyrolysis conditions were 0.1 MPa of Ar, a heating rate of 10 ℃/min and a final temperature of 1000℃. Both the thermogravimetric properties and the simultaneous evolution of gaseous products during pyrolysis were studied. The TG/DTG results showed that as the pyrolysis temperature increases the weight loss and weight loss rate of PVC increases. Near 412℃ the weight loss rate attained its peak value. At higher temperatures the rate of loss gradually decreases. The gases evolved during thermogravimetric analysis were analyzed by a mass spectrometer, monitoring the relative intensity of HC1, C6H6, light hydrocarbon and chlorine-containing gases The evolution curves showed that HC1, C6H6, light hydrocarbon and chlorine-containing gases all peak at about 416℃. This is consistent with the fact that the weight loss curves also peak at about 412℃. The extensive HCl evolution is consistent with the high chlorine content of PVC. The formation of these gases can be explained by considering these reactions： dehydrochlorination, intramolecular cyclization and the addition of HCl to unsaturated hydrocarbons.展开更多
The validation and assessment of Envisat advanced synthetic aperture radar (ASAR) ocean wave spectra products are important to their application in ocean wave numerical predictions. Six-year ASAR wave spectra data are...The validation and assessment of Envisat advanced synthetic aperture radar (ASAR) ocean wave spectra products are important to their application in ocean wave numerical predictions. Six-year ASAR wave spectra data are compared with one-dimensional (1D) wave spectra of 55 co-located moored buoy observations in the northern Pacific Ocean. The ASAR wave spectra data are firstly quality control filtered and spatio-temporal matched with buoy data. The comparisons are then performed in terms of 1D wave spectra, significant wave height (SWH) and mean wave period (MWP) in different spatio-temporal offsets respectively. SWH comparison results show the evident dependence of SWH biases on wind speed and the ASAR SWH saturation effect. The ASAR wave spectra tend to underestimate SWH at high wind speeds and overestimate SWH at low wind speeds. MWP comparison results show that MWP has a systematic bias and therefore it should be bias-modified before used. The comparisons of 1D wave spectra show that both wave spectra agree better at low frequencies than at high frequencies, which indicates the ASAR data cannot resolve the high frequency waves.展开更多
基金supported by the National Natural Science Foundation of China(51325203,51472263)Shanghai Materials Genome Project,China(14DZ2261200)+2 种基金Shanghai Technical Platform for Testing and Characterization on Inorganic Materials,China(14DZ2292900)Shanghai Sailing Program,China(16YF1413100)Program of the Innovative Fund of Shanghai Institute of Ceramics,Chinese Academy of Science(Y37ZC4143G)~~
文摘本文由氧化石墨烯通过水热法制备直接获得石墨烯。采用热重-差热分析方法检测了石墨烯受热过程中的质量变化和氧化温度。利用热分析-质谱联用技术在400-650°C温度区间得到了水和二氧化碳正离子质谱峰,这说明石墨烯氧化过程中的质量损失是由羟基水和二氧化碳脱除造成的。同时,还采用非等温热分析动力学方法,利用5、10、15°C?min^(-1)三种不同升温速率获得了石墨烯材料在空气气氛下的热分析动力学参数。通过Kissinger方法计算出石墨烯氧化过程中的活化能(Ea)和指前因子的对数(lg(A/s-1))分别为155.11 k J?mol^(-1)和6.90。利用Ozawa-Flynn-Wall(FWO)方法还建立了活化能和指前因子与反应转化率之间的关系。基于以上研究结果,本工作将对石墨烯在热界面、导热和先进复合材料等领域的应用提供参考价值。
基金Project 2005BS09003 supported by Shandong Province Foundation for Distinguished Young Scholars
文摘The pyrolysis characteristics of PVC were systematically investigated using a Netzschne TG thermo-balance coupled to a quadrupole mass spectrometer. The pyrolysis conditions were 0.1 MPa of Ar, a heating rate of 10 ℃/min and a final temperature of 1000℃. Both the thermogravimetric properties and the simultaneous evolution of gaseous products during pyrolysis were studied. The TG/DTG results showed that as the pyrolysis temperature increases the weight loss and weight loss rate of PVC increases. Near 412℃ the weight loss rate attained its peak value. At higher temperatures the rate of loss gradually decreases. The gases evolved during thermogravimetric analysis were analyzed by a mass spectrometer, monitoring the relative intensity of HC1, C6H6, light hydrocarbon and chlorine-containing gases The evolution curves showed that HC1, C6H6, light hydrocarbon and chlorine-containing gases all peak at about 416℃. This is consistent with the fact that the weight loss curves also peak at about 412℃. The extensive HCl evolution is consistent with the high chlorine content of PVC. The formation of these gases can be explained by considering these reactions： dehydrochlorination, intramolecular cyclization and the addition of HCl to unsaturated hydrocarbons.
基金Supported by the Special Fund for Marine Commonweal Scientific Research of China (No.200705027)
文摘The validation and assessment of Envisat advanced synthetic aperture radar (ASAR) ocean wave spectra products are important to their application in ocean wave numerical predictions. Six-year ASAR wave spectra data are compared with one-dimensional (1D) wave spectra of 55 co-located moored buoy observations in the northern Pacific Ocean. The ASAR wave spectra data are firstly quality control filtered and spatio-temporal matched with buoy data. The comparisons are then performed in terms of 1D wave spectra, significant wave height (SWH) and mean wave period (MWP) in different spatio-temporal offsets respectively. SWH comparison results show the evident dependence of SWH biases on wind speed and the ASAR SWH saturation effect. The ASAR wave spectra tend to underestimate SWH at high wind speeds and overestimate SWH at low wind speeds. MWP comparison results show that MWP has a systematic bias and therefore it should be bias-modified before used. The comparisons of 1D wave spectra show that both wave spectra agree better at low frequencies than at high frequencies, which indicates the ASAR data cannot resolve the high frequency waves.
